Crystal structure of sodium iodide·(diglyme) : An unprecedented bridging role for diglyme
Mulvey, Robert and Clegg, W. and Barr, Donald and Snaith, R. (1986) Crystal structure of sodium iodide·(diglyme) : An unprecedented bridging role for diglyme. Polyhedron, 5 (12). pp. 2109-2111. ISSN 0277-5387
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Abstract
The diglyme adduct of sodium iodide, NaI·(CH3OCH2CH2)2O, has been structurally characterized by X-ray diffraction. It forms infinite zig-zag chains which, unlike most complexes of the salt, retain NaI bonds. In addition, diglyme molecules bridge pairs of Na atoms through four-co-ordinate O atoms, so representing a new role for this neutral oxygen donor.
| Creators(s): |
Mulvey, Robert  ORCID: https://orcid.org/0000-0002-1015-2564, Clegg, W., Barr, Donald and Snaith, R.;
| Item type: | Article |
|---|---|
| ID code: | 37560 |
| Keywords: | crystal structure, sodium iodide, Chemistry, Materials Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Depositing user: | Pure Administrator |
| Date deposited: | 09 Feb 2012 17:52 |
| Last modified: | 20 Jan 2021 19:58 |
| URI: | https://strathprints.strath.ac.uk/id/eprint/37560 |
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