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Crystal structures of (Ph2CNLi·NC5H5)4 and [CILi·OP(NMe2)3]4; discrete tetrameric pseudo-cubane clusters with bridging of Li3 triangles by nitrogen and by chlorine atoms

BARR, D and CLEGG, W and Mulvey, Robert and SNAITH, R (1984) Crystal structures of (Ph2CNLi·NC5H5)4 and [CILi·OP(NMe2)3]4; discrete tetrameric pseudo-cubane clusters with bridging of Li3 triangles by nitrogen and by chlorine atoms. Journal of the Chemical Society, Chemical Communications (2). pp. 79-80. ISSN 0022-4936

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Abstract

X-Ray crystallographic studies of the title compounds (Ph2CNLi·NC5H5)4, (1), and [CILi·OP(NMe2)3]4, (2) show them to have pseudo cubane tetrameric structures in which triply-bonding methyleneamino -nitrogen atoms [(1)] or chlorine atoms [(2)] hold together the tetrahedral Li4 frameworks.

Item type:Article
ID code:37482
Keywords:crystal structures, chlorine atoms, nitrogen atoms, Chemistry, Molecular Medicine
Subjects:Science > Chemistry
Department:Faculty of Science > Pure and Applied Chemistry
Depositing user: Pure Administrator
Date deposited:08 Feb 2012 15:09
Last modified:03 Jan 2019 13:14
URI:https://strathprints.strath.ac.uk/id/eprint/37482
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