Lewis base stabilized lithium TMP-aluminates: an unexpected fragmentation and capture reaction involving cyclic ether 1,4-dioxane
Mulvey, R.E. and Kennedy, A.R. and Klett, J. and Hevia, E. and Garcia Alvarez, Joaquin (2007) Lewis base stabilized lithium TMP-aluminates: an unexpected fragmentation and capture reaction involving cyclic ether 1,4-dioxane. Chemical Communications (London) (23). pp. 2402-2404. ISSN 0009-241X (https://doi.org/10.1039/b700785j)
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Three Lewis base variations of the synthetically useful aluminate [L?Li(TMP)(iBu)Al(iBu)2], where L is TMPH, Et3N or PhC(LO)NiPr2, are reported, together with the reaction of the benzamide complex with 1,4-dioxane, which surprisingly leads to fragmentation of the cyclic ether and capture of its alkoxy vinyl ether residue within a novel dilithium dialuminium hexaalkyl aggregate.
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Item type: Article ID code: 27771 Dates: DateEventMarch 2007PublishedSubjects: Science > Chemistry > Physical and theoretical chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Miss Stephanie Cassidy Date deposited: 11 Oct 2010 19:39 Last modified: 08 Apr 2024 18:11 URI: https://strathprints.strath.ac.uk/id/eprint/27771
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