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Reactive alkoxide complexes of groups 6 and 7 metals

Hevia, E and Perez, J and Riera, L and Riera, V and Miguel, D (2002) Reactive alkoxide complexes of groups 6 and 7 metals. Organometallics, 21 (9). pp. 1750-1752. ISSN 0276-7333

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Official URL: http://dx.doi.org/10.1021/om010977s

Abstract

Easily available alkoxo complexes [M(OR)(CO)(3)(bipy)] (M = Mn, Re) and [Mo(OR)(eta(3)-C3H5)(CO)(2)(phen)] react with dimethylacetylenedicarboxylate (DALA-D) to afford the Z-alkenyls resulting from DMAD insertion into the M-OR bonds. Evidence suggesting a nondissociative mechanism is presented.

Item type:	Article
ID code:	34755
Keywords:	x-ray structure, carbon dioxide , oxygen bonds, carbanions, Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry
Subjects:	Science > Chemistry
Department:	Faculty of Science > Pure and Applied Chemistry
Depositing user:	Pure Administrator
Date deposited:	21 Oct 2011 12:08
Last modified:	23 Jun 2017 03:57
URI:	https://strathprints.strath.ac.uk/id/eprint/34755
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