Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations

Mulvey, R.E. and Kennedy, A.R. and Klett, J. and Garcia-Alvarez, P. (2010) Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations. Dalton Transactions, 39. pp. 62-65. ISSN 1477-9234

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    Abstract

    Direct zincation of ferrocene and ruthenocene by the synergic base [PMDETA.K(μ-TMP)(μ-Me)Zn(Me)] produces the monozincated complexes [{PMDETA.K(μ-Me)2Zn(Fc)}∞] and [{PMDETA.K(μ-Me)2Zn(Rc)}2] respectively, having similar monomeric (dinuclear) units but aggregating supramolecularly in very different polymeric and dimeric forms.

    Author(s):Mulvey, R.E. ORCID logoORCID: https://orcid.org/0000-0002-1015-2564, Kennedy, A.R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Klett, J. and Garcia-Alvarez, P.
    Item type:Article
    ID code:27630
    Keywords:potassium-mediated zincation, ferrocene, ruthenocene, potassium, supramolecular variations, Chemistry
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Mrs Gillian Neeson
    Date deposited:05 Oct 2010 14:14
    Last modified:17 Nov 2019 01:19
    Related URLs:
    URI:https://strathprints.strath.ac.uk/id/eprint/27630
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