Potassium-mediated zincation of ferrocene and ruthenocene : potassium, the architect behind supramolecular structural variations

Clegg, William and Conway, Ben and García-Álvarez, Pablo and Kennedy, Alan R. and Klett, Jan and Mulvey, Robert E. and Russo, Luca (2010) Potassium-mediated zincation of ferrocene and ruthenocene : potassium, the architect behind supramolecular structural variations. Dalton Transactions, 39. pp. 62-65. ISSN 1477-9234 (https://doi.org/10.1039/b917202p)

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Abstract

Direct zincation of ferrocene and ruthenocene by the synergic base [PMDETA.K(μ-TMP)(μ-Me)Zn(Me)] produces the monozincated complexes [{PMDETA.K(μ-Me)2Zn(Fc)}∞] and [{PMDETA.K(μ-Me)2Zn(Rc)}2] respectively, having similar monomeric (dinuclear) units but aggregating supramolecularly in very different polymeric and dimeric forms.

ORCID iDs

Clegg, William, Conway, Ben, García-Álvarez, Pablo, Kennedy, Alan R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Klett, Jan, Mulvey, Robert E. ORCID logoORCID: https://orcid.org/0000-0002-1015-2564 and Russo, Luca;
  • Item type:Article
    ID code:27630
    Dates:
    Date
    Event
    2010
    Published
    30 September 2009
    Published Online
    16 September 2009
    Accepted
    Keywords:potassium-mediated zincation, ferrocene, ruthenocene, potassium, supramolecular variations, Chemistry, Chemistry(all)
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Mrs Gillian Neeson
    Date deposited:05 Oct 2010 14:14
    Last modified:21 Mar 2022 01:19
    Related URLs:
    URI:https://strathprints.strath.ac.uk/id/eprint/27630
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