Alkali-metal-mediated zincation of polycyclic aromatic hydrocarbons : synthesis and structures of mono- and dizincated naphthalenes
Mulvey, R.E. and Clegg, W. and Hevia, E. and O'Hara, C.T. and Dale, S.H. and Hogg, L.M. and Honeyman, G.W. (2006) Alkali-metal-mediated zincation of polycyclic aromatic hydrocarbons : synthesis and structures of mono- and dizincated naphthalenes. Angewandte Chemie, 45. pp. 6548-6550.
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Since the pioneering work of Schlenk nearly a century ago, alkali-metal–organic compounds (organolithium reagents, in particular) have served as frontline reagents in the battle to advance chemical synthesis. Metal–hydrogen exchange (metalation) in which a relatively inert carbon–hydrogen bond is transformed into a more labile carbon–alkali-metal bond, thus opening up a myriad of bond-forming possibilities at the carbon center, represents one of the oldest and still most important general uses of these centurial reagents.[1, 2]
| Author(s): | Mulvey, R.E., Clegg, W., Hevia, E., O'Hara, C.T., Dale, S.H., Hogg, L.M. and Honeyman, G.W. | Item type: | Article |
|---|---|
| ID code: | 10260 |
| Keywords: | alkali metals, zinc, polycyclic aromatic hydrocarbons, metalation, crystal structures, Chemistry, Medicine(all) |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Depositing user: | Strathprints Administrator |
| Date deposited: | 19 Nov 2011 04:55 |
| Last modified: | 03 Jan 2019 11:58 |
| URI: | https://strathprints.strath.ac.uk/id/eprint/10260 |
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