Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations
Mulvey, R.E. and Kennedy, A.R. and Klett, J. and Garcia-Alvarez, P. (2010) Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations. Dalton Transactions, 39. pp. 62-65. ISSN 1477-9234
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Official URL: http://dx.doi.org/10.1039/b917202p
Abstract
Direct zincation of ferrocene and ruthenocene by the synergic base [PMDETA.K(μ-TMP)(μ-Me)Zn(Me)] produces the monozincated complexes [{PMDETA.K(μ-Me)2Zn(Fc)}∞] and [{PMDETA.K(μ-Me)2Zn(Rc)}2] respectively, having similar monomeric (dinuclear) units but aggregating supramolecularly in very different polymeric and dimeric forms.
Creators(s): |
Mulvey, R.E. ![]() ![]() | Item type: | Article |
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ID code: | 27630 |
Keywords: | potassium-mediated zincation, ferrocene, ruthenocene, potassium, supramolecular variations, Chemistry |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Mrs Gillian Neeson |
Date deposited: | 05 Oct 2010 14:14 |
Last modified: | 26 Feb 2021 04:46 |
Related URLs: | |
URI: | https://strathprints.strath.ac.uk/id/eprint/27630 |
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