Reactive alkoxide complexes of groups 6 and 7 metals
Hevia, E and Perez, J and Riera, L and Riera, V and Miguel, D (2002) Reactive alkoxide complexes of groups 6 and 7 metals. Organometallics, 21 (9). pp. 1750-1752. ISSN 0276-7333
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Abstract
Easily available alkoxo complexes [M(OR)(CO)(3)(bipy)] (M = Mn, Re) and [Mo(OR)(eta(3)-C3H5)(CO)(2)(phen)] react with dimethylacetylenedicarboxylate (DALA-D) to afford the Z-alkenyls resulting from DMAD insertion into the M-OR bonds. Evidence suggesting a nondissociative mechanism is presented.
Creators(s): |
Hevia, E ![]() | Item type: | Article |
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ID code: | 34755 |
Keywords: | x-ray structure, carbon dioxide , oxygen bonds, carbanions, Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Pure Administrator |
Date deposited: | 21 Oct 2011 12:08 |
Last modified: | 20 Jan 2021 19:43 |
URI: | https://strathprints.strath.ac.uk/id/eprint/34755 |
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