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2024

Judge, Neil R. and Hevia, Eva (2024) Combining two relatively weak bases (Zn(TMP)2 and KOtBu) for the regioselective metalation of non-activated arenes and heteroarenes. Chemical Science, 15 (36). pp. 14757-14765. ISSN 2041-6539

2022

Ballmann, Gerd M. and Gentner, Thomas X. and Kennedy, Alan R. and Hevia, Eva and Mulvey, Robert E. (2022) Heavy alkali metal manganate complexes : synthesis, structures and solvent-induced dissociation effects. Chemistry - A European Journal, 28 (55). e202201716. ISSN 1521-3765

2021

Maddock, Lewis C. H. and Morton, Rebekka and Kennedy, Alan R. and Hevia, Eva (2021) Lateral metallation and redistribution reactions of sodium ferrates containing bulky 2,6-Diisopropyl- N -(trimethylsilyl)anilide ligands. Chemistry - A European Journal, 27 (61). pp. 15181-15187. ISSN 1521-3765

Maddock, Lewis C. H. and Mu, Manting and Kennedy, Alan R. and García-Melchor, Max and Hevia, Eva (2021) Facilitating the ferration of aromatic substrates through intramolecular sodium mediation. Angewandte Chemie - International Edition, 60 (28). pp. 15296-15301. ISSN 1521-3773

2020

Mulks, Florian F. and Bole, Leonie J. and Davin, Laia and Hernán-Gómez, Alberto and Kennedy, Alan and García-Álvarez, Joaquín and Hevia, Eva (2020) Ambient moisture accelerates hydroamination reactions of vinylarenes with alkali-metal amides under air. Angewandte Chemie - International Edition, 59 (43). pp. 19021-19026. ISSN 1521-3773

Honeyman, Gordon W. and Armstrong, David R. and Clegg, William and Hevia, Eva and Kennedy, Alan R. and McLellan, Ross and Orr, Samantha A. and Parkinson, John A. and Ramsay, Donna L. and Robertson, Stuart D. and Towie, Stephen and Mulvey, Robert E. (2020) A regioselectively 1, 1',3 ,3'-tetrazincated ferrocene complex displaying core and peripheral reactivity. Chemical Science, 11 (25). pp. 6510-6520. ISSN 2041-6539

2019

Balkenhohl, Moritz and Ziegler, Dorothée S. and Desaintjean, Alexandre and Bole, Leonie J. and Kennedy, Alan R. and Hevia, Eva and Knochel, Paul (2019) Preparation of polyfunctional arylzinc organometallics in toluene by halogen/zinc exchange reactions. Angewandte Chemie International Edition, 58 (37). pp. 12898-12902. ISSN 1521-3773

Fairley, Michael and Davin, Laia and Hernan-Gomez, Alberto and García-Álvarez, Joaquín and O'Hara, Charles T. and Hevia, Eva (2019) s-Block cooperative catalysis : alkali metal magnesiate-catalysed cyclisation of alkynols. Chemical Science, 10 (22). pp. 5821-5831. ISSN 2041-6539

Davin, Laia and Hernán-Gómez, Alberto and McLaughlin, Calum and Kennedy, Alan R. and McLellan, Ross and Hevia, Eva (2019) Alkali metal and stoichiometric effects in intermolecular hydroamination catalysed by lithium, sodium and potassium magnesiates. Dalton Transactions, 48 (23). pp. 8122-8130. ISSN 1477-9226

Bole, Leonie J. and Davin, Laia and Kennedy, Alan R. and McLellan, Ross and Hevia, Eva (2019) Magnesium-mediated arylation of amines via C-F bond activation of fluoroarenes. Chemical Communications, 55 (30). pp. 4339-4342. ISSN 1359-7345

McLellan, Ross and Uzelac, Marina and Bole, Leonie J. and Gil-Negrete, Jose Maria and Armstrong, David R. and Kennedy, Alan R. and Mulvey, Robert E. and Hevia, Eva (2019) Alkali metal effects in trans-metal-trapping (TMT) : comparing LiTMP with NaTMP in cooperative MTMP/Ga(CH2SiMe3)3 metalation reactions. Synthesis, 51 (05). pp. 1207-1215. ISSN 0039-7881

2018

Hevia, Eva and McLellan, Ross and Davin, Laia and Clegg, William and Kennedy, Alan and Probert, Michael R (2018) Structural and synthetic insights into pyridine homocouplings mediated by a β-diketiminato magnesium amide complex. Chemistry - A European Journal. ISSN 1521-3765

Lemmerz, Lara E. and McLellan, Ross and Judge, Neil R. and Kennedy, Alan R. and Orr, Samantha A. and Uzelac, Marina and Hevia, Eva and Robertson, Stuart D. and Okuda, Jun and Mulvey, Robert E. (2018) Donor-influenced structure-activity correlations in stoichiometric and catalytic reactions of lithium monoamido-monohydrido-dialkylaluminates. Chemistry - A European Journal, 24 (39). pp. 9940-9948. ISSN 1521-3765

García-Álvarez, Joaquín and Hevia, Eva and Capriati, Vito (2018) The future of polar organometallic chemistry written in bio-based solvents and water. Chemistry - A European Journal. ISSN 1521-3765

Hernan-Gomez, Alberto and Orr, Samantha and Uzelac, Marina and Kennedy, Alan and Barroso, Santiago and Jusseau, Xavier and Lemaire, Sebastien and Hevia, Eva (2018) Exploiting synergistic effects in organozinc chemistry for direct stereoselective C‐glycosylation reactions at room temperature. Angewandte Chemie International Edition. ISSN 1521-3773

Hevia, Eva and Hernán-Gómez, Alberto and Uzelac, Marina and Baillie, Sharon and Armstrong, David and Kennedy, Alan and Fuentes, Maria Ángeles (2018) Molecular manipulations of a utility nitrogen-heterocyclic carbene by sodium magnesiate complexes and transmetallation chemistry with gold complexes. Chemistry - A European Journal. ISSN 1521-3765

Pollard, Victoria A. and Orr, Samantha A. and McLellan, Ross and Kennedy, Alan R. and Hevia, Eva and Mulvey, Robert E. (2018) Lithium diamidodihydridoaluminates : bimetallic cooperativity in catalytic hydroboration and metallation applications. Chemical Communications, 54 (10). pp. 1233-1236. ISSN 1359-7345

Uzelac, Marina and Hevia, Eva (2018) Polar organometallic strategies for regioselective C-H metallation of N-heterocyclic Carbenes. Chemical Communications, 54. pp. 2455-2462. ISSN 1359-7345

2017

Maddock, Lewis C. H. and Nixon, Tracy and Kennedy, Alan R. and Probert, Michael R. and Clegg, William and Hevia, Eva (2017) Utilising sodium-mediated ferration for regioselective functionalisation of fluoroarenes via C-H and C-F bond activations. Angewandte Chemie International Edition, 57 (1). pp. 187-191. ISSN 1521-3773

Rodríguez-Álvarez, María J. and García-Álvarez, Joaquín and Uzelac, Marina and Fairley, Michael and O'Hara, Charles T. and Hevia, Eva (2017) Introducing glycerol as a sustainable solvent to organolithium chemistry : ultrafast chemoselective addition of aryllithium reagents to nitriles under air and at ambient temperature. Chemistry - A European Journal. ISSN 1521-3765

Davin Cardona, Laia and McLellan, Ross and Kennedy, Alan R. and Hevia, Eva (2017) Ligand-induced reactivity of β-diketiminate magnesium complexes for regioselective functionalization of fluoroarenes via C-H or C-F bond activations. Chemical Communications (85). pp. 11650-11653. ISSN 1359-7345

Davin, Laia and McLellan, Ross and Hernán-Gómez, Alberto and Clegg, Bill and Kennedy, A R and Stepek, Iain and Mertens, Maria and Hevia, Eva (2017) Regioselective magnesiation of N-heterocyclic molecules: securing insecure cyclic anions by a β-diketiminate-magnesium clamp. Chemical Communications. ISSN 1359-7345

McLellan, Ross and Uzelac, Marina and Kennedy, Alan R. and Hevia, Eva and Mulvey, Robert E. (2017) LiTMP trans-metal-trapping of fluorinated aromatic molecules : a comparative study of Al and Ga carbanion traps. Angewandte Chemie International Edition, 56 (32). pp. 9566-9570. ISSN 1521-3773

Hernán‐gómez, Alberto and Kennedy, Alan r. and Hevia, Eva (2017) C-N bond activation and ring opening of a saturated N heterocyclic carbene via lateral alkali-metal-mediated metallation (AMMM). Angewandte Chemie International Edition, 56 (23). pp. 6632-6635. ISSN 1521-3773

Uzelac, Marina and Kennedy, Alan R. and Hevia, Eva (2017) Trans-metal-trapping meets FLP chemistry : Ga(CH2SiMe3)3 induced C-H functionalizations. Inorganic Chemistry. ISSN 1520-510X

Maddock, Lewis Caradoc Huw and Borliovic, Ivana and McIntyre, Jamie and Kennedy, Alan R. and Aromi, Guilem and Hevia, Eva (2017) Synthetic, structural and magnetic implications of introducing 2,2’-dipyridylamide to sodium-ferrate complexes. Dalton Transactions. ISSN 1477-9226

2016

Vidal, Cristian and García-Álvarez, Joaquín and Hernán-Gómez, Alberto and Kennedy, Alan R. and Hevia, Eva (2016) Exploiting deep eutectic solvents and organolithium reagent partnerships : chemoselective ultrafast addition to imines and quinolines under aerobic ambient temperature conditions. Angewandte Chemie International Edition, 55 (52). pp. 16145-16148. ISSN 1521-3773

De Tullio, Marco and Hernán-Gómez, Alberto and Livingstone, Zoe and Clegg, William and Kennedy, Alan R. and Harrington, Ross W. and Antiñolo, Antonio and Martínez, Antonio and Carrillo-Hermosilla, Fernando and Hevia, Eva (2016) Structural and mechanistic insights into s-block bimetallic catalysis : sodium magnesiate-catalyzed guanylation of amines. Chemistry - A European Journal, 22 (49). pp. 17646-17656. ISSN 1521-3765

Uzelac, Marina and Kennedy, Alan R. and Hernán-Gómez, Alberto and Fuentes, M. Ángeles and Hevia, Eva (2016) Heavier alkali-metal gallates as platforms for accessing functionalized abnormal NHC carbene-gallium complexes. Zeitschrift fur Anorganische und Allgemeine Chemie, 642 (22). pp. 1241-1244. ISSN 1521-3749

Uzelac, Marina and Armstrong, David R. and Kennedy, Alan R. and Hevia, Eva (2016) Understanding the subtleties of frustrated Lewis pair activation of carbonyl compounds by N-Heterocyclic carbene/alkyl gallium pairings. Chemistry - A European Journal, 22 (44). pp. 15826-15833. ISSN 1521-3765

Roberts, Andrew J. and Kennedy, Alan R. and McLellan, Ross and Robertson, Stuart D. and Hevia, Eva (2016) Synthesis, structure and solution studies on mixed aryl/alkyl lithium zincates. European Journal of Inorganic Chemistry. pp. 4752-4760. ISSN 1434-1948

Uzelac, Marina and Kennedy, Alan R. and Hevia, Eva and Mulvey, Robert E. (2016) Transforming LiTMP lithiation of challenging diazines via gallium alkyl trans-metal-trapping. Angewandte Chemie International Edition, 55. pp. 13147-13150. ISSN 1521-3773

Livingstone, Zoe and Hernán-Gómez, Alberto and Baillie, Sharon E. and Armstrong, David R. and Carrella, Luca M. and Clegg, William and Harrington, Ross W. and Kennedy, Alan R. and Rentschler, Eva and Hevia, Eva (2016) Assessing the reactivity of sodium alkyl-magnesiates towards quinoxaline : single electron transfer (SET) vs. nucleophilic alkylation processes. Dalton Transactions, 45 (14). pp. 6175-6182. ISSN 1477-9226

Uzelac, Marina and Borilovic, Ivana and Amores, Marco and Cadenbach, Thomas and Kennedy, Alan R. and Aromí, Guillem and Hevia, Eva (2016) Structural and magnetic diversity in alkali-metal Manganate chemistry : evaluating donor and alkali-metal effects in co-complexation processes. Chemistry - A European Journal, 22 (14). pp. 4843-4854. ISSN 1521-3765

2015

Martínez-Martínez, Antonio J. and Fuentes, M. Ángeles and Hernán-Gõmez, Alberto and Hevia, Eva and Kennedy, Alan R. and Mulvey, Robert E. and O'Hara, Charles T. (2015) Alkali-metal-mediated magnesiations of an N-heterocyclic carbene : normal, abnormal and "paranormal" reactivity in a single tritopic molecule. Angewandte Chemie International Edition, 54 (47). pp. 14075-14079. ISSN 1521-3773

García-Álvarez, Joaquin and Hevia, Eva and Capriati, Vito (2015) Reactivity of polar organometallic compounds in unconventional reaction media : challenges and opportunities. European Journal of Organic Chemistry, 2015 (31). 6779–6799. ISSN 1434-193X

Uzelac, Marina and Hernán-Gómez, Alberto and Armstrong, David R. and Kennedy, Alan R. and Hevia, Eva (2015) Rational synthesis of normal, abnormal and anionic NHC-gallium alkyl complexes : structural, stability and isomerization insights. Chemical Science, 6 (10). pp. 5719-5728. ISSN 2041-6539

Maddock, Lewis C H and Cadenbach, Thomas and Kennedy, Alan R. and Borilovic, Ivana and Aromí, Guillem and Hevia, Eva (2015) Accessing Sodium Ferrate complexes containing neutral and anionic N-heterocyclic carbene ligands : structural, synthetic, and magnetic insights. Inorganic Chemistry, 54 (18). pp. 9201-9210. ISSN 1520-510X

Hernán-Gómez, Alberto and Herd, Emma and Uzelac, Marina and Cadenbach, Thomas and Kennedy, Alan R. and Borilovic, Ivana and Aromí, Guillem and Hevia, Eva (2015) Zincate-mediated arylation reactions of acridine : pre- and postarylation structural insights. Organometallics, 34 (11). pp. 2614-2623. ISSN 0276-7333

Roberts, Andrew J. and Clegg, William and Kennedy, Alan R. and Probert, Michael R. and Robertson, Stuart D. and Hevia, Eva (2015) Two alternative approaches to access mixed hydride-amido zinc complexes : synthetic, structural and solution implications. Dalton Transactions, 44 (17). pp. 8169-8177. ISSN 1477-9226

Clegg, William and Crosbie, Elaine and Dale-Black, Sophie H. and Hevia, Eva and Honeyman, Gordon W. and Kennedy, Alan R. and Mulvey, Robert E. and Ramsay, Donna L. and Robertson, Stuart D. (2015) Structurally defined zincated and aluminated complexes of ferrocene made by alkali-metal-synergistic syntheses. Organometallics, 34 (11). pp. 2580-2589. ISSN 0276-7333

2014

Armstrong, David R. and Emerson, Helena S. and Hernán-Gómez, Alberto and Kennedy, Alan R. and Hevia, Eva (2014) New supramolecular assemblies in heterobimetallic chemistry : synthesis of a homologous series of unsolvated alkali-metal zincates. Dalton Transactions, 43 (38). pp. 14229-14238. ISSN 1477-9226

Baillie, Sharon E. and Bluemke, Tobias D. and Clegg, William and Kennedy, Alan R. and Klett, Jan and Russo, Luca and De Tullio, Marco and Hevia, Eva (2014) Potassium-alkyl magnesiates : synthesis, structures and Mg-H exchange applications of aromatic and heterocyclic substrates. Chemical Communications, 50. pp. 12859-12862. ISSN 1359-7345

Bluemke, Tobias D. and Clegg, William and García-Alvarez, Pablo and Kennedy, Alan R. and Koszinowski, Konrad and McCall, Matthew D. and Russo, Luca and Hevia, Eva (2014) Structural and reactivity insights in Mg–Zn hybrid chemistry : Zn–I exchange and Pd-catalysed cross-coupling applications of aromatic substrates. Chemical Science, 5 (9). pp. 3552-3562. ISSN 2041-6539

Armstrong, David R. and Crosbie, Elaine and Hevia, Eva and Mulvey, Robert E. and Ramsay, Donna L. and Robertson, Stuart D. (2014) TMP (2,2,6,6-tetramethylpiperidide)-aluminate bases : lithium-mediated alumination or lithiation-alkylaluminium-trapping reagents? Chemical Science, 5 (8). pp. 3031-3045. ISSN 2041-6539

Vidal, Cristian and Garcia Alvarez, Joaquin and Hernán-Gómez, Alberto and Kennedy, Alan R and Hevia, Eva (2014) Introducing deep eutectic solvents to polar organometallic chemistry : chemoselective addition of organolithium and grignard reagents to ketones in air. Angewandte Chemie International Edition, 53 (23). 5969–5973. ISSN 1521-3773

Armstrong, D.R. and Clegg, W. and Hernan-Gomez, Alberto and Kennedy, A.R. and Livingstone, Z. and Robertson, S.D. and Russo, L. and Hevia, E. (2014) Probing the metallating ability of a polybasic sodium alkylmagnesiate supported by a bulky bis(amido) ligand : deprotomagnesiation reactions of nitrogen-based aromatic substrates. Dalton Transactions, 43 (11). pp. 4361-4369. ISSN 1477-9226

Hernán-Gómez, Alberto and Herd, Emma and Hevia, Eva and Kennedy, Alan R. and Knochel, Paul and Koszinowski, Konrad and Manolikakes, Sophia M. and Mulvey, Robert E. and Schnegelsberg, Christoph (2014) Organozinc pivalate reagents : segregation, solubility, stabilisation and structural insights. Angewandte Chemie International Edition, 53 (10). 2706–2710. ISSN 1521-3773

2013

Garden, Jennifer and Armstrong, David and Clegg, William and Garcia Alvarez, Joaquin and Hevia, Eva and Kennedy, Alan and Mulvey, Robert and Robertson, Stuart and Russo, Luca (2013) Donor-activated lithiation and sodiation of trifluoromethylbenzene : structural, spectroscopic and theoretical insights. Organometallics, 32 (19). pp. 5481-5490. ISSN 0276-7333

Hevia, Eva and Kennedy, Alan R. and Mulvey, Robert E. and Ramsay, Donna L. and Robertson, Stuart D. (2013) Concealed cyclotrimeric polymorph of lithium 2, 2, 6, 6- tetramethylpiperidide unconcealed : X-ray crystallographic and NMR spectroscopic studies. Chemistry - A European Journal, 19 (42). pp. 14069-14075. ISSN 1521-3765

Hernan-Gomez, Alberto and Bradley, T.D. and Kennedy, A.R. and Livingstone, Z. and Robertson, S.D. and Hevia, E. (2013) Developing catalytic applications of cooperative bimetallics : competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates. Chemical Communications, 49 (77). pp. 8659-8661. ISSN 1359-7345

Armstrong, David R. and Brammer, Elanor and Cadenbach, Thomas and Hevia, Eva and Kennedy, Alan R. (2013) Co-complexation syntheses, structural characterization, and DFT studies of a novel series of polymeric alkali-metal tetraorganogallates. Organometallics, 32 (2). pp. 480-489. ISSN 0276-7333

Armstrong, David and Baillie, Sharon and Blair, Victoria and Chabloz, Nicholas and Diez, Josefina and Garcia Alvarez, Joaquin and Kennedy, Alan and Robertson, Stuart and Hevia, Eva (2013) Alkali-metal-mediated zincation (AMMZn) meets N-heterocyclic carbene (NHC) chemistry : Zn–H exchange reactions and structural authentication of a dinuclear Au(I) complex with a NHC anion. Chemical Science, 4 (11). pp. 4259-4266. ISSN 2041-6539

Baillie, Sharon E. and Blair, Victoria L. and Bradley, Tyne D. and Clegg, William and Cowan, Jemma and Harrington, Ross W. and Hernan-Gomez, Alberto and Kennedy, Alan R. and Livingstone, Zoe and Hevia, Eva (2013) Isomeric and chemical consequences of the direct magnesiation of 1,3-benzoazoles using β-diketiminate-stabilized magnesium bases. Chemical Science, 4 (4). pp. 1895-1905. ISSN 2041-6539

2012

Baillie, Sharon E. and Clegg, William and Garcia-Alvarez, Pablo and Hevia, Eva and Klett, Jan and Russo, Luca and Kennedy, Alan (2012) Synthesis, structural elucidation, and diffusion-ordered NMR studies of homoleptic alkyllithium magnesiates: donor-controlled structural variations in mixed-metal chemistry. Organometallics, 31 (14). pp. 5131-5142. ISSN 0276-7333

Cadenbach, Thomas and Hevia, Eva and Kennedy, Alan and Mulvey, Robert E. and Pickrell, Janie-Anne and Robertson, Stuart D. (2012) Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire. Dalton Transactions, 41 (34). pp. 10141-10144. ISSN 1477-9226

Hevia, Eva and Kennedy, Alan and Mccall, Matthew David (2012) Assessing the reactivity of sodium zincate [(TMEDA)Na(TMP)ZntBu2] towards benzoylferrocene : deprotonative metalation vs. alkylation reactions. Dalton Transactions, 41 (1). pp. 98-103. ISSN 1472-7773

Baillie, Sharon E. and Blair, Victoria L. and Blakemore, David C. and Hay, Duncan and Kennedy, Alan and Pryde, David C. and Hevia, Eva (2012) New lithium-zincate approaches for the selective functionalisation of pyrazine: direct dideprotozincation vs. nucleophilic alkylation. Chemical Communications, 48 (14). pp. 1985-1987. ISSN 1359-7345

2011

Hevia, Eva (2011) Nuevas estrategias sinérgicas en química organometálica de Zinc : diseño racional de reactivos bimetálicos y sus aplicaciones en síntesis. Anales de Quimica, 104 (4). pp. 335-342. ISSN 1130-2283

Blair, Victoria L. and Clegg, William and Kennedy, Alan R. and Livingstone, Zoe and Russo, Luca and Hevia, Eva (2011) Magnesium-mediated benzothiazole activation : a room temperature cascade of C-H deprotonation, C-C coupling, ring-opening and nucleophilic addition reactions. Angewandte Chemie, 50 (42). pp. 9857-9860. ISSN 1521-3773

Hevia, Eva and Mulvey, Robert (2011) A record-breaking magnesium hydride molecular cluster : implications for hydrogen storage. Angewandte Chemie, 50 (40). pp. 9242-9243. ISSN 1521-3773

Blair, Victoria L. and Blakemore, David C. and Hay, Duncan and Hevia, Eva and Pryde, David C. (2011) Alkali-metal mediated zincation of N-heterocyclic substrates using the lithium zincate complex, (THF)Li(TMP)Zn(tBu)(2) and applications in in situ cross coupling reactions. Tetrahedron Letters, 52 (36). pp. 4590-4594. ISSN 0040-4039

Armstrong, David R. and Balloch, Liam and Hevia, Eva and Kennedy, Alan R. and Mulvey, Robert E. and O'Hara, Charles T. and Robertson, Stuart D. (2011) Meta-metallation of N,N-dimethylaniline: contrasting direct sodium-mediated zincation with indirect sodiation-dialkylzinc co-complexation. Beilstein Journal of Organic Chemistry, 7. pp. 1234-1248.

Armstrong, David R. and Clegg, William and Garcia-Alvarez, Pablo and Kennedy, Alan R. and McCall, Matthew D. and Russo, Luca and Hevia, Eva (2011) Expanding Mg-Zn hybrid chemistry : inorganic salt effects in addition reactions of organozinc reagents to trifluoroacetophenone and the implications for a synergistic lithium-magnesium-zinc activation. Chemistry - A European Journal, 17 (30). pp. 8333-8341. ISSN 1521-3765

Hevia, Eva and Mulvey, Robert E. (2011) Split personality of lithium chloride : recent salt effects in organometallic recipes. Angewandte Chemie, 50 (29). pp. 6448-6450. ISSN 1521-3773

Baillie, Sharon E. and Blair, Victoria L. and Hevia, Eva and Kennedy, Alan R. (2011) A new polymeric alkyl/alkoxide magnesium-sodium inverse crown complex. Acta Crystallographica Section C: Crystal Structure Communications, 67 (7). M249-M251. ISSN 0108-2701

Armstrong, David R. and Clegg, William and Garcia-Alvarez, Pablo and McCall, Matthew D. and Nuttall, Lorraine and Kennedy, Alan R. and Russo, Luca and Hevia, Eva (2011) Shedding new light on ZnCl2-mediated addition reactions of Grignard reagents to ketones : structural authentication of key intermediates and diffusion-ordered NMR studies. Chemistry - A European Journal, 17 (16). pp. 4470-4479. ISSN 1521-3765

Baillie, Sharon E. and Clegg, William and Garcia-Alvarez, Pablo and Hevia, Eva and Kennedy, Alan R. and Klett, Jan and Russo, Luca (2011) Synthesis and characterization of an infinite sheet of metal-alkyl bonds : unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate. Chemical Communications (London), 47 (1). pp. 388-390. ISSN 0009-241X

2010

Armstrong, David R. and Blair, Victoria L. and Clegg, William and Dale, Sophie H. and Garcia-Alvarez, Joaquin and Honeyman, Gordon W. and Hevia, Eva and Mulvey, Robert E. and Russo, Luca (2010) Structural basis for regioisomerization in the alkali-metal-mediated zincation (AMMZn) of trifluoromethyl benzene by isolation of kinetic and thermodynamic intermediates. Journal of the American Chemical Society, 132 (27). pp. 9480-9487. ISSN 1520-5126

Hevia, Eva and Chua, Jonathan Z. and Garcia-Alvarez, Pablo and Kennedy, Alan R. and McCall, Matthew D. (2010) Exposing the hidden complexity of stoichiometric and catalytic metathesis reactions by elucidation of Mg-Zn hybrids. Proceedings of the National Academy of Sciences, 107 (12). pp. 5294-5299. ISSN 0027-8424

Hevia, Eva and Kennedy, Alan R. and Klett, Jan and Livingstone, Zoe and McCall, Matthew D. (2010) New insights into addition reactions of dialkylzinc reagents to trifluoromethyl ketones : structural authentication of a beta-hydride elimination product containing a tetranuclear zinc chain. Dalton Transactions, 39 (2). pp. 520-526. ISSN 1472-7773

2009

Conway, Ben and Garcia-Alvarez, Joaquin and Hevia, Eva and Kennedy, Alan R. and Mulvey, Robert E. and Robertson, Stuart D. (2009) Contacted ion-pair lithium alkylamidoaluminates: intramolecular alumination (al-h exchange) traps for tmeda and pmdeta. Organometallics, 28 (22). pp. 6462-6468. ISSN 0276-7333

Armstrong, D.R. and Balloch, L. and Clegg, William and Dale, S.H. and Garcia-Alvarez, P. and Hevia, E. and Hogg, L.M. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, Charles (2009) Synergic synthesis of benzannulated zincabicyclic complexes, alpha-zincated n ylides, through sodium-TMEDA-mediated zincation of a haloarene. Angewandte Chemie, 48 (46). pp. 8675-8678. ISSN 1521-3773

Clegg, W. and Conway, B. and Graham, D.V. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. and Russo, L. and Wright, D.S. (2009) Structurally defined potassium-mediated zincation of pyridine and 4-R-substituted pyridines (R = Et, iPr, tBu, Ph, and Me2N) by using dialkyl-tmp-zincate bases. Chemistry - A European Journal, 15 (29). pp. 7074-7082. ISSN 1521-3765

Clegg, W. and Graham, D.V. and Herd, E. and Hevia, E. and Kennedy, A.R. and McCall, M.D. and Russo, L. (2009) Donor-dictated interlocking co-complexation reactions of LiNHDipp with dimethylzinc: synthesis and structures of new methyl(amido)zincates. Inorganic Chemistry, 48 (12). pp. 5320-5327. ISSN 1520-510X

Clegg, W. and Conway, B. and Hevia, E. and McCall, M.D. and Russo, L. and Mulvey, R.E. (2009) Closer insight into the reactivity of TMP-dialkyl zincates in directed ortho-zincation of anisole : experimental evidence of amido basicity and structural elucidation of key reaction intermediates. Journal of the American Chemical Society, 131 (6). pp. 2375-2384. ISSN 1520-5126

Hevia, E. and Kennedy, A.R. and Klett, J. and McCall, M.D. (2009) Direct lateral metallation using alkali-metal mediated zincation (AMMZn): SiC-H vs. Si-O bond cleavage. Chemical Communications (London) (22). pp. 3240-3242. ISSN 0009-241X

Armstrong, D.R. and Garcia-Alvarez, J. and Graham, D.V. and Honeyman, G.W. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. (2009) Synthetic and structural insights into the zincation of toluene: direct synergic ring metallation versus indirect nonsynergic lateral metallation. Chemistry - A European Journal, 15 (15). pp. 3800-3807. ISSN 1521-3765

2008

Armstrong, D.R. and Dougan, C. and Graham, D.V. and Hevia, E. and Kennedy, A.R. (2008) Synthesis and structural elucidation of alkyl, amido, and mixed. alkyl-amido "highly-coordinated" zincates. Organometallics, 27 (23). pp. 6063-6070. ISSN 0276-7333

Armstrong, D.R. and Drummond, A.M. and Balloch, L. and Graham, D.V. and Hevia, E. and Kennedy, A.R. (2008) Metalation of 2,4,6-trimethylacetophenone using organozinc reagents: the role of the base in determining composition and structure of the developing enolate. Organometallics, 27 (22). pp. 5860-5866. ISSN 0276-7333

Garcia-Alvarez, P. and Graham, D.V. and Hevia, E. and Kennedy, A.R. and Klett, J. and Mulvey, R.E. and O'Hara, C.T. and Weatherstone, Susan (2008) Unmasking representative structures of tmp-active hauser and turbo-hauser bases. Angewandte Chemie, 47 (42). pp. 8079-8081. ISSN 1521-3773

Clegg, W. and Garcia-Alvarez, J. and Garcia-Alvarez, P. and Graham, D.V. and Harrington, R.W. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. (2008) Synthesis, structural authentication, and structurally defined metalation reactions of lithium and sodium da-zincate bases (da = diisopropylamide) with phenylacetylene. Organometallics, 27 (11). pp. 2654-2663. ISSN 0276-7333

Blair, V.L. and Clegg, W. and Conway, B. and Hevia, E. and Kennedy, A. and Klett, J. and Mulvey, R.E. and Russo, L. (2008) Alkali-metal-mediated manganation(ii) of functionalized arenes and applications of ortho-manganated products in pd-catalyzed cross-coupling reactions with iodobenzene. Chemistry - A European Journal, 14 (1). pp. 65-72. ISSN 1521-3765

Clegg, W. and Dale, S.H. and Hevia, E. and Hogg, L.M. and Honeyman, G.W. and Mulvey, R.E. and O'Hara, C.T. and Russo, L. (2008) Structurally defined reactions of sodium tmp-zincate with nitrile compounds: synthesis of a salt-like sodium sodiumdizincate and other unexpected ion-pair products. Angewandte Chemie, 47 (4). pp. 731-734. ISSN 1521-3773

Conway, B. and Graham, D.V. and Hevia, E. and Kennedy, A.R. and Klett, J. and Mulvey, R.E. (2008) Structurally-defined potassium-mediated regioselective zincation of amino-and alkoxy-substituted pyridines. Chemical Communications (London) (23). pp. 2638-2640. ISSN 0009-241X

Garcia-Alvarez, J. and Graham, D.V. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. (2008) Synthesis and characterisation of new bimetallic alkali metal-magnesium mixed diisopropylamide-acetylides: structural variations in bimetallic lithium- and sodium-heteroleptic magnesiates. Dalton Transactions (11). pp. 1481-1486. ISSN 1472-7773

Armstrong, D.R. and Clegg, W. and Dale, S.H. and Garcia-Alvarez, Joaquin and Harrington, R.W. and Hevia, E. and Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. (2008) Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate. Chemical Communications (London) (2). pp. 187-189. ISSN 0009-241X

2007

Clegg, W. and Dale, S.H. and Graham, D.V. and Harrington, R.W. and Hevia, E. and Hogg, L.M. and Kennedy, A.R. and Mulvey, R.E. (2007) Structural variations in bimetallic sodium-magnesium and sodium-zinc ketimides, and a sodium-zinc alkide-alkoxide-amide: connections to ring-stacking, ring-laddering, and inverse crown concepts. Chemical Communications (London) (16). pp. 1641-1643. ISSN 0009-241X

Mulvey, R.E. and Kennedy, A.R. and Klett, J. and Hevia, E. and Garcia Alvarez, Joaquin (2007) Lewis base stabilized lithium TMP-aluminates: an unexpected fragmentation and capture reaction involving cyclic ether 1,4-dioxane. Chemical Communications (London) (23). pp. 2402-2404. ISSN 0009-241X

Armstrong, D.R. and Clegg, William and Dale, S.H. and Graham, D.V. and Hevia, E. and Hogg, L.M. and Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. (2007) Dizincation and dimagnesiation of benzene using alkali-metal-mediated metallation. Chemical Communications (London) (6). pp. 598-600. ISSN 0009-241X

Conway, B. and Hevia, E. and Garcia-Alvarez, J. and Graham, D.V. and Kennedy, A.R. and Mulvey, R.E. (2007) Isolation and structural elucidation of a key aluminoaromatic intermediate and evidence for dismutation phenomena in tmp-alumination chemistry. Chemical Communications (London) (48). pp. 5241-5243. ISSN 0009-241X

Mulvey, R.E. and Kennedy, A.R. and Hevia, E. (2007) Structurally-defined direct C-magnesiation and C-zincation of N-heterocyclic aromatic compounds using alkali-metal-mediated metallation. Chemical Communications (London) (27). pp. 2864-2866. ISSN 0009-241X

2006

Baillie, S.H. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. (2006) Synthesis of mixed alkali-metal-zinc enolate complexes derived from 2,4,6-trimethylacetophenone: new inverse crown structures. Organometallics, 26 (1). pp. 204-209. ISSN 0276-7333

Gabrielsson, Anders and Busby, Michael and Matousek, Pavel and Towrie, Michael and Hevia, Eva and Cuesta, Luciano and Perez, Julio and Zalis, Stanislav and Vlcek, Antonin (2006) Electronic structure and excited states of rhenium(I) amido and phosphido carbonyl-bipyridine complexes studied by picosecond time-resolved IR spectroscopy and DFT calculations. Inorganic Chemistry, 45 (24). pp. 9789-9797. ISSN 1520-510X

Hevia, Eva and Miguel, Daniel and Perez, Julio and Riera, Victor (2006) Synthesis and reactivity of new (methoxy)methyl complexes of manganese(I) and rhenium(I). Organometallics, 25 (20). pp. 4909-4912. ISSN 0276-7333

Graham, D.V. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. (2006) Lithium dimethyl(amido)zinc complexes: contrasting zincate (amido = tmp) and inverse zincate (amido = hmds) structures on addition of TMEDA. Organometallics, 25 (14). pp. 3297-3300. ISSN 0276-7333

Clegg, W and Dale, S H and Drummond, A M and Hevia, E and Honeyman, G W and Mulvey, R E (2006) Alkali-metal-mediated zincation of anisole: synthesis and structures of three instructive ortho-zincated complexes. Journal of the American Chemical Society, 128 (23). pp. 7434-7435. ISSN 1520-5126

Cuesta, L and Hevia, E and Morales, D and Perez, J and Riera, L and Miguel, D (2006) Reactivity of molybdenum and rhenium hydroxo complexes toward organic electrophiles: reactions that afford carboxylato products. Organometallics, 25 (7). pp. 1717-1722. ISSN 0276-7333

Hevia, E. and Henderson, K.W. and Kennedy, A.R. and Mulvey, R.E. (2006) Synthesis and characterization of new mixed-metal sodium-magnesium enolates derived from 2,4,6-trimethylacetophenone. Organometallics, 25 (7). pp. 1778-1785. ISSN 0276-7333

Graham, D.V. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Talmard, C. (2006) Building an extended inverse crown motif via alkali-metal-mediated alpha-magnesiation of furan. Chemical Communications (London), 2006 (4). pp. 417-419. ISSN 0009-241X

Mulvey, R.E. and Clegg, W. and Hevia, E. and O'Hara, C.T. and Dale, S.H. and Hogg, L.M. and Honeyman, G.W. (2006) Alkali-metal-mediated zincation of polycyclic aromatic hydrocarbons : synthesis and structures of mono- and dizincated naphthalenes. Angewandte Chemie, 45. pp. 6548-6550. ISSN 1521-3773

Mulvey, R.E. and Armstrong, David R. and Clegg, W. and Hevia, E. and Dale, S.H. and Hogg, L.M. and Honeyman, G.W. (2006) Directed meta-metalation using alkali-metal-mediated zincation. Angewandte Chemie, 45. pp. 3775-3778. ISSN 1521-3773

Clegg, W and Dale, S H and Harrington, R W and Hevia, E and Honeyman, G W and Mulvey, R E (2006) Post-metalation structural insights into the use of alkali-metal-mediated zincation for directed ortho-metalation of a tertiary aromatic amide. Angewandte Chemie, 45 (15). pp. 2374-2377. ISSN 1521-3773

Clegg, W and Dale, S H and Hevia, E and Honeyman, G W and Mulvey, R E (2006) Pre-metalation structural insights into the use of alkali-metal-mediated zincation for directed ortho-metalation of a tertiary aromatic amide. Angewandte Chemie, 45 (15). pp. 2370-2374. ISSN 1521-3773

Hevia, E. and Armstrong, David R. and Kennedy, A. and Mulvey, R.E. (2006) Synergic para-directed-monometalation ofcby using alkali-metal-mediated magnesiation. Organometallics, 25. pp. 2415-2418. ISSN 0276-7333

2005

Hevia, E. and Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. (2005) Trapping, stabilization, and characterization of an enolate anion of a 1,6-adduct of benzophenone chelated by a sodium alkylamidozincate cation. Journal of the American Chemical Society, 127 (38). pp. 13106-13107. ISSN 1520-5126

Andrikopoulos, Prokopis C. and Armstrong, David R. and Graham, David V. and Hevia, Eva and Kennedy, Alan R. and Mulvey, Robert E. and O'Hara, Charles T. and Talmard, Christine (2005) Selective meta-deprotonation of toluene by using alkali-metal-mediated magnesiation. Angewandte Chemie, 44 (22). pp. 3459-3462. ISSN 1521-3773

Andrikopoulos, P.C. and Armstrong, D.R. and Barley, H.R.L. and Clegg, W. and Dale, S.H. and Hevia, E. and Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. (2005) Sodium dialkyl-amidozincates: Alkyl or amido bases? An experimental and theoretical case study. Journal of the American Chemical Society, 127 (17). pp. 6184-6185. ISSN 1520-5126

Cuesta, L and Hevia, E and Morales, D and Perez, J and Riera, V and Seitz, M and Miguel, D (2005) Activation of ancillary ligands in the reactions of DMAD with phosphido and alkylideneamido rhenium complexes. Organometallics, 24 (7). pp. 1772-1775. ISSN 0276-7333

Andrikopoulos, Prokopis C. and Armstrong, David R. and Hevia, Eva and Kennedy, Alan R. and Mulvey, Robert E. and O'Hara, Charles T. (2005) Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions. Chemical Communications (London), 2005 (9). pp. 1131-1133. ISSN 0009-241X

Cuesta, L and Hevia, E and Morales, D and Perez, J and Riera, V and Rodriguez, E and Miguel, D (2005) Activation of a 1,10-phenanthroline ligand on a rhenium tricarbonyl complex. Chemical Communications (1). pp. 116-117. ISSN 1359-7345

Barley, H.R.L. and Clegg, W. and Dale, S.H. and Hevia, E. and Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. (2005) Alkali-metal-mediated zineation of ferrocene: Synthesis, structure, and reactivity of a lithium tmp/zincate reagent. Angewandte Chemie, 44 (37). pp. 6018-6021. ISSN 1521-3773

Hevia, E. and Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. and Sherrington, D.C. (2005) Synergic monodeprotonation of bis(benzene)chromium by using mixed alkali metal-magnesium amide bases and structural characterization of the heterotrimetallic products. Angewandte Chemie, 44 (1). pp. 68-72. ISSN 1521-3773

Conway, B. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. and Weatherstone, S. (2005) Synthesis and characterisation of a series of alkylmagnesium amide and related oxygen-contaminated 'alkoxy' compounds. Dalton Transactions, 2005 (8). pp. 1532-1544. ISSN 1472-7773

2004

Hevia, E. and Gallagher, D.J. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Talmard, C. (2004) Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns. Chemical Communications (London), 2004 (21). pp. 2422-2423. ISSN 0009-241X

Andrikopoulos, Prokopis C. and Armstrong, David R. and Clegg, William and Gilfillan, Carly J. and Hevia, Eva and Kennedy, Alan R. and Mulvey, Robert E. and O'Hara, Charles T. and Parkinson, John A. and Tooke, Duncan M. (2004) A homologous series of regioselectively tetradeprotonated group 8 metallocenes: New inverse crown ring compounds synthesized via a mixed sodium-magnesium tris(diisopropylamide) synergic base. Journal of the American Chemical Society, 126 (37). pp. 11612-11620. ISSN 1520-5126

Cuesta, L and Gerbino, D C and Hevia, E and Morales, D and Clemente, M E N and Perez, J and Riera, L and Riera, V and Miguel, D and del Rio, I and Garcia-Granda, S (2004) Reactivity of molybdenum and rhenium hydroxo-carbonyl complexes toward organic electrophiles. Chemistry - A European Journal, 10 (7). pp. 1765-1777. ISSN 1521-3765

Hevia, E. and Kennedy, A.R. and Mulvey, R.E. and Weatherstone, S. (2004) Synthesis and crystal structure of [{nBuMg(mu-TMP)}(2)] and of a homometallic inverse crown in tetranuclear [{nBuMg(2)[mu-N(H)Dipp](2)(mu(3)-OnBu)}(2)]. Angewandte Chemie, 43 (13). pp. 1709-1712. ISSN 1521-3773

2003

Hevia, E. and Kenley, F.R. and Kennedy, A.R. and Mulvey, R.E. and Rowlings, R.B. (2003) Solvent-free and TMEDA-solvated mixed alkali metal-magnesium tris-diisopropylamides. European Journal of Inorganic Chemistry, 2003 (18). pp. 3347-3353. ISSN 1434-1948

Hevia, E and Perez, J and Riera, V and Miguel, D and Campomanes, P and Menendez, M I and Sordo, T L and Garcia-Granda, S (2003) Synthesis of beta-lactams from a N-rhenaimine: effect of the transition metal on the energetic profile of the Staudinger reaction. Journal of the American Chemical Society, 125 (13). pp. 3706-3707. ISSN 1520-5126

Perez, J and Hevia, E and Riera, L and Riera, V and Garcia-Granda, S and Garcia-Rodriguez, E and Miguel, D (2003) Mono- and dimetallic cyano complexes with {Mo(eta(3)-allyl)(CO)(2)(N-N)} fragments. European Journal of Inorganic Chemistry (6). pp. 1113-1120. ISSN 1434-1948

Hevia, E and Perez, J and Riera, V (2003) Reactivity of the amido complex [Re(NHpTol)(CO)(3)(bipy)] toward neutral organic electrophiles. Organometallics, 22 (2). pp. 257-263. ISSN 0276-7333

Gerbino, D C and Hevia, E and Morales, D and Clemente, M E N and Perez, J and Riera, L and Riera, V and Miguel, D (2003) A new reactivity pattern of low-valent transition-metal hydroxo complexes: straightforward synthesis of hydrosulfido complexes via reaction with carbon disulfide. Chemical Communications (3). pp. 328-329. ISSN 1359-7345

2002

Hevia, E and Perez, J and Riera, V (2002) Manganese(I) and rhenium(I) tricarbonyl (Alkylthio)methyl and alkylidenesulfonium complexes. Organometallics, 21 (24). pp. 5312-5319. ISSN 0276-7333

Hevia, E and Perez, J and Riera, L and Riera, V and del Rio, I and Garcia-Granda, S and Miguel, D (2002) Insertion of unsaturated organic electrophiles into molybdenum-alkoxide and rhenium-alkoxide bonds of neutral, stable carbonyl complexes. Chemistry - A European Journal, 8 (19). pp. 4510-4521. ISSN 1521-3765

Hevia, E and Perez, J and Riera, V and Miguel, D and Kassel, S and Rheingold, A (2002) New synthetic routes to cationic rhenium tricarbonyl bipyridine complexes with labile ligands. Inorganic Chemistry, 41 (18). pp. 4673-4679. ISSN 1520-510X

Hevia, E and Perez, J and Riera, V and Miguel, D (2002) New octahedral rhenium(I) tricarbonyl amido complexes. Organometallics, 21 (9). pp. 1966-1974. ISSN 0276-7333

Hevia, E and Perez, J and Riera, L and Riera, V and Miguel, D (2002) Reactive alkoxide complexes of groups 6 and 7 metals. Organometallics, 21 (9). pp. 1750-1752. ISSN 0276-7333

Hevia, E and Perez, J and Riera, V and Miguel, D (2002) Different sites of insertion in the reaction of isocyanates with [Re(N(R)Ar)(CO)(3)(bipy)] (R=H or Me): N-H vs. Re-N. Chemical Communications (17). pp. 1814-1815. ISSN 1359-7345

Hevia, E and Perez, J and Riera, V and Miguel, D (2002) Insertion and cycloaddition reactivity of a transition-metal N-metalloimine. Angewandte Chemie, 41 (20). pp. 3858-3860. ISSN 1521-3773

2000

Burke, Lisa T. and Hevia-Freire, Eva and Holland, Rebecca and Jeffery, John C. and Leedham, Angela P. and Russell, Christopher A. and Steiner, Alexander and Zagorski, Anette (2000) Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions. Chemical Communications (London) (18). pp. 1769-1770. ISSN 0009-241X