Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions

Burke, Lisa T. and Hevia-Freire, Eva and Holland, Rebecca and Jeffery, John C. and Leedham, Angela P. and Russell, Christopher A. and Steiner, Alexander and Zagorski, Anette (2000) Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions. Chemical Communications (London) (18). pp. 1769-1770. ISSN 0009-241X (https://doi.org/10.1039/B004192K)

Abstract

The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with BunLi (2 equivalents) yields a complex [Li2P(H)(NR)3]2 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3]2−.

ORCID iDs

Hevia-Freire, Eva ORCID: https://orcid.org/0000-0002-3998-7506

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  Item type:	Article
  ID code:	34775
  Dates:	Date Event 2000 Published
  Keywords:	phosphonate anion , phosphorous oxoanions , 2-methoxyaniline , Chemistry, Chemistry(all)
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	21 Oct 2011 12:27
  Last modified:	20 May 2023 03:55
  URI:	https://strathprints.strath.ac.uk/id/eprint/34775