Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions

Burke, Lisa T. and Hevia-Freire, Eva and Holland, Rebecca and Jeffery, John C. and Leedham, Angela P. and Russell, Christopher A. and Steiner, Alexander and Zagorski, Anette (2000) Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions. Chemical Communications (London) (18). pp. 1769-1770. ISSN 0009-241X (https://doi.org/10.1039/B004192K)

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Abstract

The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with BunLi (2 equivalents) yields a complex [Li2P(H)(NR)3]2 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3]2−.

ORCID iDs

Burke, Lisa T., Hevia-Freire, Eva ORCID logoORCID: https://orcid.org/0000-0002-3998-7506, Holland, Rebecca, Jeffery, John C., Leedham, Angela P., Russell, Christopher A., Steiner, Alexander and Zagorski, Anette;
  • Item type:Article
    ID code:34775
    Dates:
    Date
    Event
    2000
    Published
    Keywords:phosphonate anion , phosphorous oxoanions , 2-methoxyaniline , Chemistry, Chemistry(all)
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:21 Oct 2011 12:27
    Last modified:18 Mar 2023 03:44
    URI:https://strathprints.strath.ac.uk/id/eprint/34775
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