Reactive alkoxide complexes of groups 6 and 7 metals
Hevia, E and Perez, J and Riera, L and Riera, V and Miguel, D (2002) Reactive alkoxide complexes of groups 6 and 7 metals. Organometallics, 21 (9). pp. 1750-1752. ISSN 0276-7333 (https://doi.org/10.1021/om010977s)
Full text not available in this repository.Request a copyAbstract
Easily available alkoxo complexes [M(OR)(CO)(3)(bipy)] (M = Mn, Re) and [Mo(OR)(eta(3)-C3H5)(CO)(2)(phen)] react with dimethylacetylenedicarboxylate (DALA-D) to afford the Z-alkenyls resulting from DMAD insertion into the M-OR bonds. Evidence suggesting a nondissociative mechanism is presented.
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Item type: Article ID code: 34755 Dates: DateEvent29 April 2002PublishedSubjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 21 Oct 2011 12:08 Last modified: 08 Apr 2024 19:33 URI: https://strathprints.strath.ac.uk/id/eprint/34755
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