Diisopropylamide and TMP turbo-grignard reagents : a structural rationale for their contrasting reactivities
Armstrong, David R. and Garcia-Álvarez, Pablo and Kennedy, Alan R. and Mulvey, Robert E. and Parkinson, John A. (2010) Diisopropylamide and TMP turbo-grignard reagents : a structural rationale for their contrasting reactivities. Angewandte Chemie International Edition, 49 (18). 3185–3188. ISSN 1433-7851
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Official URL: https://doi.org/10.1002/anie.201000539
Abstract
A neutral dimeric molecule in crystal form, the diisopropylamido turbo-Grignard reagent "(iPr2N)MgCl⋅LiCl" (see structure; blue N, red O, green Mg, yellow Cl, black C) separates into several charged ate species in dynamic exchange with each other in THF solution as determined by a combination of EXSY and DOSY NMR studies.
Creators(s): |
Armstrong, David R., Garcia-Álvarez, Pablo, Kennedy, Alan R. ![]() ![]() ![]() | Item type: | Article |
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ID code: | 27619 |
Notes: | This is the peer reviewed version of the following article: Armstrong, DR, Garcia-Álvarez, P, Kennedy, AR, Mulvey, RE & Parkinson, JA 2010, 'Diisopropylamide and TMP turbo-grignard reagents: a structural rationale for their contrasting reactivities' Angewandte Chemie International Edition , vol 49, no. 18, pp. 3185–3188, which has been published in final form at https://doi.org/10.1002/anie.201000539. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. |
Keywords: | amides, grignard reagents, metalation, structure elucidation, DOSY NMR spectroscopy, Chemistry, Chemistry(all) |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Mrs Gillian Neeson |
Date deposited: | 04 Oct 2010 15:31 |
Last modified: | 26 Jan 2021 02:22 |
Related URLs: | |
URI: | https://strathprints.strath.ac.uk/id/eprint/27619 |
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