Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] towards TEMPO and chalcone
Armstrong, D. R. and Balloch, L. and Crawford, J. J. and Fleming, B. J. and Hogg, L. M. and Kennedy, A. R. and Klett, J. and Mulvey, R. E. and O'Hara, C. T. and Orr, S. A. and Robertson, Stuart (2012) Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] towards TEMPO and chalcone. Chemical Communications, 48 (10). pp. 1541-1543. ISSN 1359-7345
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More usually thought of as a base, the sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] 1 can undergo single electron transfer with TEMPO to give [(TMEDA)center dot Na(mu-TMP)-(mu-TEMPO )Zn(Bu-t)] 2 and [(TMEDA)center dot Na(mu-TEMPO )(2)-Zn(Bu-t)] 3; and with chalcone [PhCOCH=CHPh] gives [{(TMEDA)center dot Na(mu-TMP)Zn(Bu-t)}(2)(mu-OCPhCH=CHPhCH-PhCH=CPh-mu-O)] which contains two chalcone units C-C coupled though their benzylic C atoms.
Creators(s): |
Armstrong, D. R., Balloch, L., Crawford, J. J., Fleming, B. J. ![]() ![]() ![]() ![]() ![]() | Item type: | Article |
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ID code: | 39457 |
Keywords: | electron transfer , dialkyl-amido sodium zincate , chalcone, Chemistry, Materials Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Ceramics and Composites, Chemistry(all), Catalysis, Electronic, Optical and Magnetic Materials |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Pure Administrator |
Date deposited: | 30 Apr 2012 15:44 |
Last modified: | 01 Jan 2021 10:17 |
Related URLs: | |
URI: | https://strathprints.strath.ac.uk/id/eprint/39457 |
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