Developing catalytic applications of cooperative bimetallics : competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates

Hernan-Gomez, Alberto and Bradley, T.D. and Kennedy, A.R. and Livingstone, Z. and Robertson, S.D. and Hevia, E. (2013) Developing catalytic applications of cooperative bimetallics : competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates. Chemical Communications, 49 (77). pp. 8659-8661. ISSN 1359-7345 (https://doi.org/10.1039/c3cc45167d)

Abstract

Mixed-metal reagents [NaMg(CHSiMe)] (1) and [(THF)NaMg(NPh)(THF)] [3-(THF)] can act as precatalysts to selectively promote the hydroamination/trimerization of isocyanates (RNCO) depending on the steric bulk of the R substituent.

ORCID iDs

Hernan-Gomez, Alberto ORCID: https://orcid.org/0000-0001-8150-7249

Kennedy, A.R. ORCID: https://orcid.org/0000-0003-3652-6015

Robertson, S.D. ORCID: https://orcid.org/0000-0002-9330-8770

Hevia, E. ORCID: https://orcid.org/0000-0002-3998-7506

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  Item type:	Article
  ID code:	46000
  Dates:	Date Event 7 October 2013 Published
  Keywords:	mixed-metal reagents, bimetallics, isocyanates, Chemistry, Chemistry(all)
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	19 Nov 2013 16:53
  Last modified:	25 Nov 2022 01:36
  Related URLs:	Scopus publication
  URI:	https://strathprints.strath.ac.uk/id/eprint/46000