Lithium and aluminium carbamato derivatives of the utility amide 2, 2, 6, 6- tetramethylpiperidide

Mulvey, R.E. and Kennedy, A.R. and Robertson, Stuart (2010) Lithium and aluminium carbamato derivatives of the utility amide 2, 2, 6, 6- tetramethylpiperidide. Dalton Transactions, 39. pp. 6190-6197. ISSN 1477-9234

[thumbnail of strathprints027625.pdf]
Preview
 PDF (strathprints027625.pdf)
strathprints027625.pdf
Accepted Author Manuscript
Download (1MB)| Preview

    Abstract

    Insertion of CO2 into the metal-N bond of a series of synthetically-important alkali-metal TMP (2,2,6,6-tetramethylpiperidide) complexes has been studied. Determined by X-ray crystallography, the molecular structure of the TMEDA-solvated Li derivative shows a central 8-membered (LiOCO)2 ring lying in a chair conformation with distorted tetrahedral lithium centres. While trying to obtain crystals of a THF solvated derivative, a mixed carbonato/carbamato dodecanuclear lithium cluster was formed containing two central (CO3)2- fragments and eight O2CTMP ligands with four distinct bonding modes. A bisalkylaluminium carbamato complex has also been prepared via two different methods (CO2 insertion into a pre-formed Al-N bond and ligand transfer from the corresponding lithium reagent) which adopts a dimeric structure in the solid state.

    ORCID iDs

    Mulvey, R.E. ORCID logoORCID: https://orcid.org/0000-0002-1015-2564, Kennedy, A.R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015 and Robertson, Stuart ORCID logoORCID: https://orcid.org/0000-0002-9330-8770;
    • Item type:Article
      ID code:27625
      Dates:
      Date
      Event
      2010
      Published
      Keywords:lithium, aluminium, carbamato derivatives, chemistry, Chemistry
      Subjects:Science > Chemistry
      Department:Faculty of Science > Pure and Applied Chemistry
      Depositing user: Mrs Gillian Neeson
      Date deposited:05 Oct 2010 15:07
      Last modified:31 Jul 2021 02:20
      Related URLs:
      URI:https://strathprints.strath.ac.uk/id/eprint/27625
    CORE (COnnecting REpositories)