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Open Access research with a European policy impact...

The Strathprints institutional repository is a digital archive of University of Strathclyde's Open Access research outputs. Strathprints provides access to thousands of Open Access research papers by Strathclyde researchers, including by researchers from the European Policies Research Centre (EPRC).

EPRC is a leading institute in Europe for comparative research on public policy, with a particular focus on regional development policies. Spanning 30 European countries, EPRC research programmes have a strong emphasis on applied research and knowledge exchange, including the provision of policy advice to EU institutions and national and sub-national government authorities throughout Europe.

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Synthesis and structural characterisation of the mixed lithium–magnesium amide, [{PhCH2(Me2NCH2CH2)N}4Li2Mg] : a new type of magnesiate complex free of a donor solvent as ligand

Clegg, W. and Henderson, Kenneth W. and Mulvey, Robert and O'Neil, P.A. (1993) Synthesis and structural characterisation of the mixed lithium–magnesium amide, [{PhCH2(Me2NCH2CH2)N}4Li2Mg] : a new type of magnesiate complex free of a donor solvent as ligand. Journal of the Chemical Society, Chemical Communications, 1993 (11). pp. 969-970. ISSN 0022-4936

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Abstract

A mixture of the alkyl(amido)magnesium compound, [PhCH2(Me2NCH2CH2)NMgBun], the secondary amine, [PhCH2(Me2NCH2CH2)NH], and the alkyl lithium, (Bu(n)Li), produces the lithium amidomagnesiate, [{PhCH2(Me2NCH2CH2)N}4Li2Mg] which is shown by an X-ray diffraction study to have intramolecular (tertiary amine) N-Li coordinations in the solid state.