Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines
Mulvey, R.E. and Naseri, Vasel and Less, R.J. and McPartlin, Mary and Wright, Dominic S. (2010) Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines. Chemical Communications (London), 46 (27). pp. 5000-5002. ISSN 0009-241X
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Abstract
The room-temperature reactions of stannocene, Cp*2Sn, with a range of primary phosphines, RPH2, result in diphosphanes [RP(H)P(H)R]. The reactions involving Cp*2SnCl2, however, result in catalytic dehydrocoupling; the first example of main group metal catalysed dehydrocoupling to be identified.
Creators(s): |
Mulvey, R.E. ![]() | Item type: | Article |
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ID code: | 27638 |
Keywords: | phosphines, dehydrocoupling, stannocene, Physical and theoretical chemistry, Chemistry(all) |
Subjects: | Science > Chemistry > Physical and theoretical chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Mrs Gillian Neeson |
Date deposited: | 08 Oct 2010 19:51 |
Last modified: | 01 Jan 2021 04:44 |
Related URLs: | |
URI: | https://strathprints.strath.ac.uk/id/eprint/27638 |
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