Inverse crown ether complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo- centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interac

Kennedy, A.R. and Mulvey, R.E. and Raston, C.L. and Roberts, B.A. and Rowlings, R.B. (1999) Inverse crown ether complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo- centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interac. Chemical Communications (London), 1999 (4). pp. 353-354. ISSN 0009-241X

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Abstract

The title compound represents the first potassium example of a novel class of amide-supported heterobimetallic macrocycle having a dicationic (N4K2Mg2)2+ octagonal ring framework surrounding a dianionic (O2)2- core.

Creators(s): Kennedy, A.R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Mulvey, R.E. ORCID logoORCID: https://orcid.org/0000-0002-1015-2564, Raston, C.L., Roberts, B.A. and Rowlings, R.B.;
Item type:Article
ID code:1290
Keywords:potassium, amide-supported heterobimetallic macrocycle, dicationic, octagonal ring, Chemistry, Chemistry(all)
Subjects:Science > Chemistry
Department:Faculty of Science > Pure and Applied Chemistry
Depositing user: Catriona Mccallum
Date deposited:27 Jun 2006
Last modified:20 Jan 2021 16:42
URI:https://strathprints.strath.ac.uk/id/eprint/1290
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