Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate
Armstrong, D.R. and Clegg, W. and Dale, S.H. and Garcia-Alvarez, Joaquin and Harrington, R.W. and Hevia, E. and Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. (2008) Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate. Chemical Communications (London) (2). pp. 187-189. ISSN 0009-241X
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Abstract
In a new type of reactivity for sodium TMP-zincate [(TMEDA) NaZn(Bu-t)(2)(TMP)] (1), transamination reactions with the amines diisopropylamine, DA(H), hexamethyldisilazane, HMDS(H) and chiral (R)-N-benzyl-alpha-methylbenzylamine have produced new sodium amido-di-tert-butyl zincates (all structurally characterised) with concomitant loss of TMP(H).
Author(s): | Armstrong, D.R., Clegg, W., Dale, S.H., Garcia-Alvarez, Joaquin, Harrington, R.W., Hevia, E. ![]() ![]() ![]() ![]() | Item type: | Article |
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ID code: | 19846 |
Notes: | Strathprints' policy is to record up to 8 authors per publication, plus any additional authors based at the University of Strathclyde. More authors may be listed on the official publication than appear in the Strathprints' record. |
Keywords: | metal mediated zincation, directed ortho metalation, magnesium, amides, base, reactivity, complexes, alkoxides, alkyl, Chemistry, Chemistry(all) |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Strathprints Administrator |
Date deposited: | 03 Jun 2010 17:27 |
Last modified: | 12 Jul 2019 02:45 |
URI: | https://strathprints.strath.ac.uk/id/eprint/19846 |
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