Synthesis of the mixed lithium-potassium-(bis)magnesium N-metallated / N, C-dimetallated amide [Li2K2Mg4 {But(Me3Si)N} 4{But[Me2(H2C)Si]N}4] : an inverse crown molecule with an atomless cavity

Forbes, G.C. and Kenley, F.R. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Parkinson, J.A. (2003) Synthesis of the mixed lithium-potassium-(bis)magnesium N-metallated / N, C-dimetallated amide [Li2K2Mg4 {But(Me3Si)N} 4{But[Me2(H2C)Si]N}4] : an inverse crown molecule with an atomless cavity. Chemical Communications (London), 2003 (10). pp. 1140-1141. ISSN 0009-241X (https://doi.org/10.1039/b301374j)

Abstract

Unlike previous members of the inverse crown family, which are heterobimetallic and have cationic rings surrounding anionic cores, the title compound is heterotrimetallic and its "guest" anion is intramolecularly stitched into the complex fused-ring structure of its cationic "host".

ORCID iDs

Kennedy, A.R. ORCID: https://orcid.org/0000-0003-3652-6015

Mulvey, R.E. ORCID: https://orcid.org/0000-0002-1015-2564

Parkinson, J.A. ORCID: https://orcid.org/0000-0003-4270-6135

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  Item type:	Article
  ID code:	1080
  Dates:	Date Event 17 April 2003 Published
  Keywords:	inverse crown family, heterobimetallic, cationic rings surrounding anionic cores, heterotrimetallic, guest anion, intramolecularly, cationic, Chemistry, Chemistry(all)
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry Unknown Department
  Depositing user:	Users 45 not found.
  Date deposited:	19 May 2006
  Last modified:	19 May 2023 01:01
  URI:	https://strathprints.strath.ac.uk/id/eprint/1080