Ambient temperature zincation of N-Boc pyrrolidine and its solvent dependency
Garden, Jennifer A. and Kennedy, Alan R. and Mulvey, Robert E. and Robertson, Stuart D. (2012) Ambient temperature zincation of N-Boc pyrrolidine and its solvent dependency. Chemical Communications, 48 (43). pp. 5265-5267. ISSN 1359-7345
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Abstract
Sodium TMP-zincate, [(TMEDA)Na(TMP)(Bu-t)Zn(Bu-t)], can deproto-zincate N-Boc pyrrolidine at ambient temperature in hexane solution, whereas in toluene the captured alpha-carbanion of the heterocycle attacks the solvent setting off a cascade of reactions that ultimately produce a pyrrolidine-substituted enolate.
Creators(s): |
Garden, Jennifer A., Kennedy, Alan R. ![]() ![]() ![]() | Item type: | Article |
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ID code: | 39877 |
Keywords: | zincation , N-Boc pyrrolidine , solvent dependency, Physical and theoretical chemistry, Materials Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Ceramics and Composites, Chemistry(all), Catalysis, Electronic, Optical and Magnetic Materials |
Subjects: | Science > Chemistry > Physical and theoretical chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Pure Administrator |
Date deposited: | 30 May 2012 15:14 |
Last modified: | 20 Jan 2021 20:08 |
Related URLs: | |
URI: | https://strathprints.strath.ac.uk/id/eprint/39877 |
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