Three model structural types in lithium amide chemistry: the crystal and molecular structures of dimeric [Ph(Me)NLi·TMEDA]2(TMEDA = Me2NCH2CH2NMe2) and monomeric Ph(naphthyl)NLi·PMDETA [PMDETA = MeN(CH2CH2NMe2)2], and of [Ph(naphthyl)NLi·TMEDA]2, a ‘loose dimer’

BARR, D and CLEGG, W and Mulvey, Robert and SNAITH, R and WRIGHT, D S (1987) Three model structural types in lithium amide chemistry: the crystal and molecular structures of dimeric [Ph(Me)NLi·TMEDA]2(TMEDA = Me2NCH2CH2NMe2) and monomeric Ph(naphthyl)NLi·PMDETA [PMDETA = MeN(CH2CH2NMe2)2], and of [Ph(naphthyl)NLi·TMEDA]2, a ‘loose dimer’. Journal of the Chemical Society, Chemical Communications (10). pp. 716-718. ISSN 0022-4936

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Abstract

The crystal structures of three amidolithium complexes are reported, those of [Ph(Me)NLi·TMEDA]2(TMEDA = Me2NCH2CH2NMe2), (1), and Ph(naphthyl)NLi·PMDETA [PMDETA = MeN(CH2CH2NMe2)2], (2), whose Li atoms are all four-co-ordinate, confirming predicted structural types, while a new structural option is found for [Ph(naphthyl)NLi·TMEDA]n, (3), whose monomeric (n= 1) moolecules, each containing a three-co-ordinate Li atom, are prompted to associate looselyin pairs (n= 2)via intermolecular Li phenyl interactions.

Creators(s): BARR, D, CLEGG, W, Mulvey, Robert ORCID logoORCID: https://orcid.org/0000-0002-1015-2564, SNAITH, R and WRIGHT, D S;
Item type:Article
ID code:37494
Keywords:lithium amide chemistry , crystal structures, amidolithium complexes, Physical and theoretical chemistry, Molecular Medicine
Subjects:Science > Chemistry > Physical and theoretical chemistry
Department:Faculty of Science > Pure and Applied Chemistry
Depositing user: Pure Administrator
Date deposited:08 Feb 2012 15:57
Last modified:20 Jan 2021 20:00
URI:https://strathprints.strath.ac.uk/id/eprint/37494
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