Inverse crown ether complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo- centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interac

Kennedy, A.R. and Mulvey, R.E. and Raston, C.L. and Roberts, B.A. and Rowlings, R.B. (1999) Inverse crown ether complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo- centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interac. Chemical Communications (London), 1999 (4). pp. 353-354. ISSN 0009-241X (http://dx.doi.org/10.1039/a809681c)

Abstract

The title compound represents the first potassium example of a novel class of amide-supported heterobimetallic macrocycle having a dicationic (N4K2Mg2)2+ octagonal ring framework surrounding a dianionic (O2)2- core.

ORCID iDs

Kennedy, A.R. ORCID: https://orcid.org/0000-0003-3652-6015

Mulvey, R.E. ORCID: https://orcid.org/0000-0002-1015-2564

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  Item type:	Article
  ID code:	1290
  Dates:	Date Event 1999 Published
  Keywords:	potassium, amide-supported heterobimetallic macrocycle, dicationic, octagonal ring, Chemistry, Chemistry(all)
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Catriona Mccallum
  Date deposited:	27 Jun 2006
  Last modified:	04 Jun 2021 02:20
  URI:	https://strathprints.strath.ac.uk/id/eprint/1290