Developing catalytic applications of cooperative bimetallics : competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates
Hernan-Gomez, Alberto and Bradley, T.D. and Kennedy, A.R. and Livingstone, Z. and Robertson, S.D. and Hevia, E. (2013) Developing catalytic applications of cooperative bimetallics : competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates. Chemical Communications, 49 (77). pp. 8659-8661. ISSN 1359-7345 (https://doi.org/10.1039/c3cc45167d)
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Mixed-metal reagents [NaMg(CHSiMe)] (1) and [(THF)NaMg(NPh)(THF)] [3-(THF)] can act as precatalysts to selectively promote the hydroamination/trimerization of isocyanates (RNCO) depending on the steric bulk of the R substituent.
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Item type: Article ID code: 46000 Dates: DateEvent7 October 2013PublishedSubjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 19 Nov 2013 16:53 Last modified: 28 Jul 2024 00:57 Related URLs: URI: https://strathprints.strath.ac.uk/id/eprint/46000
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