Modifying alkylzinc reactivity with 2,2 '-dipyridylamide : activation of tBu-Zn bonds for para-alkylation of benzophenone
Armstrong, David R. and Garden, Jennifer A. and Kennedy, Alan R. and Mulvey, Robert and Robertson, Stuart D. (2013) Modifying alkylzinc reactivity with 2,2 '-dipyridylamide : activation of tBu-Zn bonds for para-alkylation of benzophenone. Angewandte Chemie International Edition, 52 (28). pp. 7190-7193. ISSN 1433-7851
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Official URL: https://doi.org/10.1002/anie.201302426
Abstract
Undercover agent: Masquerading as a simple donor-acceptor complex (1), sodium amide substoichiometrically activates tBuZn for the challenging 1,6-addition of a tert-butyl group to benzophenone. In contrast, the nonactivated tBuZn is ineffectual.
Creators(s): |
Armstrong, David R., Garden, Jennifer A., Kennedy, Alan R., Mulvey, Robert ![]() ![]() | Item type: | Article |
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ID code: | 44630 |
Keywords: | zinc, reagents, ligands, alkylation, metalation, alkali metal, crystal-structure, dipyridylamine, chloride, 2,2-dipyridylamine, sodium TMP-zincate, chemistry, homogeneous catalysis, amides, complexes, Chemistry, Chemistry(all), Biochemistry |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Pure Administrator |
Date deposited: | 28 Aug 2013 13:39 |
Last modified: | 20 Jan 2021 20:47 |
Related URLs: | |
URI: | https://strathprints.strath.ac.uk/id/eprint/44630 |
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