Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] towards TEMPO and chalcone

Armstrong, D. R. and Balloch, L. and Crawford, J. J. and Fleming, B. J. and Hogg, L. M. and Kennedy, A. R. and Klett, J. and Mulvey, R. E. and O'Hara, C. T. and Orr, S. A. and Robertson, Stuart (2012) Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] towards TEMPO and chalcone. Chemical Communications, 48 (10). pp. 1541-1543. ISSN 1359-7345

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Official URL: https://doi.org/10.1039/c1cc12869h

Abstract

More usually thought of as a base, the sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] 1 can undergo single electron transfer with TEMPO to give [(TMEDA)center dot Na(mu-TMP)-(mu-TEMPO )Zn(Bu-t)] 2 and [(TMEDA)center dot Na(mu-TEMPO )(2)-Zn(Bu-t)] 3; and with chalcone [PhCOCH=CHPh] gives [{(TMEDA)center dot Na(mu-TMP)Zn(Bu-t)}(2)(mu-OCPhCH=CHPhCH-PhCH=CPh-mu-O)] which contains two chalcone units C-C coupled though their benzylic C atoms.

Author(s):	Armstrong, D. R., Balloch, L., Crawford, J. J., Fleming, B. J. ORCID: https://orcid.org/0000-0003-0111-8679, Hogg, L. M., Kennedy, A. R. ORCID: https://orcid.org/0000-0003-3652-6015, Klett, J., Mulvey, R. E. ORCID: https://orcid.org/0000-0002-1015-2564, O'Hara, C. T. ORCID: https://orcid.org/0000-0002-1691-1568, Orr, S. A. and Robertson, Stuart ORCID: https://orcid.org/0000-0002-9330-8770
Item type:	Article
ID code:	39457
Keywords:	electron transfer , dialkyl-amido sodium zincate , chalcone, Chemistry, Materials Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Ceramics and Composites, Chemistry(all), Catalysis, Electronic, Optical and Magnetic Materials
Subjects:	Science > Chemistry
Department:	Faculty of Science > Pure and Applied Chemistry
Depositing user:	Pure Administrator
Date deposited:	30 Apr 2012 15:44
Last modified:	16 Aug 2019 02:35
Related URLs:	Scopus publication
URI:	https://strathprints.strath.ac.uk/id/eprint/39457
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