Crystal structures of (Ph2CNLi·NC5H5)4 and [CILi·OP(NMe2)3]4; discrete tetrameric pseudo-cubane clusters with bridging of Li3 triangles by nitrogen and by chlorine atoms

BARR, D and CLEGG, W and Mulvey, Robert and SNAITH, R (1984) Crystal structures of (Ph2CNLi·NC5H5)4 and [CILi·OP(NMe2)3]4; discrete tetrameric pseudo-cubane clusters with bridging of Li3 triangles by nitrogen and by chlorine atoms. Journal of the Chemical Society, Chemical Communications (2). pp. 79-80. ISSN 0022-4936 (https://doi.org/10.1039/C39840000079)

Abstract

X-Ray crystallographic studies of the title compounds (Ph2CNLi·NC5H5)4, (1), and [CILi·OP(NMe2)3]4, (2) show them to have pseudo cubane tetrameric structures in which triply-bonding methyleneamino -nitrogen atoms [(1)] or chlorine atoms [(2)] hold together the tetrahedral Li4 frameworks.

ORCID iDs

Mulvey, Robert ORCID: https://orcid.org/0000-0002-1015-2564

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  Item type:	Article
  ID code:	37482
  Dates:	Date Event 1984 Published
  Keywords:	crystal structures, chlorine atoms, nitrogen atoms, Chemistry, Molecular Medicine
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	08 Feb 2012 15:09
  Last modified:	20 Jan 2023 02:21
  URI:	https://strathprints.strath.ac.uk/id/eprint/37482