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Barker, Jim and Reid, Jacqueline and Wilmot, Edward and Mulqueen, Simon and Smith, Sarah Angel and Scurr, David and Snape, Colin and Kersting, Reinhard and Gauld, Richard and Mulvey, Robert (2020) Investigations of diesel injector deposits characterization and testing. SAE Technical Papers. 2020-01-2094. ISSN 0148-7191

Whitelaw, Michael T. and Kennedy, Alan R. and Mulvey, Robert E. (2020) Structural similarity in a series of alkali metal aluminates with heteroleptic tert-butoxide–isobutyl ligand sets. European Journal of Inorganic Chemistry, 2020 (30). pp. 2912-2918. ISSN 1434-1948

Brouillet, Etienne V. and Kennedy, Alan R. and Krämer, Tobias and Mulvey, Robert E. and Robertson, Stuart D. and Stewart, Alexander and Towie, Stephen (2020) Synthesis, structure and DFT analysis of the THF solvate of 2-picolyllithium : a 2-picolyllithium solvate with significant carbanionic character. Zeitschrift fur Anorganische und Allgemeine Chemie, 646 (13). pp. 726-733. ISSN 1521-3749

Honeyman, Gordon W. and Armstrong, David R. and Clegg, William and Hevia, Eva and Kennedy, Alan R. and McLellan, Ross and Orr, Samantha A. and Parkinson, John A. and Ramsay, Donna L. and Robertson, Stuart D. and Towie, Stephen and Mulvey, Robert E. (2020) A regioselectively 1, 1',3 ,3'-tetrazincated ferrocene complex displaying core and peripheral reactivity. Chemical Science, 11 (25). pp. 6510-6520. ISSN 2041-6539

Gauld, Richard M. and McLellan, Ross and Kennedy, Alan R. and Barker, Jim and Reid, Jacqueline and Mulvey, Robert E. (2019) Backbone reactivity of lithium β-Diketiminate (NacNac) complexes with CO 2, tBuNCO and iPrNCO. Chemistry - A European Journal, 25 (64). pp. 14728-14734. ISSN 1521-3765

Pollard, Victoria A. and Young, Allan and McLellan, Ross and Kennedy, Alan R. and Tuttle, Tell and Mulvey, Robert E. (2019) Lithium-aluminate-catalyzed hydrophosphination applications. Angewandte Chemie International Edition, 58 (35). pp. 12291-12296. ISSN 1521-3773

Martínez-Martínez, Antonio J. and Kennedy, Alan R. and Paprocki, Valerie and Fantuzzi, Felipe and Dewhurst, Rian D. and O'Hara, Charles T. and Braunschweig, Holger and Mulvey, Robert E. (2019) Selective mono- and dimetallation of a group 3 sandwich complex. Chemical Communications, 55 (65). pp. 9677-9680. ISSN 1359-7345

Robertson, Stuart D. and Uzelac, Marina and Mulvey, Robert E. (2019) Alkali-metal-mediated synergistic effects in polar main group organometallic chemistry. Chemical Reviews, 119 (14). pp. 8332-8405. ISSN 0009-2665

Gauld, Richard M. and Kennedy, Alan R. and McLellan, Ross and Barker, Jim and Reid, Jacqueline and Mulvey, Robert E. (2019) Diverse outcomes of CO2 fixation using alkali metal amides including formation of a heterobimetallic lithium-sodium carbamato-anhydride via lithium-sodium bis-hexamethyldisilazide. Chemical Communications, 55 (10). pp. 1478-1481. ISSN 1359-7345

McLellan, Ross and Uzelac, Marina and Bole, Leonie J. and Gil-Negrete, Jose Maria and Armstrong, David R. and Kennedy, Alan R. and Mulvey, Robert E. and Hevia, Eva (2019) Alkali metal effects in trans-metal-trapping (TMT) : comparing LiTMP with NaTMP in cooperative MTMP/Ga(CH2SiMe3)3 metalation reactions. Synthesis, 51 (05). pp. 1207-1215. ISSN 0039-7881

Stevens, MIchael A and Hashim, Fairuz H. and Gwee, Eunice S. H. and Izgorodina, Ekaterina I. and Mulvey, Robert E. and Blair, Victoria L. (2018) Contrasting synergistic heterobimetallic (Na-Mg) and homometallic (Na or Mg) bases in metalation reactions of dialkylphenylphosphines and dialkylanilines : lateral vs ring selectivities. Chemistry - A European Journal, 24 (58). pp. 15669-15677. ISSN 1521-3765

Lemmerz, Lara E. and McLellan, Ross and Judge, Neil R. and Kennedy, Alan R. and Orr, Samantha A. and Uzelac, Marina and Hevia, Eva and Robertson, Stuart D. and Okuda, Jun and Mulvey, Robert E. (2018) Donor-influenced structure-activity correlations in stoichiometric and catalytic reactions of lithium monoamido-monohydrido-dialkylaluminates. Chemistry - A European Journal, 24 (39). pp. 9940-9948. ISSN 1521-3765

Pollard, Victoria A. and Fuentes, M. Àngeles and Kennedy, Alan R. and McLellan, Ross and Mulvey, Robert E. (2018) Comparing neutral (monometallic) and anionic (bimetallic) aluminium complexes in hydroboration catalysis : influences of lithium cooperation and ligand set. Angewandte Chemie International Edition. ISSN 1521-3773

Uzelac, Marina and Mulvey, Robert E. (2018) Trans-metal-trapping : concealed crossover complexes en route to transmetallation? Chemistry - A European Journal, 24 (31). pp. 7786-7793. ISSN 1521-3765

Pollard, Victoria A. and Orr, Samantha A. and McLellan, Ross and Kennedy, Alan R. and Hevia, Eva and Mulvey, Robert E. (2018) Lithium diamidodihydridoaluminates : bimetallic cooperativity in catalytic hydroboration and metallation applications. Chemical Communications, 54 (10). pp. 1233-1236. ISSN 1359-7345

Mulvey, Robert Emmet (2017) Benzene submits to main-group power. Science, 358 (6367). p. 1132. ISSN 0036-8075

McLellan, Ross and Kennedy, Alan R. and Mulvey, Robert E. and Orr, Samantha A. and Robertson, Stuart D. (2017) 1-Alkali-metal-2-alkyl-1,2-dihydropyridines : soluble hydride surrogates for catalytic dehydrogenative coupling and hydroboration applications. Chemistry - A European Journal, 23 (66). pp. 16853-16861. ISSN 1521-3765

McLellan, Ross and Uzelac, Marina and Kennedy, Alan R. and Hevia, Eva and Mulvey, Robert E. (2017) LiTMP trans-metal-trapping of fluorinated aromatic molecules : a comparative study of Al and Ga carbanion traps. Angewandte Chemie International Edition, 56 (32). pp. 9566-9570. ISSN 1521-3773

Campbell, Ross and Kennedy, Alan R. and McLellan, Ross and Robertson, Stuart D. and Sproules, Stephen and Mulvey, Robert E. (2017) Contrasting the Group 6 metal-metal bonding in sodium dichromate(II) and sodium dimolybdate(II) polymethyl complexes : synthetic, x-ray crystallographic and theoretical studies. Dalton Transactions, 46. pp. 6392-6403. ISSN 1477-9226

McLellan, Ross and Kennedy, Alan R. and Orr, Samantha A. and Robertson, Stuart D. and Mulvey, Robert E. (2017) Lithium dihydropyridine dehydrogenation catalysis : a group 1 approach to cyclisation of diamine-boranes. Angewandte Chemie International Edition, 56 (4). pp. 1036-1041. ISSN 1521-3773

Fuentes, Maria Ángeles and Martínez-Martínez, Antonio J. and Kennedy, Alan R. and Mulvey, Robert E. (2016) Revealing the remarkable structural diversity of the alkali metal transfer agents of the trans-calix[2]benzene[2]pyrrolidide ligand. Chemical Communications, 52 (82). pp. 12199-12201. ISSN 1359-7345

Uzelac, Marina and Kennedy, Alan R. and Hevia, Eva and Mulvey, Robert E. (2016) Transforming LiTMP lithiation of challenging diazines via gallium alkyl trans-metal-trapping. Angewandte Chemie International Edition, 55. pp. 13147-13150. ISSN 1521-3773

Fuentes, M. Angeles and Zabala, Andoni and Kennedy, Alan R. and Mulvey, Robert E. (2016) Structural diversity in alkali metal and alkali metal magnesiate chemistry of the bulky 2,6-diisopropyl-N-(trimethylsilyl)anilino ligand. Chemistry - A European Journal, 22. pp. 14968-14978. ISSN 1521-3765

Orr, Samantha A. and Kennedy, Alan R. and Liggat, John J. and McLellan, Ross and Mulvey, Robert E. and Robertson, Stuart D. (2016) Accessible heavier s-block dihydropyridines : structural elucidation and reactivity of isolable molecular hydride sources. Dalton Transactions, 45 (14). pp. 6234-6240. ISSN 1477-9226

Brouillet, Etienne V. and Kennedy, Alan R. and Koszinowski, Konrad and McLellan, Ross and Mulvey, Robert E. and Robertson, Stuart D. (2016) Exposing elusive cationic magnesium-chloro aggregates in aluminate complexes through donor control. Dalton Transactions, 45 (13). pp. 5590-5597. ISSN 1477-9226

Kennedy, Alan R. and McLellan, Ross and McNeil, Greg J. and Mulvey, Robert E. and Robertson, Stuart D. (2016) Tetraamine Me6TREN induced monomerization of alkali metal borohydrides and aluminohydrides. Polyhedron, 103A. pp. 94-99. ISSN 0277-5387

Martínez-Martínez, Antonio J. and Fuentes, M. Ángeles and Hernán-Gõmez, Alberto and Hevia, Eva and Kennedy, Alan R. and Mulvey, Robert E. and O'Hara, Charles T. (2015) Alkali-metal-mediated magnesiations of an N-heterocyclic carbene : normal, abnormal and "paranormal" reactivity in a single tritopic molecule. Angewandte Chemie International Edition, 54 (47). pp. 14075-14079. ISSN 1521-3773

Fuentes, M. Ángeles and Kennedy, Alan R. and Mulvey, Robert E. and Parkinson, John A. and Rantanen, Toni and Robertson, Stuart D. and Snieckus, Victor (2015) Adding a structural context to the deprotometalation and trans-metal trapping chemistry of phenyl-substituted benzotriazole. Chemistry - A European Journal, 21 (42). pp. 14812-14822. ISSN 1521-3765

Robertson, Stuart D. and Kennedy, Alan R. and Liggat, John J. and Mulvey, Robert E. (2015) Facile synthesis of a genuinely alkane-soluble but isolable lithium hydride transfer reagent. Chemical Communications, 51 (25). pp. 5452-5455. ISSN 1359-7345

Kennedy, Alan R. and Mulvey, Robert E. and Ramsay, Donna L. and Robertson, Stuart D. (2015) Heterobimetallic metallation studies of N,N-dimethylphenylethylamine (DMPEA) : benzylic C-H bond cleavage/dimethylamino capture or intact DMPEA complex. Dalton Transactions, 44 (12). pp. 5875-5887. ISSN 1477-9226

Armstrong, David R. and Harris, Catriona M. M. and Kennedy, Alan R. and Liggat, John J. and McLellan, Ross and Mulvey, Robert E. and Urquhart, Matthew D. T. and Robertson, Stuart D. (2015) Developing lithium chemistry of 1,2-dihydropyridines : from kinetic intermediates to isolable characterized compounds. Chemistry - A European Journal, 21 (41). pp. 14410-14420. ISSN 1521-3765

Clegg, William and Crosbie, Elaine and Dale-Black, Sophie H. and Hevia, Eva and Honeyman, Gordon W. and Kennedy, Alan R. and Mulvey, Robert E. and Ramsay, Donna L. and Robertson, Stuart D. (2015) Structurally defined zincated and aluminated complexes of ferrocene made by alkali-metal-synergistic syntheses. Organometallics, 34 (11). pp. 2580-2589. ISSN 0276-7333

Martínez-Martínez, Antonio J. and Kennedy, Alan R and Mulvey, Robert E and O'Hara, Charles T (2014) Directed ortho-meta'- and meta-meta'-dimetalations : a template base approach to deprotonation. Science, 346 (6211). pp. 834-837. ISSN 0036-8075

Armstrong, David R. and Brouillet, Etienne V. and Kennedy, Alan R. and Garden, Jennifer A. and Granitzka, Markus and Mulvey, Robert E. and Trivett, Joshua J. (2014) Donor-activated alkali metal dipyridylamides : co-complexation reactions with zinc alkyls and reactivity studies with benzophenone. Dalton Transactions, 43 (38). pp. 14409-14423. ISSN 1477-9226

Kennedy, Alan R. and Mulvey, Robert E. and Urquhart, Robert I. and Robertson, Stuart D. (2014) Lithium, sodium and potassium picolyl complexes : syntheses, structures and bonding. Dalton Transactions, 43 (38). pp. 14265-14274. ISSN 1477-9226

Kennedy, Alan R. and Leenhouts, Sarah M. and Liggat, John J. and Martínez-Martínez, Antonio J. and Miller, Kimberley and Mulvey, Robert E. and O'Hara, Charles T. and O'Keefe, Philip and Steven, Alan (2014) Dehydromethylation of alkali metal salts of the utility amide 2,2,6,6-tetramethylpiperidide (TMP). Chemical Communications, 50 (73). pp. 10588-10591. ISSN 1359-7345

Armstrong, David R. and Crosbie, Elaine and Hevia, Eva and Mulvey, Robert E. and Ramsay, Donna L. and Robertson, Stuart D. (2014) TMP (2,2,6,6-tetramethylpiperidide)-aluminate bases : lithium-mediated alumination or lithiation-alkylaluminium-trapping reagents? Chemical Science, 5 (8). pp. 3031-3045. ISSN 2041-6539

Hernán-Gómez, Alberto and Herd, Emma and Hevia, Eva and Kennedy, Alan R. and Knochel, Paul and Koszinowski, Konrad and Manolikakes, Sophia M. and Mulvey, Robert E. and Schnegelsberg, Christoph (2014) Organozinc pivalate reagents : segregation, solubility, stabilisation and structural insights. Angewandte Chemie International Edition, 53 (10). 2706–2710. ISSN 1521-3773

Kennedy, Alan and Klett, Jan and McGrath, Graeme and Mulvey, Robert and Robertson, Gemma and Robertson, Stuart and O'Hara, Charles (2014) Synthesis of an alkylmagnesium amide and interception of a ring-opened isomer of the important utility amide 2,2,6,6-tetramethylpiperidide (TMP). Inorganica Chimica Acta, 411. pp. 1-4. ISSN 0020-1693

Martinez-Martinez, A. J. and Armstrong, D. R. and Conway, B. and Fleming, B. J. and Klett, J. and Kennedy, A. R. and Mulvey, R. E. and Robertson, S. D. and O'Hara, C. T. (2014) Pre-inverse-crowns : synthetic, structural and reactivity studies of alkali metal magnesiates primed for inverse crown formation. Chemical Science, 5 (2). pp. 771-781. ISSN 2041-6539

Mulvey, Robert E. and Robertson, Stuart D. (2013) Synthetically important alkali-metal-utility amides : lithium, sodium and potassium hexamethyldisilazides, diisopropylamides and tetramethylpiperidides. Angewandte Chemie International Edition, 52 (44). 11470–11487. ISSN 1521-3773

Garden, Jennifer and Armstrong, David and Clegg, William and Garcia Alvarez, Joaquin and Hevia, Eva and Kennedy, Alan and Mulvey, Robert and Robertson, Stuart and Russo, Luca (2013) Donor-activated lithiation and sodiation of trifluoromethylbenzene : structural, spectroscopic and theoretical insights. Organometallics, 32 (19). pp. 5481-5490. ISSN 0276-7333

Hevia, Eva and Kennedy, Alan R. and Mulvey, Robert E. and Ramsay, Donna L. and Robertson, Stuart D. (2013) Concealed cyclotrimeric polymorph of lithium 2, 2, 6, 6- tetramethylpiperidide unconcealed : X-ray crystallographic and NMR spectroscopic studies. Chemistry - A European Journal, 19 (42). pp. 14069-14075. ISSN 1521-3765

Armstrong, David R. and Davidson, Matthew G. and Garcia-Vivo, Daniel and Kennedy, Alan R. and Mulvey, Robert E. and Robertson, Stuart D. (2013) Monomerizing alkali-metal 3,5-dimethylbenzyl salts with tris(N, N -dimethyl-2-aminoethyl)amine (MeTREN) : structural and bonding implications. Inorganic Chemistry, 52 (20). pp. 12023-12032. ISSN 1520-510X

Armstrong, D.R. and Garden, J.A. and Kennedy, A.R. and Leenhouts, S.M. and Mulvey, R.E. and O'Keefe, P. and O'Hara, C.T. and Steven, A. (2013) Evaluating cis-2,6-dimethylpiperidide (cis-DMP) as a base component in lithium-mediated zincation chemistry. Chemistry - A European Journal, 19 (40). pp. 13492-13503. ISSN 1521-3765

Armstrong, David R. and Garden, Jennifer A. and Kennedy, Alan and Mulvey, Robert and Robertson, Stuart D. (2013) Modifying alkylzinc reactivity with 2,2 '-dipyridylamide : activation of tBu-Zn bonds for para-alkylation of benzophenone. Angewandte Chemie International Edition, 52 (28). pp. 7190-7193. ISSN 1521-3773

Campbell, R. and Crosbie, E. and Kennedy, A.R. and Mulvey, R.E. and Naismith, R.A. and Robertson, Stuart (2013) Contrasting reactivity of mono- versus Bis-2,2,6,6-tetramethylpiperidide lithium aluminates towards polydentate lewis bases : co-complexation versus deprotonation. Australian Journal of Chemistry, 66 (10). pp. 1189-1201. ISSN 0004-9425

Clegg, William and Fleming, Ben J. and Garcia-Alvarez, Pablo and Hogg, Lorna M. and Kennedy, Alan R. and Klett, Jan and Martinez-Martinez, Antonio J. and Mulvey, Robert E. and Russo, Luca and O'Hara, Charles T. (2013) Structural elucidation of homometallic anthracenolates synthesised via deprotonative metallation of anthrone. Dalton Transactions, 42 (7). pp. 2512-2519. ISSN 1477-9226

Mulvey, Robert E. (2013) An alternative picture of alkali-metal-mediated metallation : cleave and capture chemistry. Dalton Transactions, 42 (19). pp. 6676-6693. ISSN 1477-9226

Armstrong, David R. and Kennedy, Alan R. and Mulvey, Robert E. and Robertson, Stuart D. (2013) A hetero-alkali-metal version of the utility amide LDA : lithium-potassium diisopropylamide. Dalton Transactions, 42 (10). pp. 3704-3711. ISSN 1477-9226

Kennedy, Alan and Mulvey, Robert and O'Hara, Charles and Robertson, Stuart and Robertson, Gemma (2012) catena-Poly[sodium-2-(N,N,N',N'-tetramethylethane-1,2-diamine)-2N:N'-sodium-bis[2-bis(trimethylsilyl)azanido-2N:N]]. Acta Crystallographica Section E: Structure Reports, E68 (12). m1468. ISSN 1600-5368

Balloch, Liam and Garden, Jennifer A. and Kennedy, Alan and Mulvey, Robert E. and Rantanen, Toni and Robertson, Stuart D. and Snieckus, Victor (2012) Dizincation of a 2-substituted thiophene : constructing a cage with a [16]crown-4 zincocyclic core. Agewandte Chemie-International Edition, 51 (28). pp. 6934-6937. ISSN 1521-3773

Clegg, William and Klett, Jan and Mulvey, Robert E. and Russo, Luca and Kennedy, Alan (2012) Adding rubidium and cesium to the homologous series of alkali metal compounds of (Trimethylsilyl)methanides and 2,2,6,6-Tetramethylpiperidides. European Journal of Inorganic Chemistry, 2012 (18). pp. 2989-2994. ISSN 1434-1948

Cadenbach, Thomas and Hevia, Eva and Kennedy, Alan and Mulvey, Robert E. and Pickrell, Janie-Anne and Robertson, Stuart D. (2012) Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire. Dalton Transactions, 41 (34). pp. 10141-10144. ISSN 1477-9226

Crosbie, Elaine and Kennedy, Alan and Mulvey, Robert E. and Robertson, Stuart D. (2012) After-effects of lithium-mediated alumination of 3-iodoanisole: isolation of molecular salt elimination and trapped-benzyne products. Dalton Transactions, 41 (6). pp. 1832-1839. ISSN 1477-9226

Garden, Jennifer A. and Kennedy, Alan R. and Mulvey, Robert E. and Robertson, Stuart D. (2012) Ambient temperature zincation of N-Boc pyrrolidine and its solvent dependency. Chemical Communications, 48 (43). pp. 5265-5267. ISSN 1359-7345

Mulvey, Robert (2012) Interview with Robert Mulvey. Chemical Communications, 48 (39). pp. 4657-4658. ISSN 1359-7345

Armstrong, David R. and Kennedy, Alan and Mulvey, Robert E. and Parkinson, John A. and Robertson, Stuart D. (2012) Opening the black box of mixed-metal TMP metallating reagents : direct cadmation or lithium-cadmium transmetallation? Chemical Science, 3 (9). pp. 2700-2707. ISSN 2041-6539

Conway, Benjamin Grant and Crosbie, Elaine and Kennedy, Alan and Mulvey, Robert E. and Robertson, Stuart D. (2012) Regioselective heterohalogenation of 4-halo-anisoles via a series of sequential ortho-aluminations and electrophilic halogenations. Chemical Communications, 48 (39). pp. 4674-4676. ISSN 1359-7345

Armstrong, D. R. and Balloch, L. and Crawford, J. J. and Fleming, B. J. and Hogg, L. M. and Kennedy, A. R. and Klett, J. and Mulvey, R. E. and O'Hara, C. T. and Orr, S. A. and Robertson, Stuart (2012) Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] towards TEMPO and chalcone. Chemical Communications, 48 (10). pp. 1541-1543. ISSN 1359-7345

Mulvey, Robert and Armstrong, David R. and Conway, Ben and Crosbie, Elaine and Kennedy, Alan and Robertson, Stuart (2011) Structurally powered synergic 2,2,6,6-tetramethylpiperidine bimetallics: new reflections through lithium-mediated ortho aluminations. Inorganic Chemistry, 50 (24). pp. 12241-12251. ISSN 1520-510X

Garcia-Alvarez, Pablo and Mulvey, Robert and Parkinson, John (2011) “LiZn(TMP)3”, a zincate or a turbo-lithium amide reagent? : DOSY NMR spectroscopic evidence. Angewandte Chemie, 50 (41). pp. 9668-9671. ISSN 1521-3773

Kennedy, Alan and Klett, Jan and Robertson, Stuart and Mulvey, Robert (2011) N-heterocyclic-carbene-induced monomerization of sterically encumbered dialkylmagnesium and dialkylmanganese polymers. European Journal of Inorganic Chemistry (30). pp. 4675-4679. ISSN 1434-1948

Hevia, Eva and Mulvey, Robert (2011) A record-breaking magnesium hydride molecular cluster : implications for hydrogen storage. Angewandte Chemie, 50 (40). pp. 9242-9243. ISSN 1521-3773

Armstrong, David R. and Balloch, Liam and Hevia, Eva and Kennedy, Alan R. and Mulvey, Robert E. and O'Hara, Charles T. and Robertson, Stuart D. (2011) Meta-metallation of N,N-dimethylaniline: contrasting direct sodium-mediated zincation with indirect sodiation-dialkylzinc co-complexation. Beilstein Journal of Organic Chemistry, 7. pp. 1234-1248.

Campbell, Ross and Cannon, Daniel and Garcia-Alvarez, Pablo and Kennedy, Alan R. and Mulvey, Robert E. and Robertson, Stuart D. and Sassmannshausen, Joerg and Tuttle, Tell (2011) Main group multiple C-H/N-H bond activation of a diamine and isolation of a molecular dilithium zincate hydride : experimental and DFT evidence for Alkali metal-zinc synergistic effects. Journal of the American Chemical Society, 133 (34). pp. 13706-13717. ISSN 1520-5126

Fyfe, Andrew A. and Kennedy, Alan R. and Klett, Jan and Mulvey, Robert E. (2011) Crossing organolithium compounds with organolithium compounds : molecular squares and a cage-encapsulating reaction. Angewandte Chemie, 50 (34). pp. 7776-7780. ISSN 1521-3773

Armstrong, David R. and Kennedy, Alan R. and Mulvey, Robert E. and Robertson, Stuart D. (2011) Developing a hetero-alkali-metal chemistry of 2,2,6,6-tetramethylpiperidide (TMP) : stoichiometric and structural diversity within a series of lithium/sodium, lithium/potassium and sodium/potassium TMP compounds. Chemistry - A European Journal, 17 (32). pp. 8820-8831. ISSN 1521-3765

Kennedy, Alan and Mulvey, Robert and O'Hara, Charles and Robertson, Gemma and Robertson, Stuart (2011) Mixed lithium amide–lithium halide compounds : unusual halide-deficient amido metal anionic crowns. Angewandte Chemie, 50 (36). pp. 8375-8378. ISSN 1521-3773

Hevia, Eva and Mulvey, Robert E. (2011) Split personality of lithium chloride : recent salt effects in organometallic recipes. Angewandte Chemie, 50 (29). pp. 6448-6450. ISSN 1521-3773

Balloch, Liam and Kennedy, Alan R. and Mulvey, Robert E. and Robertson, Stuart D. (2011) A mu(4)-oxide-containing a dimeric variant of a sodium dialkyl(amido)zincate reagent. Acta Crystallographica Section C: Crystal Structure Communications, 67 (7). M252-M254. ISSN 0108-2701

Armstrong, David R. and Garcia-Alvarez, Pablo and Kennedy, Alan R. and Mulvey, Robert E. and Robertson, Stuart D. (2011) Molecular structures of THF-solvated alkali-metal 2,2,6,6-tetramethylpiperidides finally revealed: x-ray crystallographic, DFT, and NMR (including DOSY) spectroscopic studies. Chemistry - A European Journal, 17 (24). pp. 6725-6730. ISSN 1521-3765

Campbell, Ross and Carrella, Luca M. and Clegg, William and Mulvey, Robert E. and Rentschler, Eva and Robertson, Stuart D. and Russo, Luca (2011) Sodium congener of the classical lithium methylchromate dimer: synthetic, x-ray crystallographic, and magnetic studies of Me8Cr2[Na(OEt2)](4). Inorganic Chemistry, 50 (10). pp. 4656-4659. ISSN 1520-510X

Davidson, Matthew G. and Garcia-Vivo, Daniel and Kennedy, Alan R. and Mulvey, Robert E. and Robertson, Stuart D. (2011) Exploiting sigma/pi coordination isomerism to prepare homologous organoalkali metal (Li, Na, K) monomers with identical ligand sets. Chemistry - A European Journal, 17 (12). pp. 3364-3369. ISSN 1521-3765

Clegg, William and Conway, Benjamin Grant and Kennedy, Alan R. and Klett, Jan and Mulvey, Robert E. and Russo, Luca (2011) Synthesis and structures of [(trimethylsilyl)methyl]sodium and -potassium with bi- and tridentate n-donor ligands. European Journal of Inorganic Chemistry, 2011 (5). pp. 721-726. ISSN 1434-1948

Balloch, Liam and Kennedy, Alan R. and Mulvey, Robert E. and Rantanen, Toni and Robertson, Stuart D. and Snieckus, Victor (2011) Concerning the structures of alkali-metal-mediated ortho zincation of benzamides and phenyl o-carbamate. Organometallics, 30 (1). pp. 145-152. ISSN 0276-7333

Garcia, Felipe and Less, Robert J. and McPartlin, Mary and Michalski, Annette and Mulvey, Robert E. and Naseri, Vesal and Stead, Matthew L. and de Vega, Ana Moran and Wright, Dominic S. (2011) Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity. Chemical Communications (London), 47 (6). pp. 1821-1823. ISSN 0009-241X

Garden, Jennifer A. and Kennedy, Alan and Mulvey, Robert and Robertson, Stuart (2011) Neutral zinc, lower-order zincate and higher-order zincate derivatives of pyrrole: synthesis and structural characterisation of zinc complexes with one, two, three or four pyrrolyl ligands. Dalton Transactions, 40 (44). pp. 11945-11954. ISSN 1472-7773

Carrella, Luca M. and Forster, Christoph and Kennedy, Alan R. and Klett, Jan and Mulvey, Robert E. and Rentschler, Eva (2010) Synthesis and structure of a potassium potassiochromate : a bis-chromium(II) molecule held together by near-square-planar potassium-ligand bridges. Organometallics, 29 (21). pp. 4756-4758. ISSN 0276-7333

Campbell, Ross and Garcia-Alvarez, Pablo and Kennedy, Alan R. and Mulvey, Robert E. (2010) Synergic transformation of an ethylenediamine to a lithium 1,3-diaza-2-zincacyclopentene via an alkyllithium/bis(alkyl)zinc mixture. Chemistry - A European Journal, 16 (33). pp. 9964-9968. ISSN 1521-3765

Kennedy, Alan R. and Mulvey, Robert E. and Robertson, Stuart (2010) N-Heterocyclic carbene stabilized adducts of alkyl magnesium amide, bisalkyl magnesium and Grignard reagents : trapping oligomeric organo s-block fragments with NHCs. Dalton Transactions, 39 (38). pp. 9091-9099. ISSN 1472-7773

Blair, Victoria L. and Kennedy, Alan R. and Mulvey, Robert E. and O'Hara, Charles T. (2010) Sodium-mediated magnesiation of thiophene and tetrahydrothiophene : structural contrasts with furan and tetrahydrofuran. Chemistry - A European Journal, 16 (29). pp. 8600-8604. ISSN 1521-3765

Armstrong, David R. and Blair, Victoria L. and Clegg, William and Dale, Sophie H. and Garcia-Alvarez, Joaquin and Honeyman, Gordon W. and Hevia, Eva and Mulvey, Robert E. and Russo, Luca (2010) Structural basis for regioisomerization in the alkali-metal-mediated zincation (AMMZn) of trifluoromethyl benzene by isolation of kinetic and thermodynamic intermediates. Journal of the American Chemical Society, 132 (27). pp. 9480-9487. ISSN 1520-5126

Mulvey, R.E. and Blair, V.L. and Clegg, William and Kennedy, A.R. and Klett, J. and Russo, L. (2010) Cleave and capture chemistry illustrated through bimetallic-induced fragmentation of tetrahydrofuran. Nature Chemistry, 2. pp. 588-591. ISSN 1755-4330

Armstrong, David R. and Garcia-Álvarez, Pablo and Kennedy, Alan R. and Mulvey, Robert E. and Parkinson, John A. (2010) Diisopropylamide and TMP turbo-grignard reagents : a structural rationale for their contrasting reactivities. Angewandte Chemie International Edition, 49 (18). 3185–3188. ISSN 1521-3773

Conway, B. and Kennedy, A.R. and Mulvey, R.E. and Robertson, Stuart D. and Garcia Alvarez, Joaquin (2010) Structurally stimulated deprotonation/alumination of the TMP anion. Angewandte Chemie, 49 (18). pp. 3182-3184. ISSN 1521-3773

Balloch, Liam and Kennedy, Alan R. and Klett, Jan and Mulvey, Robert E. and O'Hara, Charles T. (2010) Structural elaboration of the surprising ortho-zincation of benzyl methyl ether. Chemical Communications (London), 46 (13). pp. 2319-2321. ISSN 0009-241X

Forret, Robert and Kennedy, Alan R. and Klett, Jan and Mulvey, Robert E. and Robertson, Stuart D. (2010) Multistep self-assembly of heteroleptic magnesium and sodium-magnesium benzamidinate complexes. Organometallics, 29 (6). pp. 1436-1442. ISSN 0276-7333

Mulvey, R.E. and Kennedy, A.R. and Robertson, Stuart (2010) Lithium and aluminium carbamato derivatives of the utility amide 2, 2, 6, 6- tetramethylpiperidide. Dalton Transactions, 39. pp. 6190-6197. ISSN 1472-7773

Clegg, William and Conway, Ben and García-Álvarez, Pablo and Kennedy, Alan R. and Klett, Jan and Mulvey, Robert E. and Russo, Luca (2010) Potassium-mediated zincation of ferrocene and ruthenocene : potassium, the architect behind supramolecular structural variations. Dalton Transactions, 39. pp. 62-65. ISSN 1472-7773

Mulvey, R.E. and Naseri, Vasel and Less, R.J. and McPartlin, Mary and Wright, Dominic S. (2010) Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines. Chemical Communications (London), 46 (27). pp. 5000-5002. ISSN 0009-241X

Conway, Ben and Garcia-Alvarez, Pablo and Kennedy, Alan R. and Klett, Jan and Mulvey, Robert E. and Robertson, Stuart D. (2010) Structural insights into mono-amido tris-alkyl potassium aluminates. New Journal of Chemistry, 34 (8). pp. 1707-1712. ISSN 1144-0546

Crosbie, Elaine and Garcia-Alvarez, Pablo and Kennedy, Alan R. and Klett, Jan and Mulvey, Robert E. and Robertson, Stuart D. (2010) Structurally engineered deprotonation/alumination of THF and THTP with retention of their cycloanionic structures. Angewandte Chemie International Edition, 49 (49). pp. 9388-9391. ISSN 1521-3773

Campbell, R. and Conway, B. and Garcia-Alvarez, P. and Kennedy, A.R. and Klett, J. and O'Hara, C.T. and Mulvey, R.E. and Robertson, G., EPSRC (Funder) (2010) cis-2,6-Dimethylpiperidide: a structural mimic for TMP (2,2,6,6-tetramethypiperidide) or DA (diisopropylamide)? Dalton Transactions, 39. pp. 511-519. ISSN 1472-7773

Conway, Ben and Garcia-Alvarez, Joaquin and Hevia, Eva and Kennedy, Alan R. and Mulvey, Robert E. and Robertson, Stuart D. (2009) Contacted ion-pair lithium alkylamidoaluminates: intramolecular alumination (al-h exchange) traps for tmeda and pmdeta. Organometallics, 28 (22). pp. 6462-6468. ISSN 0276-7333

Armstrong, D.R. and Balloch, L. and Clegg, William and Dale, S.H. and Garcia-Alvarez, P. and Hevia, E. and Hogg, L.M. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, Charles (2009) Synergic synthesis of benzannulated zincabicyclic complexes, alpha-zincated n ylides, through sodium-TMEDA-mediated zincation of a haloarene. Angewandte Chemie, 48 (46). pp. 8675-8678. ISSN 1521-3773

Kennedy, Alan R. and Klett, Jan and O'Hara, Charles T. and Mulvey, Robert E. and Robertson, Gemma M. (2009) Structural elucidation of tmeda-solvated alkali metal diphenylamide complexes. European Journal of Inorganic Chemistry, 2009 (33). pp. 5029-5035. ISSN 1434-1948

Kennedy, A.R. and Klett, J. and Mulvey, R.E. and Wright, D.S. (2009) Synergic sedation of sensitive anions : alkali-mediated zincation of cyclic ethers and ethene. Science, 326 (5953). pp. 706-708. ISSN 0036-8075

Blair, V.L. and Clegg, W. and Mulvey, R.E. and Russo, L. (2009) Alkali-metal-mediated manganation(II) of naphthalenes: constructing metal la-anthracene and metalla-phenanthrene structures. Inorganic Chemistry, 48 (18). pp. 8863-8870. ISSN 1520-510X

Clegg, W. and Conway, B. and Graham, D.V. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. and Russo, L. and Wright, D.S. (2009) Structurally defined potassium-mediated zincation of pyridine and 4-R-substituted pyridines (R = Et, iPr, tBu, Ph, and Me2N) by using dialkyl-tmp-zincate bases. Chemistry - A European Journal, 15 (29). pp. 7074-7082. ISSN 1521-3765

Mulvey, Robert E. (2009) Avant-garde metalating agents: Structural basis of alkali-metal-mediated metalation. Accounts of Chemical Research, 42 (6). pp. 743-755. ISSN 0001-4842

Balloch, L. and Drummond, A.M. and Garcia-Alvarez, P. and Graham, D.V. and Kennedy, A.R. and Klett, J. and Mulvey, R.E. and O'Hara, C.T. and Rodger, P.J.A. and Rushworth, Iain David (2009) Structural variations within group 1 (Li-Cs)(+)(2,2,6,6-tetramethyl-1-piperidinyloxy)(-) complexes made via metallic reduction of the nitroxyl radical. Inorganic Chemistry, 48 (14). pp. 6934-6944. ISSN 1520-510X

Alberola, A. and Blair, V.L. and Carrella, L.M. and Clegg, W. and Kennedy, A.R. and Klett, J. and Mulvey, R.E. and Newton, S. (2009) Bis[(trimethylsilyl)methyl]manganese: structural variations of its solvent-free and tmeda-, pyridine-, and dioxane-complexed forms. Organometallics, 28 (7). pp. 2112-2118. ISSN 0276-7333

Clegg, W. and Conway, B. and Hevia, E. and McCall, M.D. and Russo, L. and Mulvey, R.E. (2009) Closer insight into the reactivity of TMP-dialkyl zincates in directed ortho-zincation of anisole : experimental evidence of amido basicity and structural elucidation of key reaction intermediates. Journal of the American Chemical Society, 131 (6). pp. 2375-2384. ISSN 1520-5126

Blair, V.L. and Carrella, L.M. and Clegg, W. and Klett, J. and Mulvey, R.E. and Rentschler, E. and Russo, L. (2009) Structural and magnetic insights into the trinuclear ferrocenophane and unexpected hydrido inverse crown products of alkali-metal-mediated manganation(ii) of ferrocene. Chemistry - A European Journal, 15 (4). pp. 856-863. ISSN 1521-3765

Albores, Pablo and Carrella, L.M. and Clegg, W. and Garcia-Alvarez, P. and Kennedy, A.R. and Klett, J. and Mulvey, R.E. and Rentschler, E. and Russo, Luca (2009) Direct C-H metalation with chromium(ii) and iron(ii) : transition-metal host/benzenediide guest magnetic inverse-crown complexes. Angewandte Chemie, 48 (18). pp. 3317-3321. ISSN 1521-3773

Clegg, W. and Conway, B. and Garcia-Alvarez, P. and Kennedy, A.R. and Mulvey, R.E. and Russo, L. and Sassmannshausen, J. and Tuttle, Tell (2009) Structural tracking of the potassium-mediated magnesiation of anisole. Chemistry - A European Journal, 15 (41). pp. 10702-10706. ISSN 1521-3765

Armstrong, D.R. and Garcia-Alvarez, J. and Graham, D.V. and Honeyman, G.W. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. (2009) Synthetic and structural insights into the zincation of toluene: direct synergic ring metallation versus indirect nonsynergic lateral metallation. Chemistry - A European Journal, 15 (15). pp. 3800-3807. ISSN 1521-3765

Garcia-Alvarez, P. and Graham, D.V. and Hevia, E. and Kennedy, A.R. and Klett, J. and Mulvey, R.E. and O'Hara, C.T. and Weatherstone, Susan (2008) Unmasking representative structures of tmp-active hauser and turbo-hauser bases. Angewandte Chemie, 47 (42). pp. 8079-8081. ISSN 1521-3773

Blair, V.L. and Carrella, L.M. and Clegg, W. and Conway, B. and Harrington, R.W. and Hogg, L.M. and Klett, J. and Mulvey, R.E. and Rentschler, Eva and Russo, Luca (2008) Tuning the basicity of synergic bimetallic reagents : switching the regioselectivity of the direct dimetalation of toluene from 2,5-to 3,5-positions. Angewandte Chemie, 47 (33). pp. 6208-6211. ISSN 1521-3773

Clegg, W. and Garcia-Alvarez, J. and Garcia-Alvarez, P. and Graham, D.V. and Harrington, R.W. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. (2008) Synthesis, structural authentication, and structurally defined metalation reactions of lithium and sodium da-zincate bases (da = diisopropylamide) with phenylacetylene. Organometallics, 27 (11). pp. 2654-2663. ISSN 0276-7333

Chan, W.T.K. and Eisler, D. and Garcia, F. and Gonzalez-Calera, S. and McPartlin, M. and Morey, J.V. and Mulvey, R.E. and Singh, S. (2008) Synthesis and structure of the li-13 cage [{[o - p(mu-(nbu)-bu-t)](2)li-2}(3)(licl)(6)li(cl/(obu)-bu-n)(0.5)(thf)(7)], containing a [o - p(mu-(nbu)-bu-t)](2)(2-) dianion. Chemical Communications (London) (19). pp. 2251-2253. ISSN 0009-241X

Blair, V.L. and Clegg, W. and Conway, B. and Hevia, E. and Kennedy, A. and Klett, J. and Mulvey, R.E. and Russo, L. (2008) Alkali-metal-mediated manganation(ii) of functionalized arenes and applications of ortho-manganated products in pd-catalyzed cross-coupling reactions with iodobenzene. Chemistry - A European Journal, 14 (1). pp. 65-72. ISSN 1521-3765

Kennedy, A.R. and Klett, J. and Mulvey, R.E. and Newton, S. and Wright, D.S. (2008) Manganese(ii)-lithium and -sodium inverse crown ether (ICE) complexes. Chemical Communications (London) (3). pp. 308-310. ISSN 0009-241X

Blair, V.L. and Kennedy, A.R. and Klett, J. and Mulvey, R.E. (2008) Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like mg-3(2,5-fur-di-yl)(3) substructure. Chemical Communications (London) (42). pp. 5426-5428. ISSN 0009-241X

Clegg, W. and Dale, S.H. and Hevia, E. and Hogg, L.M. and Honeyman, G.W. and Mulvey, R.E. and O'Hara, C.T. and Russo, L. (2008) Structurally defined reactions of sodium tmp-zincate with nitrile compounds: synthesis of a salt-like sodium sodiumdizincate and other unexpected ion-pair products. Angewandte Chemie, 47 (4). pp. 731-734. ISSN 1521-3773

Conway, B. and Graham, D.V. and Hevia, E. and Kennedy, A.R. and Klett, J. and Mulvey, R.E. (2008) Structurally-defined potassium-mediated regioselective zincation of amino-and alkoxy-substituted pyridines. Chemical Communications (London) (23). pp. 2638-2640. ISSN 0009-241X

Garcia-Alvarez, J. and Graham, D.V. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. (2008) Synthesis and characterisation of new bimetallic alkali metal-magnesium mixed diisopropylamide-acetylides: structural variations in bimetallic lithium- and sodium-heteroleptic magnesiates. Dalton Transactions (11). pp. 1481-1486. ISSN 1472-7773

Armstrong, D.R. and Clegg, W. and Dale, S.H. and Garcia-Alvarez, Joaquin and Harrington, R.W. and Hevia, E. and Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. (2008) Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate. Chemical Communications (London) (2). pp. 187-189. ISSN 0009-241X

Edge, R. and Less, R.J. and Naseri, V. and McInnes, E.J.L. and Mulvey, R.E. and Wright, D.S. (2008) A mechanistic study of the c-p bond cleavage reaction of 1,2-(ph2)(2)-c6h4 with (buli)-bu-n/sb(nme2)(3). Dalton Transactions (45). pp. 6454-6460. ISSN 1472-7773

Armstrong, D.R. and Graham, D.V. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. (2008) A structural and computational study of synthetically important alkali-metal/tetramethylpiperidide (tmp) amine solvates. Chemistry - A European Journal, 14 (26). pp. 8025-8034. ISSN 1521-3765

Morris, J. Jacob and Noll, B.C. and Honeyman, Gordon William and O'Hara, C.T. and Kennedy, A.R. and Mulvey, R.E. and Henderson, K (2007) Organometallic polymers assembled from cation-p interactions : Use of ferrocene as a ditopic linker within the homologous series [{(Me3Si)2NM}2⋅(Cp2Fe)]∞ (M=Na, K, Rb, Cs; Cp=cyclopentadienyl). Chemistry - A European Journal, 13 (16). pp. 4418-4432. ISSN 1521-3765

Mulvey, R.E. and Mongin, F. and Uchiyama, M. and Kondo, Y. (2007) Deprotonative metalation using ate compounds: synergy, synthesis, and structure building. Angewandte Chemie, 46 (21). pp. 3802-3824. ISSN 1521-3773

Clegg, W. and Dale, S.H. and Graham, D.V. and Harrington, R.W. and Hevia, E. and Hogg, L.M. and Kennedy, A.R. and Mulvey, R.E. (2007) Structural variations in bimetallic sodium-magnesium and sodium-zinc ketimides, and a sodium-zinc alkide-alkoxide-amide: connections to ring-stacking, ring-laddering, and inverse crown concepts. Chemical Communications (London) (16). pp. 1641-1643. ISSN 0009-241X

Andrikopoulos, Prokopis C. and Armstrong, D.R. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Rowlings, Rene and Weatherstone, Susan (2007) Synthesis and structural characterisation of mixed alkalimetal-magnesium mixed ligand alkyl-amido ate complexes. Inorganica Chimica Acta, 360 (4). pp. 1370-1375. ISSN 0020-1693

Mulvey, R.E. and Kennedy, A.R. and Klett, J. and Hevia, E. and Garcia Alvarez, Joaquin (2007) Lewis base stabilized lithium TMP-aluminates: an unexpected fragmentation and capture reaction involving cyclic ether 1,4-dioxane. Chemical Communications (London) (23). pp. 2402-2404. ISSN 0009-241X

Mulvey, R.E. and Garcia-Alvarez, J. and Kennedy, A.R. and Klett, J. (2007) Alkali-metal-mediated manganation: a method for directly attaching manganese(II) centers to aromatic frameworks. Angewandte Chemie, 46 (7). pp. 1105-1108. ISSN 1521-3773

Armstrong, D.R. and Clegg, William and Dale, S.H. and Graham, D.V. and Hevia, E. and Hogg, L.M. and Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. (2007) Dizincation and dimagnesiation of benzene using alkali-metal-mediated metallation. Chemical Communications (London) (6). pp. 598-600. ISSN 0009-241X

Conway, B. and Hevia, E. and Garcia-Alvarez, J. and Graham, D.V. and Kennedy, A.R. and Mulvey, R.E. (2007) Isolation and structural elucidation of a key aluminoaromatic intermediate and evidence for dismutation phenomena in tmp-alumination chemistry. Chemical Communications (London) (48). pp. 5241-5243. ISSN 0009-241X

Carrella, L.M. and Clegg, William and Graham, D.V. and Hogg, L.M. and Kennedy, A.R. and Klett, J. and Mulvey, R.E. and Rentschler, E. (2007) Sodium-mediated manganation: direct mono- and dimanganation of benzene and synthesis of a transition-metal inverse-crown complex. Angewandte Chemie, 46 (25). pp. 4662-4666. ISSN 1521-3773

Mulvey, R.E. and Kennedy, A.R. and Hevia, E. (2007) Structurally-defined direct C-magnesiation and C-zincation of N-heterocyclic aromatic compounds using alkali-metal-mediated metallation. Chemical Communications (London) (27). pp. 2864-2866. ISSN 0009-241X

Baillie, S.H. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. (2006) Synthesis of mixed alkali-metal-zinc enolate complexes derived from 2,4,6-trimethylacetophenone: new inverse crown structures. Organometallics, 26 (1). pp. 204-209. ISSN 0276-7333

Graham, D.V. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. (2006) A polymeric solvent-free variant of a hydridomagnesium inverse crown. Acta Crystallographica Section C: Crystal Structure Communications, 62 (8). M366-M368. ISSN 0108-2701

Graham, D.V. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. (2006) Lithium dimethyl(amido)zinc complexes: contrasting zincate (amido = tmp) and inverse zincate (amido = hmds) structures on addition of TMEDA. Organometallics, 25 (14). pp. 3297-3300. ISSN 0276-7333

Clegg, W and Dale, S H and Drummond, A M and Hevia, E and Honeyman, G W and Mulvey, R E (2006) Alkali-metal-mediated zincation of anisole: synthesis and structures of three instructive ortho-zincated complexes. Journal of the American Chemical Society, 128 (23). pp. 7434-7435. ISSN 1520-5126

Hevia, E. and Henderson, K.W. and Kennedy, A.R. and Mulvey, R.E. (2006) Synthesis and characterization of new mixed-metal sodium-magnesium enolates derived from 2,4,6-trimethylacetophenone. Organometallics, 25 (7). pp. 1778-1785. ISSN 0276-7333

Graham, D.V. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Talmard, C. (2006) Building an extended inverse crown motif via alkali-metal-mediated alpha-magnesiation of furan. Chemical Communications (London), 2006 (4). pp. 417-419. ISSN 0009-241X

Mulvey, R.E. and Clegg, W. and Hevia, E. and O'Hara, C.T. and Dale, S.H. and Hogg, L.M. and Honeyman, G.W. (2006) Alkali-metal-mediated zincation of polycyclic aromatic hydrocarbons : synthesis and structures of mono- and dizincated naphthalenes. Angewandte Chemie, 45. pp. 6548-6550. ISSN 1521-3773

Mulvey, R.E. and Armstrong, David R. and Clegg, W. and Hevia, E. and Dale, S.H. and Hogg, L.M. and Honeyman, G.W. (2006) Directed meta-metalation using alkali-metal-mediated zincation. Angewandte Chemie, 45. pp. 3775-3778. ISSN 1521-3773

Garcia-Alvarez, J. and Graham, D.V. and Kennedy, A.R. and Mulvey, R.E. and Weatherstone, S. (2006) New reactivity and structural insights of alkali-metal-mediated alumination in directed ortho-alumination of a tertiary aromatic amide. Chemical Communications (London) (30). pp. 3208-3210. ISSN 0009-241X

Clegg, W and Dale, S H and Harrington, R W and Hevia, E and Honeyman, G W and Mulvey, R E (2006) Post-metalation structural insights into the use of alkali-metal-mediated zincation for directed ortho-metalation of a tertiary aromatic amide. Angewandte Chemie, 45 (15). pp. 2374-2377. ISSN 1521-3773

Clegg, W and Dale, S H and Hevia, E and Honeyman, G W and Mulvey, R E (2006) Pre-metalation structural insights into the use of alkali-metal-mediated zincation for directed ortho-metalation of a tertiary aromatic amide. Angewandte Chemie, 45 (15). pp. 2370-2374. ISSN 1521-3773

Hevia, E. and Armstrong, David R. and Kennedy, A. and Mulvey, R.E. (2006) Synergic para-directed-monometalation ofcby using alkali-metal-mediated magnesiation. Organometallics, 25. pp. 2415-2418. ISSN 0276-7333

Hevia, E. and Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. (2005) Trapping, stabilization, and characterization of an enolate anion of a 1,6-adduct of benzophenone chelated by a sodium alkylamidozincate cation. Journal of the American Chemical Society, 127 (38). pp. 13106-13107. ISSN 1520-5126

Barley, H.R.L. and Kennedy, A.R. and Mulvey, R.E. (2005) A mixed iron(III)/lithium alkoxide. Acta Crystallographica Section C: Crystal Structure Communications, 61 (7). M346-M347. ISSN 0108-2701

Andrikopoulos, Prokopis C. and Armstrong, David R. and Graham, David V. and Hevia, Eva and Kennedy, Alan R. and Mulvey, Robert E. and O'Hara, Charles T. and Talmard, Christine (2005) Selective meta-deprotonation of toluene by using alkali-metal-mediated magnesiation. Angewandte Chemie, 44 (22). pp. 3459-3462. ISSN 1521-3773

Andrikopoulos, P.C. and Armstrong, D.R. and Barley, H.R.L. and Clegg, W. and Dale, S.H. and Hevia, E. and Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. (2005) Sodium dialkyl-amidozincates: Alkyl or amido bases? An experimental and theoretical case study. Journal of the American Chemical Society, 127 (17). pp. 6184-6185. ISSN 1520-5126

Andrikopoulos, Prokopis C. and Armstrong, David R. and Hevia, Eva and Kennedy, Alan R. and Mulvey, Robert E. and O'Hara, Charles T. (2005) Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions. Chemical Communications (London), 2005 (9). pp. 1131-1133. ISSN 0009-241X

Barley, H.R.L. and Clegg, W. and Dale, S.H. and Hevia, E. and Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. (2005) Alkali-metal-mediated zineation of ferrocene: Synthesis, structure, and reactivity of a lithium tmp/zincate reagent. Angewandte Chemie, 44 (37). pp. 6018-6021. ISSN 1521-3773

Barnett, N.D.R. and Clegg, W. and Kennedy, A.R. and Mulvey, R.E. and Weatherstone, S. (2005) Crystallographic characterisation of binary alkali metal alkoxide magnesium bis(alkyl) mixtures: differential binding of Na+ and K+ to a common dinuclear diorganomagnesiate. Chemical Communications (London), 2005 (3). pp. 375-377. ISSN 0009-241X

Hevia, E. and Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. and Sherrington, D.C. (2005) Synergic monodeprotonation of bis(benzene)chromium by using mixed alkali metal-magnesium amide bases and structural characterization of the heterotrimetallic products. Angewandte Chemie, 44 (1). pp. 68-72. ISSN 1521-3773

Conway, B. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. and Weatherstone, S. (2005) Synthesis and characterisation of a series of alkylmagnesium amide and related oxygen-contaminated 'alkoxy' compounds. Dalton Transactions, 2005 (8). pp. 1532-1544. ISSN 1472-7773

Hevia, E. and Gallagher, D.J. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Talmard, C. (2004) Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns. Chemical Communications (London), 2004 (21). pp. 2422-2423. ISSN 0009-241X

Andrikopoulos, Prokopis C. and Armstrong, David R. and Clegg, William and Gilfillan, Carly J. and Hevia, Eva and Kennedy, Alan R. and Mulvey, Robert E. and O'Hara, Charles T. and Parkinson, John A. and Tooke, Duncan M. (2004) A homologous series of regioselectively tetradeprotonated group 8 metallocenes: New inverse crown ring compounds synthesized via a mixed sodium-magnesium tris(diisopropylamide) synergic base. Journal of the American Chemical Society, 126 (37). pp. 11612-11620. ISSN 1520-5126

He, X.Y. and Noll, B.C. and Beatty, A. and Mulvey, R.E. and Henderson, K.W. (2004) Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates. Journal of the American Chemical Society, 126 (24). pp. 7444-7445. ISSN 1520-5126

Hevia, E. and Kennedy, A.R. and Mulvey, R.E. and Weatherstone, S. (2004) Synthesis and crystal structure of [{nBuMg(mu-TMP)}(2)] and of a homometallic inverse crown in tetranuclear [{nBuMg(2)[mu-N(H)Dipp](2)(mu(3)-OnBu)}(2)]. Angewandte Chemie, 43 (13). pp. 1709-1712. ISSN 1521-3773

Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. and Sherrington, D.C. (2004) Synthesis, structure and methyl methacrylate polymerisation activity of a mixed pi-ferrocene pi-toluene complex of potassium tris(hexamethyldisilazide)magnesiate. Organometallics, 23 (6). pp. 1197-1199. ISSN 0276-7333

Hevia, E. and Kenley, F.R. and Kennedy, A.R. and Mulvey, R.E. and Rowlings, R.B. (2003) Solvent-free and TMEDA-solvated mixed alkali metal-magnesium tris-diisopropylamides. European Journal of Inorganic Chemistry, 2003 (18). pp. 3347-3353. ISSN 1434-1948

Andrikopoulos, P.C. and Armstrong, D.R. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Rowlings, R.B. (2003) Synthesis, structure and theoretical studies of the hydrido inverse crown [K2Mg2(NiPr2)(4)(mu-H)(2)center dot(toluene)(2)] : a rare example of a molecular magnesium hydride with a Mg-(mu-H)(2)-Mg double bridge. European Journal of Inorganic Chemistry, 2003 (18). pp. 3354-3362. ISSN 1434-1948

Kennedy, A.R. and MacLellan, J.G. and Mulvey, R.E. (2003) A new Na/Mg inverse crown ether. Acta Crystallographica Section C: Crystal Structure Communications, 59 (8). M302-M303. ISSN 0108-2701

Forbes, G.C. and Kenley, F.R. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Parkinson, J.A. (2003) Synthesis of the mixed lithium-potassium-(bis)magnesium N-metallated / N, C-dimetallated amide [Li2K2Mg4 {But(Me3Si)N} 4{But[Me2(H2C)Si]N}4] : an inverse crown molecule with an atomless cavity. Chemical Communications (London), 2003 (10). pp. 1140-1141. ISSN 0009-241X

Clegg, W. and Drummond, A.M. and Liddle, S.T. and Mulvey, R.E. (2003) A triclinic polymorph of octa-tert-butoxy-tetralithiumtetrasodium. Acta Crystallographica Section E: Structure Reports, 59 (2). M64-M66. ISSN 1600-5368

Henderson, K.W. and Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. and Parkinson, J.A. and Sherrington, D.C. (2003) Magnesium aryloxides: synthesis, structure, solution behavior and magnesiate ion formation. Dalton Transactions, 2003 (7). pp. 1365-1372. ISSN 1472-7773

Clegg, W. and Forbes, G.C. and Kennedy, A.R. and Mulvey, R.E. and Liddle, S.T. (2003) Potassium-zinc induced synergic enhancement of the basicity of hexamethyldisilazide (HMDS) towards methylbenzene molecules. Chemical Communications (London), 2003 (3). pp. 406-407. ISSN 0009-241X

Forbes, G.C. and Kennedy, A.R. and Mulvey, R.E. and Roberts, B.A. and Rowlings, R.B. (2002) Alkali metal cation-pi interactions stabilized solely by [M{N(SiMe3)(2)}(3)](-) anions (M = Mg or Zn): The competing influence of alkali metal center dot center dot center dot C(Me) agostic interactions. Organometallics, 21 (23). pp. 5115-5121. ISSN 0276-7333

Henderson, K.W. and Hind, A. and Kennedy, A.R. and McKeown, A.E. and Mulvey, R.E. (2002) Synthesis of zirconocene amides and ketimides and an investigation into their ethylene polymerization activity. Journal of Organometallic Chemistry, 656 (1-2). pp. 63-70. ISSN 0022-328X

Drewette, K.J. and Henderson, K.W. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Rowlings, R.B. (2002) Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal-magnesium-alkoxide-diisopropylamides. Chemical Communications (London), 2002 (11). pp. 1176-1177. ISSN 0009-241X

Kennedy, A.R. and Mulvey, R.E. and Rowlings, R.B. (2002) Synthesis and structural characterisation of 'solvent-free' lithium-calcium hexamethyldisilazide, [Li{mu-N(SiMe3)(2)}(2)Ca{N(SiMe3)(2)}], exhibiting a double ration of agostic H3C center dot center dot center dot Li and H3C center dot center dot center dot Ca intramolecular interactions. Journal of Organometallic Chemistry, 648 (1-2). pp. 288-292. ISSN 0022-328X

Armstrong, D.R. and Forbes, G.C. and Mulvey, R.E. and Clegg, W. and Tooke, D.M. (2002) An unexpected transamination of bis[bis(trimethylsilyl)amido]zinc with dibenzylamine to form bis( dibenzylamido)zinc: structural studies by NMR spectroscopy, X-ray crystallography and theoretical calculations. Dalton Transactions, 2002 (8). pp. 1656-1661. ISSN 1472-7773

Andrews, P.C. and MacLellan, J.G. and Mulvey, R.E. and Nichols, P.J. (2002) New homo- and hetero-alkali metal alkoxide cages: crystal structures of [Me2N(CH2)(2)OLi](8) and [{Me2N(CH2)(2)O}(12)Li8K6]O. Dalton Transactions, 2002 (8). pp. 1651-1655. ISSN 1472-7773

Drummond, A.M. and Gibson, L.T. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Rowlings, R.B. and Weightman, T. (2002) Hexameric Mg-O stacks with six THF-solvated sodium amide appendages: 'Super' variants of inverse crown ethers generated by cleavage of THF. Angewandte Chemie, 41 (13). pp. 2383-2384. ISSN 1521-3773

Gallagher, D.J. and Henderson, K.W. and Kennedy, A.R. and O'Hara, C.T. and Mulvey, R.E. and Rowlings, R.B. (2002) Hydride encapsulation in s-block metal inverse crown chemistry. Chemical Communications (London), 2002 (4). pp. 376-377. ISSN 0009-241X

Kennedy, A.R. and Mulvey, R.E. and Schulte, J.H. (2001) A monomeric three-coordinate magnesium bis(amide). Acta Crystallographica Section C: Crystal Structure Communications, 57 (11). pp. 1288-1289. ISSN 0108-2701

Henderson, K.W. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Rowlings, R.B. (2001) Trimagnesium-bridged trinuclear ferrocenophanes cocomplexed with solvated mononuclear alkali metal amide molecules. Chemical Communications (London), 2001 (17). pp. 1678-1679. ISSN 0009-241X

Mulvey, R.E. (2001) S-Block metal inverse crowns: synthetic and structural synergism in mixed alkali metal-magnesium (or zinc) amide chemistry. Chemical Communications (London), 2001 (12). pp. 1049-1056. ISSN 0009-241X

Henderson, K.W. and Kennedy, A.R. and McKeown, A.E. and Mulvey, R.E. (2001) Dichlorobis(dibenzylamino)bis(tetra-hydrofuran)zirconium(IV) toluene hemisolvate. Acta Crystallographica Section C: Crystal Structure Communications, 57 (6). pp. 674-675. ISSN 0108-2701

Armstrong, David R. and Clegg, William and Mulvey, Robert E. and Rowlings, René B. (2001) Synthesis and crystal structure of the new heteroleptic magnesium bis(amide) [{Mg[mu-N(H)Ph][N(SiMe3)(2)]center dot THF}(2)], and density functional MO calculations on model systems. Journal of the Chemical Society, Dalton Transactions, 2001 (4). pp. 409-413. ISSN 0300-9246

Kennedy, A.R. and MacLellan, J.G. and Mulvey, R.E. (2001) Landmark crystal structure of an experimentally utilized tetralithium-tetrapotassium amide-alkoxide superbase. Angewandte Chemie, 40 (17). pp. 3245-3247. ISSN 1521-3773

Clegg, W. and Henderson, K.W. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Rowlings, R.B. and Tooke, D.M. (2001) Regioselective tetrametalation of ferrocene in a single reaction: Extension of s-block inverse crown chemistry to the d-block. Angewandte Chemie, 40 (20). pp. 3902-3905. ISSN 1521-3773

Forbes, G.C. and Kennedy, A.R. and Mulvey, R.E. and Rodger, P.J.A. and Rowlings, R.B. (2001) Structural chemistry of monodentate donor-solvated mixed lithium-magnesium secondary amide complexes. Journal of the Chemical Society, Dalton Transactions, 2001 (9). pp. 1477-1484. ISSN 0300-9246

Forbes, G.C. and Kennedy, A.R. and Mulvey, R.E. and Rodger, P.J.A. (2001) TEMPO: a novel chameleonic ligand for s-block metal amide chemistry. Chemical Communications (London), 2001 (15). pp. 1400-1401. ISSN 0009-241X

Armstrong, D R and Clegg, W and Drummond, A M and Liddle, S T and Mulvey, Robert (2000) A remarkable isostructural homologous series of mixed lithium-heavier alkali metal tert-butoxides [(t-BuO)(8)Li4M4] (M = Na, K, Rb or Cs). Journal of the American Chemical Society, 122 (45). pp. 11117-11124. ISSN 1520-5126

Henderson, K.W. and Kennedy, A.R. and McKeown, A.E. and Mulvey, R.E. (2000) Formation of the unprecedented trilithio-capped heteroadamantanyl iminoalane anion [(HAl)4(NPh)6{Li(OEt2)}3]-: An open cage derived from a rhombododecahedron. Angewandte Chemie, 39 (21). pp. 3879-3880. ISSN 1521-3773

Kennedy, A.R. and MacLellan, J.G. and Mulvey, R.E. and Robertson, A. (2000) A new approach to lithium-heavier alkali metal interchange reactions: synthesis of a tetralithium pentasodium mixed alkoxide-amide dome-shaped cage compound with an encapsulated hydroxide molecule. Journal of the Chemical Society, Dalton Transactions, 2000 (22). pp. 4112-4116. ISSN 0300-9246

Armstrong, D.R. and Henderson, K.W. and Little, I. and Jenny, C. and Kennedy, A.R. and McKeown, A.E. and Mulvey, R.E. (2000) Zirconocene ketimides: Synthesis, structural characterization, ethylene polymerization activity, and ab initio computational studies. Organometallics, 19 (21). pp. 4369-4375. ISSN 0276-7333

Forbes, Glenn C. and Kennedy, Alan R. and Mulvey, Robert E. and Rowlings, Rene B. and Clegg, William and Liddle, Stephen T. and Wilson, Chick C. (2000) Inverse crown ether complexes extended to group 12 through the syntheses of [Na2Zn2(HMDS)(4)(O)] and [{K2Zn2(HMDS)(4)(O-2)(x)(O)(y)}(infinity)]. Chemical Communications (London), 2000 (18). pp. 1759-1760. ISSN 0009-241X

Kennedy, A.R. and MacLellan, J.G. and Moir, J.H. and Mulvey, R.E. and Rodger, P.J.A. (2000) Synthesis of the mixed lithium-magnesium, mixed amide (R,R/S,S)-[{LiMg(TMP)[CH2Si(Me)(2)N(SiMe3)]}(2)]: a conformationally-locked structure of five fused rings inducing two stereogenic nitrogen centres. Chemical Communications (London), 2000 (18). pp. 1757-1758. ISSN 0009-241X

Andrews, P.C. and Kennedy, A.R. and Mulvey, R.E. and Raston, C.L. and Roberts, B.A. and Rowlings, R.B. (2000) An unprecented hexapotassium-hexamagnesium twenty-four membered macrocycle amide: polymetallic cationic host to six monodeprotonated arene anions. Angewandte Chemie, 39 (11). pp. 1960-1962. ISSN 1521-3773

Craig, F.J. and Kennedy, A.R. and Mulvey, R.E. (2000) Bis[(μ-cyclopentylamino-N:N)dimethylaluminium(III)]. Acta Crystallographica Section C: Crystal Structure Communications, 56 (1). pp. 31-32. ISSN 0108-2701

Clegg, William and Liddle, Stephen T. and Mulvey, Robert E. and Robertson, Alan (2000) Pentanuclear asymmetrical ladder structure of the 1,4-dimethylpiperazine solvate of lithium anilide and its implication for the unknown structure of amorphous lithium anilide. Chemical Communications, 2000 (3). pp. 223-224. ISSN 1359-7345

Clegg, W and Horsburgh, L and Liddle, S T and Mackenzie, F M and Mulvey, Robert and Robertson, A (2000) The changing structural chemistry of lithium anilide on solvation by pyridine, 4-methylpyridine or 4-tert-butylpyridine. Journal of the Chemical Society, Dalton Transactions, 7. pp. 1225-1231. ISSN 0300-9246

Gehrhus, B. and Hitchcock, P.H. and Kennedy, A.R. and Lappert, M.F. and Mulvey, R.E. and Rodger, P.J.A. (1999) Synthesis and crystal structure of trimeric sodium 2,2,6,6- tetramethylpiperidide (NaTMP). Journal of Organometallic Chemistry, 587 (1). ISSN 0022-328X

Clegg, W and Drummond, A M and Liddle, S T and Mulvey, Robert and Robertson, A (1999) A novel heterometallic alkoxide: lithium-potassium tert-butoxide [((BuO)-O-t)(8)Li4K4]. Chemical Communications (16). pp. 1569-1570. ISSN 1359-7345

Clegg, W and Horsburgh, L. and Couper, S.A. and Mulvey, Robert (1999) catena-Poly[[bis(mu-2,6-dimethylpiperidin-ido-N:N)dilithium]-mu-(N,N,N ',N '-tetra- methylethylenediamine-N : N'')]. Acta Crystallographica Section C: Crystal Structure Communications, 55 (6). pp. 867-869. ISSN 0108-2701

Clegg, W. and Liddle, S.T. and Mulvey, Robert and Robertson, Alan (1999) Dis-assembling lithium amide ladder structures : new insight through the structure of [{[PhCH2N(H)Li](2)center dot thf}(infinity)], a polymer of (NLi)(2) planar rings connected by thf-bridged (NLi)(2) butterfly junctions. Chemical Communications, 1999 (6). pp. 511-512. ISSN 1359-7345

Armstrong, D.R. and Kennedy, A.R. and Mulvey, R.E. and Rowlings, R.B. (1999) Mixed-metal sodium-magnesium macrocyclic amide chemistry: A template reaction for the site selective dideprotonation of arene molecules. Angewandte Chemie, 38 (1-2). pp. 131-133. ISSN 1521-3773

Clegg, W and Liddle, S T and Henderson, K W and Keenan, F E and Kennedy, A R and McKeown, A E and Mulvey, R E (1999) Synthesis, characterisation and a theoretical investigation of the formation of lithium dialkylaluminium amides. Journal of Organometallic Chemistry, 572 (2). pp. 283-289. ISSN 0022-328X

Kennedy, A.R. and Mulvey, R.E. and Raston, C.L. and Roberts, B.A. and Rowlings, R.B. (1999) Inverse crown ether complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo- centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interac. Chemical Communications (London), 1999 (4). pp. 353-354. ISSN 0009-241X

Clegg, W. and Davies, R.P. and Dunbar, Lorraine and Feeder, N and Liddle, S.T. and Mulvey, Robert and Snaith, R. and Wheatley, A.E.H. (1999) Lithiated organophosphorus enamines : a new synthetic approach and the first crystal structures. Chemical Communications, 1999 (15). pp. 1401-1402. ISSN 1359-7345

Roberts, B.A. and Raston, C.L. and Mulvey, R.E. and Kennedy, A.R. and Rowlings, R.B. (1999) Oxygen incorporation in mixed S-block macrocyclic amide-ring systems. Abstracts of papers - American Chemical Society, 218. p. 420. ISSN 0065-7727

Couper, S A and Mulvey, Robert and Sherrington, D C (1998) Lithium amides as initiators of anionic polymerisation of methyl methacrylate. European Polymer Journal, 34 (12). pp. 1877-1887. ISSN 0014-3057

Clegg, W and Drummond, A M and Mulvey, Robert and Liddle, S T (1998) Synthesis and structure of the novel heptalithiumtetrarubidium mixed alkoxide peroxide [{((BuOLi)-O-t)(5)((BuORb)-O-t)(4)(Li2O2)center dot 2tmeda}(infinity)]: twenty-two vertex cage molecules linked by Rb-TMEDA-Rb bridges. Chemical Communications (21). pp. 2391-2392. ISSN 1359-7345

Armstrong, D R and Clegg, W and Dunbar, L and Liddle, S T and MacGregor, M and Mulvey, Robert and Reed, D and Quinn, S A (1998) Alkali metal-1-azaallyl complexes: X-ray crystallographic, NMR spectroscopic and ab initio calculational studies. Journal of the Chemical Society, Dalton Transactions (20). pp. 3431-3436. ISSN 0300-9246

Mulvey, Robert (1998) Synthetic and structural developments in hetero-s-block-metal chemistry : new ring-laddering, ring-stacking and other architectures. Chemical Society Reviews, 27 (5). pp. 339-346. ISSN 0306-0012

Kennedy, A.R. and Mulvey, R.E. and Rowlings, R.B. (1998) Intermetallic lithium-magnesium hexamethyldisilazide: Synthesis and structure, discovery of an oxygen-centered variant, and a reaction with benzonitrile that produces a novel amidinate cage compound with a trigonal bipyramidal Li4MgO core. Journal of the American Chemical Society, 120 (31). pp. 7816-7824. ISSN 1520-5126

Clegg, W and Kleditzsch, S and Mulvey, Robert and O'Shaughnessy, P (1998) Crystal structure of a heavier alkali metal diisopropylamide complex: a discrete (KN)(2) ring dimer with TMEDA chelation and short intramolecular K center dot center dot center dot H(C)contacts. Journal of Organometallic Chemistry, 558 (1-2). pp. 193-196. ISSN 0022-328X

Armstrong, D.R. and Craig, F.J. and Kennedy, A.R. and Mulvey, R.E. (1998) Formation of the lithium alkylaluminium secondary amide [Me2Al{PhCH2}2Li.THF] by a methane elimination / amide insertion process. Journal of Organometallic Chemistry, 550 (1-2). pp. 355-358. ISSN 0022-328X

Clegg, W and Horsburgh, L and Lindsay, David and Mulvey, Robert (1998) Diphenylzirconocene. Acta Crystallographica Section C: Crystal Structure Communications, 54. pp. 315-317. ISSN 0108-2701

Kennedy, Alan R. and Mulvey, Robert E. and Robertson, Alan (1998) Regioselective solvation in a polymeric lithium amide : remarkable twisted ladder structure of [{[PhCH2N(H)Li]2•H2NCH2Ph}∞]. Chemical Communications, 1998 (1). pp. 89-90. ISSN 1359-7345

Clegg, W and Henderson, K W and Horsburgh, L and Mackenzie, F M and Mulvey, Robert (1998) New alkali metal primary amide ladder structures derived from tBuNH(2): building cisoid and transoid ring conformations into ladder frameworks. Chemistry - A European Journal, 4 (1). pp. 53-56. ISSN 1521-3765

Craig, F.J. and Kennedy, A.R. and Mulvey, R.E. (1998) Chloro(dibenzylamine)dimethylaluminium(III). Acta Crystallographica Section C: Crystal Structure Communications, 54 (3). pp. 335-337. ISSN 0108-2701

Kennedy, A R and Mulvey, R E and Rowlings, R B (1998) Remarkable reaction of hetero-S-block-metal amides with molecular oxygen: Cationic (NMNMg)(2) ring products (M = Li or Na) with anionic oxo or peroxo cores. Agewandte Chemie-International Edition, 37 (22). pp. 3180-3183. ISSN 1521-3773

Clegg, W and Horsburgh, L and Mulvey, Robert and Ross, M J and Rowlings, R B and Wilson, V (1998) Synthesis and solid-state structures of three magnesium diamide complexes derived from RN(H)CH2CH2N(H)R diamine precursors (R = Ph or PHCH2). Polyhedron, 17 (11-12). pp. 1923-1930. ISSN 0277-5387

Mackenzie, F M and Mulvey, Robert and Clegg, W and Horsburgh, L (1998) Synthesis and structure of the novel octalithium-dipotassium mixed oxide-alkoxide cage complex [Li8K2(O)((BuO)-O-t)(8)center dot 2TMEDA]. Polyhedron, 17 (5-6). pp. 993-998. ISSN 0277-5387

Mulvey, Robert and Rowlings, R (1997) Fused-ring structures of magnesium diamide dimers. Abstracts of papers - American Chemical Society, 214. ISSN 0065-7727

Clegg, W and Drummond, A M and Mulvey, Robert and OShaughnessy, P (1997) Exploiting a substituted dihydrotriazinide as a novel bulky ligand: synthesis and crystal structure of a rubidium complex with an unprecedented tetrameric cyclic core. Chemical Communications (14). pp. 1301-1302. ISSN 1359-7345

Clegg, W and Elsegood, M R J and Horsburgh, L and Mulvey, Robert and Ross, M J (1997) ''Potassium potassates'' based on dihydrotriazinide ligands: syntheses, crystal structures, and comparison with other alkali metal dihydrotriazinide compounds. Chemische berichte, 130 (5). pp. 621-631. ISSN 0009-2940

Barker, J and Barr, D and Barnett, N D R and Clegg, W and CraggHine, I and Davidson, M G and Davies, R P and Hodgson, S M and Howard, J A K and Kilner, M and Lehmann, C W and LopezSolera, I and Mulvey, Robert and Raithby, P R and Snaith, R (1997) Lithiated amidines: syntheses and structural characterisations. Journal of the Chemical Society, Dalton Transactions (6). pp. 951-955. ISSN 0300-9246

Andrews, P C and Armstrong, D R and Clegg, W and Craig, F J and Dunbar, L and Mulvey, Robert (1997) Unexpected structure of 1,3-diphenyl-2-azaallylpotassium-N,N,N',N'',N''-pentamethyldiethylenetriamine: Infinite, zigzag chains of alternating cations and two distinct types of anion, one azaallyl bonded, the other allyl bonded. Chemical Communications (3). pp. 319-320. ISSN 1359-7345

Clegg, W. and Craig, F.J. and Henderson, K.W. and Kennedy, A.R. and Mulvey, R.E. and O'Neil, P.A. and Reed, D. (1997) Solid-state and dynamic solution equilibria of bis(dibenzylamido) magnesium complexes: aggregation dependence on stoichiometry and denticity of donor solvent. Inorganic Chemistry, 36 (27). pp. 6238-6246. ISSN 1520-510X

Barnett, Nicholas D. R. and Clegg, William and Horsburgh, Lynne and Lindsay, David M. and Liu, Qi-Yong and Mackenzie, Fiona M. and Mulvey, Robert E. and Williard, Paul G. (1996) Novel octameric structure of the lithium primary amide [{Bu(t)N(H)Li}(8)] and its implication for the directed synthesis of heterometallic imide cages. Chemical Communications (20). pp. 2321-2322. ISSN 1359-7345

Craig, F J and Kennedy, A R and Mulvey, R E and Spicer, M D (1996) Structures of the potassium aluminates [{K-2(Me(3)AlOBu(t))(2)center dot pmdeta}(infinity)] and [{K(pmdeta)(2)}(+)(AlMe(4))(-)]: how the nature of the alane reagent determines which of these products form from alkoxide-containing reaction mixtures. Chemical Communications (London) (16). pp. 1951-1952. ISSN 0009-241X

Clegg, W and Horsburgh, L and Mulvey, Robert and Rowlings, R (1996) The first magnesium amide trimer, magnesio-1,8-diaminonaphthalene center dot hexamethylphosphoramide: introducing an unprecedented cage assembly incorporating an Mg-3 unit within a N-6 trigonal prism. Chemical Communications (15). pp. 1739-1740. ISSN 1359-7345

Henderson, K.W. and Mulvey, Robert and Dorigo, A.E. (1996) Solvent induced disproportionation of alkyl(amido)magnesium species containing a (2-pyridyl)amido unit : Synthetic, theoretical and NMR spectroscopic studies of bis(amido)magnesium compounds. Journal of Organometallic Chemistry, 518 (1-2). pp. 139-146. ISSN 0022-328X

Andrews, Philip C. and Barnett, N.D.R. and Mulvey, Robert and Clegg, W. and O'Neil, P.A. and Barr, Donald and Cowton, Lucy and Dawson, Andrea J. and Wakefield, Basil J. (1996) X-ray crystallographic studies and comparative reactivity studies of a sodium diisopropylamide (NDA) complex and related hindered amides. Journal of Organometallic Chemistry, 518 (1-2). pp. 85-95. ISSN 0022-328X

Mackenzie, F.M. and Mulvey, Robert and Clegg, W. and Horsburgh, Lynne (1996) The first trimetallic lithium-sodium-potassium complex : Synthesis and crystal structure of a twelve-vertex Li2Na2K2N4O2 cage molecule containing an amide-alkoxide combination. Journal of the American Chemical Society, 118 (19). pp. 4721-4722. ISSN 1520-5126

Clegg, W. and Horsburgh, L. and Dennison, P.R. and Mckenzie, F.M. and Mulvey, Robert (1996) A new architecture in lithium amide chemistry : Synthesis of [{(c-C5H9)N(H)}(12)(O)Li-14], a cage molecule containing a salt-like, distorted, face-centred cube of lithium cations. Chemical Communications, 1996 (9). pp. 1065-1066. ISSN 1359-7345

Mulvey, Robert and Dunbar, Lorraine and Clegg, W. and Horsburgh, L. (1996) Stoichiometric dependence of the long-established reaction of butyllithium with pyridine : A hidden secondary reaction that produces a pyridine adduct of a lithiodihydropyridine. Angewandte Chemie International Edition, 35 (7). pp. 753-755. ISSN 1521-3773

Barnett, N.D.R. and Clegg, W. and Mulvey, Robert and O'Neil, P.A. and Reed, D. (1996) Selective crystallization of di-sec-butylmagnesium. N,N,N',N'-tetramethylethylenediamine from solutions containing mixtures of normal-butyl and secondary-butyl isomers. Journal of Organometallic Chemistry, 510 (1-2). pp. 297-300. ISSN 0022-328X

Armstrong, D R and Baker, D R and Craig, F J and Mulvey, Robert and Clegg, W and Horsburgh, L (1996) Benzyl(trimethylsilyl)amidolithium: Structural studies by ab initio MO and X-ray crystallographic methods, and comparison with the known structures of dibenzyl and bis(trimethylsilyl) analogues. Polyhedron, 15 (20). pp. 3533-3542. ISSN 0277-5387

Armstrong, D.R. and Craig, F.J. and Kennedy, A.R. and Mulvey, R.E. (1996) Crystal structure of a representative mixed adduct of trimethylaluminium and a lithium amide and a theoretical MO study on model systems. Chemische berichte, 129. pp. 1293-1300. ISSN 0009-2940

Clegg, W. and Horsburgh, L. and Mackenzie, F.M. and Mulvey, Robert (1995) Dis-assembling lithium amide ladder structures : structural elucidation of the lithium anilide solvate [{PhN(H)Li}6·8THF], a model intermediate En route to forming tetra-solvated ring dimers. Journal of the Chemical Society, Chemical Communications, 1995 (19). pp. 2011-2012. ISSN 0022-4936

Mulvey, Robert and ROSS, M J and CLEGG, W and HORSBURGH, L (1995) Dilithio acetylacetone: remarkable solid state structural complexity. Abstracts of papers - American Chemical Society, 210. ISSN 0065-7727

Mulvey, Robert and MACKENZIE, F M (1995) Surprising structural variation in simple lithium anilides. Abstracts of papers - American Chemical Society, 210. ISSN 0065-7727

Clegg, W. and Horsburgh, L. and Mulvey, Robert and Ross, M.J. (1995) Crystal Structure of Dilithioacetylacetone: A Twenty-Four Vertex Li-O Cage Molecule with Limited Li–C(terminal) Bonding and Selective THF Solvation. Angewandte Chemie International Edition, 34 (11). pp. 1233-1234. ISSN 1521-3773

Barr, Donald and Clegg, William and Cowton, Lucy and Horsburgh, Lynn and Mackenzie, Fiona M. and Mulvey, Robert (1995) Lithium anilide complexed by pmdeta : expectation of a simple monomer, but in reality an odd trinuclear composition combining three-, four- and five-coordinate lithium. Journal of the Chemical Society, Chemical Communications, 1995 (8). pp. 891-892. ISSN 0022-4936

Armstrong, D.R. and Henderson, Kenneth. W. and MacGregor, M. and Mulvey, Robert and Ross, M.J and Clegg, W. and O'Neil, P.A. (1995) Synthetic and theoretical MO calculational studies of lithiotriazine intermediates produced during alkyllithium-induced cyclotrimerisation reactions of organic nitriles, and comparison of their structures with that of a methylmagnesiotriazine derivative. Journal of Organometallic Chemistry, 486 (1-2). pp. 79-93. ISSN 0022-328X

Andrews, P.C. and Armstrong, D.R. and Baker, D.R. and Mulvey, Robert and Clegg, W. and Horsburgh, L. and O'Neil, P.A. and Reed, D. (1995) Synthetic, structural, mechanistic, and theoretical MO studies of the alkali-metal chemistry of dibenzylamine and its transformation to 1,3-diphenyl-2-azaallyl derivatives. Organometallics, 14 (1). pp. 427-439. ISSN 0276-7333

Henderson, Kenneth W. and Mulvey, Robert and Reinhard, Friedrich B. M. and Clegg, William and Horsburgh, Lynne (1994) Mixed Lithium Magnesium Aryl Oxides Derived from Cresol: Crystal Structures and Solution NMR Studies of an Unexpected, Magnesium-Rich Oxo Product with a Trigonal Bipyramidal LiMg4 Cage and an Expected Lithium-Rich Product with a More Familiar Li.cntdot..cntdot..cntdot.Mg.cntdot..cntdot..cntdot.Li Chain. Journal of the American Chemical Society, 116 (23). pp. 10777-10778. ISSN 1520-5126

Baker, Daniel R. and Clegg, William and Horsburgh, Lynne and Mulvey, Robert (1994) Expanding the Scope of Lithium Coordination Chemistry by Placing Sodium Nearby: A Mixed Lithium-Sodium Benzyl Compound Having TMEDA-Chelated Li+ Cations in an Unprecedented Tetrameric Environment. Organometallics, 13 (11). pp. 4170-4172. ISSN 0276-7333

Clegg, W. and Horsburgh, L. and Mulvey, Robert and Ross, M.J. (1994) Potassium potassiate contact ion pair polymer synthesised by metallation of a dihydrotriazine. Journal of the Chemical Society, Chemical Communications, 1994 (20). pp. 2393-2394. ISSN 0022-4936

Clegg, W. and Henderson, Kenneth W. and Mulvey, Robert and O'Neil, P.A. (1994) Model structural types for rationalising stoichiometries and coordination numbers in lithium amidomagnesiates : syntheses and X-ray diffraction studies of [{Mg(NR2)2}2], [Li2Mg(NR2)4] and [LiMg(NR2)3·py](R = benzyl, py = pyridine). Journal of the Chemical Society, Chemical Communications, 1994 (6). pp. 769-770. ISSN 0022-4936

Clegg, W. and Frank, Michael and Mulvey, Robert and O'Neil, P.A. (1994) Synthesis and X-ray crystallographic characterisation of o-phenylenediamidomagnesium·tetrahydrofuran : the first octahedral Mg6 cluster. Journal of the Chemical Society, Chemical Communications, 1994 (1). pp. 97-98. ISSN 0022-4936

Clegg, W. and O'Neil, P.A. and Henderson, K.W. and Mulvey, Robert (1993) Structure of monomeric [TiCl4(hexamethylphosphoric triamide)2]. Acta Crystallographica Section C: Crystal Structure Communications, 49 (12). pp. 2108-2109. ISSN 0108-2701

Henderson, Kenneth W. and Mulvey, Robert and Clegg, William and O'Neil, Paul A. (1993) Synthesis of heteroleptic bis(amides) : crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]. Polyhedron, 12 (20). pp. 2535-2538. ISSN 0277-5387

Barker, James and Barnett, N.D.R. and Barr, Donald and CLEGG, W and Mulvey, Robert and O'Neil, P.A. (1993) Crystal Structure of [(-Cyanoisopropyl-sodium · Tetramethylenediamine)4 : How Coordination Expansion from Li to Na Centers can Increase the Aggregation State of an -Nitrile “Carbanion”. Angewandte Chemie International Edition, 32 (9). pp. 1366-1368. ISSN 1521-3773

ANDREWS, P C and BAKER, D R and Mulvey, Robert and CLEGG, W and ONEIL, P (1993) Structural and mechanistic variations in the alkali metal amide chemistry of dibenzylamine. Abstracts of papers - American Chemical Society, 206. ISSN 0065-7727

Andrews, Philip C. and Clegg, W. and Mulvey, Robert and O'Neil, P.A. and Wilson, Heather M.M. (1993) An infinite ladder structure of alternating, fused K2N2 rhomboids and KN2 triangles : synthesis and crystallographic characterisation of benzotriazolatopotassium·HMPA (HMPA = hexamethylphosphoric triamide). Journal of the Chemical Society, Chemical Communications, 1993 (14). pp. 1142-1144. ISSN 0022-4936

Baker, Daniel R. and Mulvey, Robert and Clegg, William and O'Neil, Paul A. (1993) An unprecedented mixed alkali metal organonitrogen ladder : synthesis, NMR spectroscopic studies, and x-ray crystallographic studies of the dilithium disodium amide [{LiNa[N(CH2Ph)2]2.cntdot.OEt2}2]. Journal of the American Chemical Society, 115 (14). pp. 6472-6473. ISSN 1520-5126

Clegg, W. and Henderson, Kenneth W. and Mulvey, Robert and O'Neil, P.A. (1993) Synthesis and structural characterisation of the mixed lithium–magnesium amide, [{PhCH2(Me2NCH2CH2)N}4Li2Mg] : a new type of magnesiate complex free of a donor solvent as ligand. Journal of the Chemical Society, Chemical Communications, 1993 (11). pp. 969-970. ISSN 0022-4936

Armstrong, David. R. and Clegg, W. and MacGregor, M. and Mulvey, Robert and O'Neil, P.A. (1993) Butyllithium-induced cyclotrimerisation reactions of organic nitriles : solvent dependency, crystal and solution structures of lithio triazine intermediates and an unexpected rearrangement of dihydrotriazino anions. Journal of the Chemical Society, Chemical Communications, 1993 (7). pp. 608-610. ISSN 0022-4936

HENDERSON, K W and Mulvey, Robert (1993) Synthesis of Bis(amido) magnesium compounds via reaction of chelating alkali-metal amides with a Grignard-reagent. Abstracts of papers - American Chemical Society, 205. ISSN 0065-7727

Barnett, N.D.R. and Mulvey, Robert and CLEGG, W and ONEIL, P A (1993) Butyllithium cubane tetramers linked by Li-TMEDA-Li bridges in an infinite, zig-zag chain arrangement: first crystallographic study of a simple butyl compound of an early main group element. Journal of the American Chemical Society, 115 (4). pp. 1573-1574. ISSN 1520-5126

HENDERSON, K W and Mulvey, Robert and CLEGG, W and ONEIL, P A (1992) Reactions of chelating alkali metal amides with the Grignard reagent nBuMgCl: crystal structures and solution 1H NMR spectroscopic studies of the expected mono(amido)-product [PhCH2(Me2NCH2CH2)NMgnBu]2 and the unexpected bis(amido)-product {[Ph(2-Pyr)N]2M9 · (THF)2}. Journal of Organometallic Chemistry, 439 (3). pp. 237-250. ISSN 0022-328X

Barnett, N.D.R. and Mulvey, Robert and Clegg, William and O'Neil, Paul A. (1992) Synthesis and crystal structure of the mixed lithium sodium guanidide [Li4Na2{NC(NMe2)2}6]: A stack of three (metal-nitrogen)2 dimeric rings with additional intramolecular (tertiary amine) nitrogen-lithium coordinations. Polyhedron, 11 (21). pp. 2809-2812. ISSN 0277-5387

CLEGG, W and MACGREGOR, M and Mulvey, Robert and ONEIL, P A (1992) Crystal and solution structures of the novel complex of sodium ketimide with two ketimine ligands [(tBu2C = NNa)4(HN = CtBu2)2]: stacking of complexed and uncomplexed (NNa)2 rings to give a highly distorted (NNa)4 cubane. Angewandte Chemie International Edition, 31 (1). pp. 93-95. ISSN 1521-3773

Barnett, N.D.R and Mulvey, Robert and Clegg, William and O'Neil, Paul A. (1991) Crystal structure of lithium diisopropylamide (LDA): an infinite helical arrangement composed of near-linear nitrogen-lithium-nitrogen units with four units per turn of helix. Journal of the American Chemical Society, 113 (21). pp. 8187-8188. ISSN 1520-5126

ANDREWS, P C and ARMSTRONG, D R and CLEGG, W and MACGREGOR, M and Mulvey, Robert (1991) A new type of structure in sodium amide ring chemistry: crystal structure of [PhCH2(Me)NNa(tmeda)]2 showing a buckled, rather than the normal planar, (NNa)2 cyclic ring, with a cisoid, rather than the normal transoid, arrangement of amido-substituents (tmeda = tetramethylethylenediamine). Journal of the Chemical Society, Chemical Communications (7). pp. 497-498. ISSN 0022-4936

Andrews, Philip C. and Baker, Daniel R. and Mulvey, Robert and Clegg, William and O'Neil, Paul A. (1991) Isostructural potassium and sodium di-nitrogen functionalized amides: Syntheses and crystal structures of [Ph(2-Pyr)NK·TMEDA]2 and [Me(2-Pyr)NNa·TMEDA]2. Polyhedron, 10 (15). pp. 1839-1841. ISSN 0277-5387

ARMSTRONG, D R and Mulvey, Robert and BARR, D and PORTER, R W and RAITHBY, P R and SIMPSON, T R E and SNAITH, R and WRIGHT, D S and GREGORY, K and MIKULCIK, P (1991) Lithiations of mercaptoamines containing NC(S)NH–,–NHC(S)S– and –NHC(S)NH– units: syntheses, crystal structures and model molecular-orbital calculations. Journal of the Chemical Society, Dalton Transactions (S). pp. 765-776. ISSN 0300-9246

ANDREWS, P C and CLEGG, W and Mulvey, Robert (1990) Lewis-base-dictated structural variations in sodium amide chemistry: X-ray crystal structures of phenyl(2-pyridyl)amidosodium with hexamethylphosphoric triamide (HMPA) and with pentamethyldiethylenetriamine (PMDETA). Angewandte Chemie International Edition, 29 (12). pp. 1440-1441. ISSN 1521-3773

ANDREWS, P C and Mulvey, Robert and CLEGG, W and REED, D (1990) X-ray crystallographic studies and dynamic 1H NMR spectroscopic studies of the novel sodium aza-allyl monomer [PhC(H)NC(H)Ph]Na · PMDETA: A discrete contact ion-pair structure held together by a short NNa bond, and showing close (ortho-Ph)CH ··· Na contacts in both solid state and solution. Journal of Organometallic Chemistry, 386 (3). pp. 287-297. ISSN 0022-328X

ANDREWS, P C and ARMSTRONG, D R and MACGREGOR, M and Mulvey, Robert and REED, D (1989) Lewis base mediated rearrangements of alkali metal imides to η3-aza-allyl complexes: preparation and n.m.r. spectroscopic solution studies of [CH3CH2CH2C(H)C(But)N(H)·M·(HMPA)x]n(M = Li, x= 1; M = Na, x= 2)(HMPA = hexamethylphosphoramide). Journal of the Chemical Society, Chemical Communications (18). pp. 1341-1342. ISSN 0022-4936

BARR, D and CLEGG, W and HODGSON, S M and LAMMING, G R and Mulvey, Robert and SCOTT, A J and SNAITH, R and WRIGHT, D S (1989) [H2C(CH2)5NLI]6, the first cyclized lithium amide ladder: synthesis and structure of hexamethyleneimidolithium. Angewandte Chemie International Edition, 28 (9). pp. 1241-1243. ISSN 1521-3773

ARMSTRONG, D R and BARR, D and CLEGG, W and HODGSON, S M and Mulvey, Robert and REED, D and SNAITH, R and WRIGHT, D S (1989) Ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] {[H2C(CH2)3NLi]3.cntdot.PMDETA}2 and [cyclic] {[H2C(CH2)3NLi]2.cntdot.TMEDA}2, and ab initio MO calculations probing ring vs ladder vs stack structural preferences. Journal of the American Chemical Society, 111 (13). pp. 4719-4727. ISSN 1520-5126

BARR, D and DOYLE, M J and Mulvey, Robert and RAITHBY, P R and REED, D and SNAITH, R and WRIGHT, D S (1989) A unique lithium halide complex, [(LiBr)2·3HMPA·toluene]: synthesis from reaction of solid NH4Br with BunLi in HMPA (hexamethylphosphoramide)/toluene media, crystal structure showing two Li–Br units linked by three µ2-HMPA ligands, and detection of 7Li 31P coupling in solutions of the complex. Journal of the Chemical Society, Chemical Communications (5). pp. 318-319. ISSN 0022-4936

ARMSTRONG, D R and Mulvey, Robert and BARR, D and SNAITH, R and WRIGHT, D S and CLEGG, W and HODGSON, S M (1989) Dilithiation of N,N′-diphenylthiourea, PhNHC(S)NHPh, in HMPA: the unexpected structure of the product, [PhNPh)SLi·2HMPA]2, and supporting ab initio MO calculations on model systems. Journal of Organometallic Chemistry, 362 (1-2). C1-C4. ISSN 0022-328X

BARR, D and CLEGG, W and Mulvey, Robert and SNAITH, R (1989) Synthesis and crystal structure of the mixed alkali metal imide Li4 -xNa2 +x[NC(Ph)But]6: three (metal–nitrogen)2 ring dimers in a triple-layered stack. Journal of the Chemical Society, Chemical Communications (1). pp. 57-58. ISSN 0022-4936

ARMSTRONG, D R and Mulvey, Robert and BARR, D and SNAITH, R and REED, D (1988) Isolation, characterisation, and solution structures of the bis(pyridine) complex of the n-butyllithium-pyridine adduct, Bun(C5H5N)Li·2C5H5N, its mode of decomposition, and ab initio calculations on model systems. Journal of Organometallic Chemistry, 350 (2). pp. 191-205. ISSN 0022-328X

Andrews, Philip C. and Armstrong, David R. and Mulvey, Robert and Reed, David (1988) Evidence for extreme activation of carbon-hydrogen bonds in [(PhCH2)2NNa]n : resultant carbon-hydrogen bond cleavage to give {[PhC(H)NC(H)Ph]Na.cntdot.PMDETA}n. Journal of the American Chemical Society, 110 (15). pp. 5235-5236. ISSN 1520-5126

BARR, D and CLEGG, W and HODGSON, S M and Mulvey, Robert and REED, D and SNAITH, R and WRIGHT, D S (1988) A Li8 cluster of three edge-connected Li4 tetrahedra held by Li–N, Li C, and Li Li interactions: crystal structure of (o-LiC6H4CH2·NLi·CH2CH2NMe2)4 and detection of metal metal coupling within it by 7Li COSY n.m.r. spectroscopy. Journal of the Chemical Society, Chemical Communications (5). pp. 367-369. ISSN 0022-4936

ARMSTRONG, D R and Mulvey, Robert and WALKER, G T and BARR, D and SNAITH, R and CLEGG, W and REED, D (1988) Syntheses and solid-state structures of trimeric dibenzylamidolithium and its diethyl ether and hexamethylphosphoramide dimeric complexes: an explanation of these structures and evidence for Li CH interactions in both solid and solution phases. Journal of the Chemical Society, Dalton Transactions (3). pp. 617-628. ISSN 0300-9246

BARR, D and DOYLE, M J and Mulvey, Robert and RAITHBY, P R and SNAITH, R and WRIGHT, D S (1988) Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)n[TMEDA = Me2N(CH2)2NMe2]: a polymeric solid with Li+ ions linked by bifunctional linear SCN– ligands. Journal of the Chemical Society, Chemical Communications (2). pp. 145-147. ISSN 0022-4936

Barr, D. and Snaith, R. and Mulvey, Robert and Reed, D. (1988) Characterization of the bis(pyridine) complex of the butyllithium-pyridine adduct, 2-Bun(C5H5N)Li·(C5H5N)2; its decomposition to 2-butylpyridine via a dihydropyridine. Polyhedron, 7 (8). pp. 665-668. ISSN 0277-5387

BARR, D and SNAITH, R and Mulvey, Robert and PERKINS, P G (1988) MOLECULAR-ORBITAL BOND INDEX (MOBI) CALCULATIONS ON SELECTED ORGANO-LITHIUM AND LITHIUM ATE SPECIES - EVIDENCE FOR LI=H-C 3-CENTER INTERACTIONS. Polyhedron, 7 (21). pp. 2119-2128. ISSN 0277-5387

BARR, D and SNAITH, R and WRIGHT, D S and Mulvey, Robert and WADE, K (1987) Reactions of ammonium salts with butyllithium and with lithium hydride: new routes to fully anhydrous inorganic lithium complexes. Journal of the American Chemical Society, 109 (25). pp. 7891-7893. ISSN 1520-5126

BARR, D and SNAITH, R and CLEGG, W and Mulvey, Robert and WADE, K (1987) The syntheses and crystal structures of two iminolithium adducts: (Ph2CNLi·NC5H5)4, a tetrameric pseudo-cubane formed by stacking two (LiN)2 four-membered rings, and [But2CNLi·OP(NMe2)3]2, a dimer prevented sterically from stacking. Journal of the Chemical Society, Dalton Transactions (9). pp. 2141-2147. ISSN 0300-9246

BARR, D and CLEGG, W and Mulvey, Robert and SNAITH, R and WRIGHT, D S (1987) Three model structural types in lithium amide chemistry: the crystal and molecular structures of dimeric [Ph(Me)NLi·TMEDA]2(TMEDA = Me2NCH2CH2NMe2) and monomeric Ph(naphthyl)NLi·PMDETA [PMDETA = MeN(CH2CH2NMe2)2], and of [Ph(naphthyl)NLi·TMEDA]2, a ‘loose dimer’. Journal of the Chemical Society, Chemical Communications (10). pp. 716-718. ISSN 0022-4936

BARR, D and SNAITH, R and WRIGHT, D S and Mulvey, Robert and JEFFREY, K and REED, D (1987) Isolation and solution structures of {PhCH2NLiCH2CH2NMe2} n and of the totally rigid dilithium compound, {o-LiC6H4CH2NLiCH2CH2NMe2} n ; evidence for Li…o-HC interactions. Journal of Organometallic Chemistry, 325 (1-2). C1-C6. ISSN 0022-328X

ARMSTRONG, D R and BARR, D and SNAITH, R and CLEGG, W and Mulvey, Robert and WADE, K and REED, D (1987) The ring-stacking principle in organolithium chemistry: its development through the isolation and crystal structures of hexameric iminolithium clusters (RR'C=NLi)6 (R'=Ph, R=But or Me2N; R=R'=Me2N or But). Journal of the Chemical Society, Dalton Transactions (5). pp. 1071-1081. ISSN 0300-9246

ARMSTRONG, D R and CLEGG, W and COLQUHOUN, H M and DANIELS, J A and Mulvey, Robert and STEPHENSON, I R and WADE, K (1987) Structure and bonding of the lithium tetrahydroborate–tetramethylethylenediamine adduct (TMEDA·LiBH4)2, a centrosymmetric dimer containing doubly and triply bridging hydrogen atoms. Journal of the Chemical Society, Chemical Communications (8). pp. 630-632. ISSN 0022-4936

Mulvey, Robert and WADE, K and ARMSTRONG, D R and WALKER, G T and SNAITH, R and CLEGG, W and REED, D (1987) X-ray crystallographic and solution studies of the pentamethyldiethylenetriamine and tetramethylethylenediamine adducts of lithium diphenylphosphide. Polyhedron, 6 (5). pp. 987-993. ISSN 0277-5387

CLEGG, W and Mulvey, Robert and SNAITH, R and TOOGOOD, G E and WADE, K (1986) The synthesis and X-ray structural characterisation of the first mixed alkali metal organonitrogen molecular cluster LiNa3[OP(NMe2)3]3[NC(NMe2)2]4. Journal of the Chemical Society, Chemical Communications (23). pp. 1740-1742. ISSN 0022-4936

BARR, D and SNAITH, R and Mulvey, Robert and WADE, K and REED, D (1986) Variable-temperature and-concentration 1H and 7Li NMR studies of solutions of hexameric iminolithium compounds, (R1R2CNLi)6. Magnetic Resonance in Chemistry, 24 (8). pp. 713-717.

ARMSTRONG, D R and BARR, D and CLEGG, W and Mulvey, Robert and REED, D and SNAITH, R and WADE, K (1986) The laddering principle in lithium amide chemistry: the crystal and molecular structure of the pyrrolididolithium adduct [H2C(CH2)3NLi]3·MeN(CH2CH2NMe2)2. Journal of the Chemical Society, Chemical Communications (11). pp. 869-870. ISSN 0022-4936

REED, D and BARR, D and Mulvey, Robert and SNAITH, R (1986) High-field lithium-7 nuclear magnetic resonance spectroscopic and cryoscopic relative molecular mass studies on solutions of amido- and imido-lithium compounds. Journal of the Chemical Society, Dalton Transactions (3). pp. 557-564. ISSN 0300-9246

BARR, D and CLEGG, W and Mulvey, Robert and SNAITH, R and WADE, K (1986) Bonding implications of interatomic distances and ligand orientations in the iminolithium hexamers [LiNC(Ph)But]6 and [LiNC(Ph)NMe2]6: a stacked-ring approach to these and related oligomeric organolithium systems. Journal of the Chemical Society, Chemical Communications (4). pp. 295-297. ISSN 0022-4936

BARR, D and HUTTON, K B and MORRIS, J H and Mulvey, Robert and REED, D and SNAITH, R (1986) The isolation of a highly arene-soluble alkali metal tetrafluoroborate complex, LiBF4·4HMPA [HMPA = OP(NMe2)3]: evidence for strong Li F interactions in solution. Journal of the Chemical Society, Chemical Communications (2). pp. 127-129. ISSN 0022-4936

Mulvey, Robert and ONEILL, M E and WADE, K and SNAITH, R (1986) Bond indices, enthalpies and relative stabilities of real and hypothetical closo-BnHc−n clusters (n = 5–12; c = 0, 2 or 4) as revealed by the molecular-orbital bond index method. Polyhedron, 5 (9). pp. 1437-1447. ISSN 0277-5387

Mulvey, Robert and Clegg, W. and Barr, Donald and Snaith, R. (1986) Crystal structure of sodium iodide·(diglyme) : An unprecedented bridging role for diglyme. Polyhedron, 5 (12). pp. 2109-2111. ISSN 0277-5387

Barr, D. and Clegg, W. and Mulvey, Robert and Reed, D. and Snaith, R. (1985) Crystal and Solution Structures of [tBu2CNLi·OP(NMe2)3]n. Angewandte Chemie International Edition, 24 (4). pp. 328-329. ISSN 1521-3773

HOUSECROFT, C E and SNAITH, R and MOSS, K and Mulvey, Robert and ONEILL, M E and WADE, K (1985) Cluster bonding and energetics of the borane anions, BnHn2− (n = 5–12): A comparative study using bond length—bond enthal. Polyhedron, 4 (11). pp. 1875-1881. ISSN 0277-5387

BARR, D and CLEGG, W and Mulvey, Robert and SNAITH, R (1984) Crystal structures of (Ph2CNLi·NC5H5)4 and [CILi·OP(NMe2)3]4; discrete tetrameric pseudo-cubane clusters with bridging of Li3 triangles by nitrogen and by chlorine atoms. Journal of the Chemical Society, Chemical Communications (2). pp. 79-80. ISSN 0022-4936

BARR, D and CLEGG, W and Mulvey, Robert and SNAITH, R (1984) Evidence for CH ‥ Li interactions in the solid state structure of dibenzylamido-lithium, and in solutions of it and its complexes: coloured species due to benzyl → lithium charge transfer. Journal of the Chemical Society, Chemical Communications (5). pp. 287-289. ISSN 0022-4936

BARR, D and CLEGG, W and Mulvey, Robert and SNAITH, R (1984) TRIMERIC DIBENZYLAMIDOLITHIUM AND ITS DIMERIC DIETHYL-ETHER AND HEXAMETHYLPHOSPHORAMIDE COMPLEXES - STRUCTURAL AND THEORETICAL-STUDIES OF REACTIVE ORGANONITROGEN LITHIUM OLIGOMERS. Journal of the Chemical Society, Chemical Communications (5). pp. 285-287. ISSN 0022-4936

BARR, D and CLEGG, W and Mulvey, Robert and SNAITH, R (1984) X-Ray crystal structure of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–: a lithium 'ate complex, with a pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding. Journal of the Chemical Society, Chemical Communications (4). pp. 226-227. ISSN 0022-4936

BARR, D and CLEGG, W and Mulvey, Robert and SNAITH, R (1984) The isolation and crystal structure of [Ph(2-Pyr)NLi]·(HMPA)·[Ph(2-Pyr)NH]; a model monomeric orgenonitrogen–lithium species containing co-ordination of lithium by both an anchimeric pyridyl N-atom and by a potentially reactive amine ligand. Journal of the Chemical Society, Chemical Communications (7). pp. 469-470. ISSN 0022-4936

BARR, D and CLEGG, W and Mulvey, Robert and SNAITH, R (1984) The isolation and crystal structure of {Li·(H2O)2·[OP(NMe2)3]}22+·2Cl–: a (LiO)2 ring compound with bridging neutral oxygen (hexamethylphosphormaide) ligands. Journal of the Chemical Society, Chemical Communications (15). pp. 974-975. ISSN 0022-4936

BARR, D and CLEGG, W and Mulvey, Robert and SNAITH, R (1984) The structural isomers of {[ph(2-pyridyl)NLi]·[OP(NMe2)3]}2: dimeric species with alternative central (LiN)2 and (LiO)2 rings, the latter involving unprecedented neutral bridging oxygen ligands. Journal of the Chemical Society, Chemical Communications (11). pp. 700-701. ISSN 0022-4936

Book Section

Mulvey, Robert and Robertson, Stuart; Wheatley, Andrew E. H. and Uchiyama, Masanobu, eds. (2022) Structural evidence for synergistic bimetallic main group bases. In: Polar Organometallic Reagents. John Wiley & Sons, Ltd., Hoboken, NJ, pp. 49-95. ISBN 9781119448846

Mulvey, Robert E. and Garden, Jennifer A.; (2014) Di-tert-butylzinc. In: e-EROS encyclopedia of reagents for organic synthesis. John Wiley & Sons, Ltd., New Jersey, pp. 1-4.

Mulvey, Robert E. and Robertson, Stuart D.; Xi, Zhenfeng, ed. (2014) FascinATES : mixed-metal ate compounds that function synergistically. In: Organo-di-Metallic Compounds (or Reagents). Topics in Organometallic Chemistry . Springer, pp. 129-158. ISBN 978-3-319-08428-2

Mulvey, Robert; Weibel, Peter and Fruk, Ljiljana, eds. (2013) Molecular architecture and synergy in organometallic chemistry. In: Molecular Aesthetics. ZKM Center for Art and Media/MIT Press, Cambridge, MA, USA, pp. 408-424. ISBN 9780262018784

Mulvey, Robert E. and Robertson, Stuart D.; Harder, Sjoerd, ed. (2013) Modern developments in magnesium reagent chemistry for synthesis. In: Alkaline-Earth Metal Compounds. Topics in Organometallic Chemistry . Springer, pp. 103-140. ISBN 978-3-642-36270-5

Review

Mulvey, Robert and Andrews, P.C. and Clegg, W. and O'Neil, P.A. (1992) Structural variations in alkali-metal amide chemistry and their influence on reactivity. [Review]

This list was generated on Wed Nov 20 17:47:33 2024 GMT.

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