Synthesis of the mixed lithium-potassium-(bis)magnesium N-metallated / N, C-dimetallated amide [Li2K2Mg4 {But(Me3Si)N} 4{But[Me2(H2C)Si]N}4] : an inverse crown molecule with an atomless cavity
Forbes, G.C. and Kenley, F.R. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Parkinson, J.A. (2003) Synthesis of the mixed lithium-potassium-(bis)magnesium N-metallated / N, C-dimetallated amide [Li2K2Mg4 {But(Me3Si)N} 4{But[Me2(H2C)Si]N}4] : an inverse crown molecule with an atomless cavity. Chemical Communications (London), 2003 (10). pp. 1140-1141. ISSN 0009-241X
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Abstract
Unlike previous members of the inverse crown family, which are heterobimetallic and have cationic rings surrounding anionic cores, the title compound is heterotrimetallic and its "guest" anion is intramolecularly stitched into the complex fused-ring structure of its cationic "host".
Creators(s): |
Forbes, G.C., Kenley, F.R., Kennedy, A.R. ![]() ![]() ![]() ![]() | Item type: | Article |
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ID code: | 1080 |
Keywords: | inverse crown family, heterobimetallic, cationic rings surrounding anionic cores, heterotrimetallic, guest anion, intramolecularly, cationic, Chemistry, Chemistry(all) |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry Unknown Department |
Depositing user: | Catriona Mccallum |
Date deposited: | 19 May 2006 |
Last modified: | 20 Jan 2021 16:54 |
URI: | https://strathprints.strath.ac.uk/id/eprint/1080 |
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