Direct lateral metallation using alkali-metal mediated zincation (AMMZn): SiC-H vs. Si-O bond cleavage

Hevia, E. and Kennedy, A.R. and Klett, J. and McCall, M.D. (2009) Direct lateral metallation using alkali-metal mediated zincation (AMMZn): SiC-H vs. Si-O bond cleavage. Chemical Communications (London) (22). pp. 3240-3242. ISSN 0009-241X (http://dx.doi.org/10.1039/b903592c)

Abstract

A new application of zincate [(THF) Li(TMP)(Bu-t) Zn(Bu-t)] (1) in alkali-metal mediated zincation (AMMZn) is reported by isolating and structurally defining the first intermediates of direct lateral zincation (DIZn) of trimethyl(phenoxy) silane (2) both of which adopt novel six-element {ZnCSiOLiN} ring structures.

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• Item metadata

  Item type:	Article
  ID code:	19126
  Dates:	Date Event 2009 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Strathprints Administrator
  Date deposited:	19 May 2010 15:16
  Last modified:	08 Apr 2024 17:45
  URI:	https://strathprints.strath.ac.uk/id/eprint/19126