Structural elaboration of the surprising ortho-zincation of benzyl methyl ether

Balloch, Liam and Kennedy, Alan R. and Klett, Jan and Mulvey, Robert E. and O'Hara, Charles T. (2010) Structural elaboration of the surprising ortho-zincation of benzyl methyl ether. Chemical Communications (London), 46 (13). pp. 2319-2321. ISSN 0009-241X (https://doi.org/10.1039/b924791b)

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Abstract

Breaking with convention, the reaction of the sodium zincate, [(TMEDA)Na(μ-TMP)(μ-tBu)Zn(tBu)] with benzyl methyl ether (PhCH2OMe) produces exclusively an ortho-zincated intermediate [(TMEDA)Na(μ-TMP)(μ-C6H4CH2OMe)Zn(tBu)] instead of the expected 'thermodynamic' α-metallated product.

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• Item metadata

  Item type:	Article
  ID code:	27629
  Dates:	Date Event 7 April 2010 Published 20 January 2010 Published Online 23 December 2009 Accepted
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Mrs Gillian Neeson
  Date deposited:	05 Oct 2010 14:36
  Last modified:	11 Apr 2024 00:36
  Related URLs:	Scopus publication
  URI:	https://strathprints.strath.ac.uk/id/eprint/27629