Potassium-mediated zincation of ferrocene and ruthenocene : potassium, the architect behind supramolecular structural variations

Clegg, William and Conway, Ben and García-Álvarez, Pablo and Kennedy, Alan R. and Klett, Jan and Mulvey, Robert E. and Russo, Luca (2010) Potassium-mediated zincation of ferrocene and ruthenocene : potassium, the architect behind supramolecular structural variations. Dalton Transactions, 39. pp. 62-65. ISSN 1477-9234

[thumbnail of strathprints027630.pdf]
Preview
 Text (strathprints027630.pdf)
strathprints027630.pdf
Accepted Author Manuscript
Download (328kB)| Preview

    Abstract

    Direct zincation of ferrocene and ruthenocene by the synergic base [PMDETA.K(μ-TMP)(μ-Me)Zn(Me)] produces the monozincated complexes [{PMDETA.K(μ-Me)2Zn(Fc)}∞] and [{PMDETA.K(μ-Me)2Zn(Rc)}2] respectively, having similar monomeric (dinuclear) units but aggregating supramolecularly in very different polymeric and dimeric forms.

    ORCID iDs

    Clegg, William, Conway, Ben, García-Álvarez, Pablo, Kennedy, Alan R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Klett, Jan, Mulvey, Robert E. ORCID logoORCID: https://orcid.org/0000-0002-1015-2564 and Russo, Luca;
    • Item type:Article
      ID code:27630
      Dates:
      Date
      Event
      2010
      Published
      30 September 2009
      Published Online
      16 September 2009
      Accepted
      Keywords:potassium-mediated zincation, ferrocene, ruthenocene, potassium, supramolecular variations, Chemistry, Chemistry(all)
      Subjects:Science > Chemistry
      Department:Faculty of Science > Pure and Applied Chemistry
      Depositing user: Mrs Gillian Neeson
      Date deposited:05 Oct 2010 14:14
      Last modified:13 May 2021 09:51
      Related URLs:
      URI:https://strathprints.strath.ac.uk/id/eprint/27630
    CORE (COnnecting REpositories)