Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines
Mulvey, R.E. and Naseri, Vasel and Less, R.J. and McPartlin, Mary and Wright, Dominic S. (2010) Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines. Chemical Communications (London), 46 (27). pp. 5000-5002. ISSN 0009-241X
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Abstract
The room-temperature reactions of stannocene, Cp*2Sn, with a range of primary phosphines, RPH2, result in diphosphanes [RP(H)P(H)R]. The reactions involving Cp*2SnCl2, however, result in catalytic dehydrocoupling; the first example of main group metal catalysed dehydrocoupling to be identified.
ORCID iDs
Mulvey, R.E.
ORCID: https://orcid.org/0000-0002-1015-2564, Naseri, Vasel, Less, R.J., McPartlin, Mary and Wright, Dominic S.;
Item type: Article ID code: 27638 Dates: DateEvent2010PublishedKeywords: phosphines, dehydrocoupling, stannocene, Physical and theoretical chemistry, Chemistry(all) Subjects: Science > Chemistry > Physical and theoretical chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Mrs Gillian Neeson Date deposited: 08 Oct 2010 19:51 Last modified: 19 Mar 2021 03:26 Related URLs: URI: https://strathprints.strath.ac.uk/id/eprint/27638
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