Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate

Armstrong, D.R. and Clegg, W. and Dale, S.H. and Garcia-Alvarez, Joaquin and Harrington, R.W. and Hevia, E. and Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. (2008) Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate. Chemical Communications (London) (2). pp. 187-189. ISSN 0009-241X

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Official URL: http://dx.doi.org/10.1039/b713987j

Abstract

In a new type of reactivity for sodium TMP-zincate [(TMEDA) NaZn(Bu-t)(2)(TMP)] (1), transamination reactions with the amines diisopropylamine, DA(H), hexamethyldisilazane, HMDS(H) and chiral (R)-N-benzyl-alpha-methylbenzylamine have produced new sodium amido-di-tert-butyl zincates (all structurally characterised) with concomitant loss of TMP(H).

Creators(s):	Armstrong, D.R., Clegg, W., Dale, S.H., Garcia-Alvarez, Joaquin, Harrington, R.W., Hevia, E. ORCID: https://orcid.org/0000-0002-3998-7506, Honeyman, G.W., Kennedy, A.R. ORCID: https://orcid.org/0000-0003-3652-6015, Mulvey, R.E. ORCID: https://orcid.org/0000-0002-1015-2564 and O'Hara, C.T. ORCID: https://orcid.org/0000-0002-1691-1568;
Item type:	Article
ID code:	19846
Notes:	Strathprints' policy is to record up to 8 authors per publication, plus any additional authors based at the University of Strathclyde. More authors may be listed on the official publication than appear in the Strathprints' record.
Keywords:	metal mediated zincation, directed ortho metalation, magnesium, amides, base, reactivity, complexes, alkoxides, alkyl, Chemistry, Chemistry(all)
Subjects:	Science > Chemistry
Department:	Faculty of Science > Pure and Applied Chemistry
Depositing user:	Strathprints Administrator
Date deposited:	03 Jun 2010 17:27
Last modified:	03 Sep 2020 02:17
URI:	https://strathprints.strath.ac.uk/id/eprint/19846
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