Synthesis of the mixed lithium-potassium-(bis)magnesium N-metallated / N, C-dimetallated amide [Li2K2Mg4 {But(Me3Si)N} 4{But[Me2(H2C)Si]N}4] : an inverse crown molecule with an atomless cavity

Forbes, G.C. and Kenley, F.R. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Parkinson, J.A. (2003) Synthesis of the mixed lithium-potassium-(bis)magnesium N-metallated / N, C-dimetallated amide [Li2K2Mg4 {But(Me3Si)N} 4{But[Me2(H2C)Si]N}4] : an inverse crown molecule with an atomless cavity. Chemical Communications (London), 2003 (10). pp. 1140-1141. ISSN 0009-241X

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Abstract

Unlike previous members of the inverse crown family, which are heterobimetallic and have cationic rings surrounding anionic cores, the title compound is heterotrimetallic and its "guest" anion is intramolecularly stitched into the complex fused-ring structure of its cationic "host".

Creators(s): Forbes, G.C., Kenley, F.R., Kennedy, A.R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Mulvey, R.E. ORCID logoORCID: https://orcid.org/0000-0002-1015-2564, O'Hara, C.T. ORCID logoORCID: https://orcid.org/0000-0002-1691-1568 and Parkinson, J.A. ORCID logoORCID: https://orcid.org/0000-0003-4270-6135;
Item type:Article
ID code:1080
Keywords:inverse crown family, heterobimetallic, cationic rings surrounding anionic cores, heterotrimetallic, guest anion, intramolecularly, cationic, Chemistry, Chemistry(all)
Subjects:Science > Chemistry
Department:Faculty of Science > Pure and Applied Chemistry
Unknown Department
Depositing user: Catriona Mccallum
Date deposited:19 May 2006
Last modified:09 Jul 2020 01:01
URI:https://strathprints.strath.ac.uk/id/eprint/1080
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