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Diisopropylamide and TMP turbo-grignard reagents : a structural rationale for their contrasting reactivities

Armstrong, David R. and Garcia-Álvarez, Pablo and Kennedy, Alan R. and Mulvey, Robert E. and Parkinson, John A. (2010) Diisopropylamide and TMP turbo-grignard reagents : a structural rationale for their contrasting reactivities. Angewandte Chemie International Edition, 49 (18). 3185–3188. ISSN 1433-7851

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Abstract

A neutral dimeric molecule in crystal form, the diisopropylamido turbo-Grignard reagent "(iPr2N)MgCl⋅LiCl" (see structure; blue N, red O, green Mg, yellow Cl, black C) separates into several charged ate species in dynamic exchange with each other in THF solution as determined by a combination of EXSY and DOSY NMR studies.

Item type: Article
ID code: 27619
Notes: This is the peer reviewed version of the following article: Armstrong, DR, Garcia-Álvarez, P, Kennedy, AR, Mulvey, RE & Parkinson, JA 2010, 'Diisopropylamide and TMP turbo-grignard reagents: a structural rationale for their contrasting reactivities' Angewandte Chemie International Edition , vol 49, no. 18, pp. 3185–3188, which has been published in final form at https://doi.org/10.1002/anie.201000539. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
Keywords: amides, grignard reagents, metalation, structure elucidation, DOSY NMR spectroscopy, Chemistry, Chemistry(all)
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Depositing user: Mrs Gillian Neeson
Date deposited: 04 Oct 2010 15:31
Last modified: 21 Sep 2017 10:39
Related URLs:
URI: https://strathprints.strath.ac.uk/id/eprint/27619
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