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Open Access research with a European policy impact...

The Strathprints institutional repository is a digital archive of University of Strathclyde's Open Access research outputs. Strathprints provides access to thousands of Open Access research papers by Strathclyde researchers, including by researchers from the European Policies Research Centre (EPRC).

EPRC is a leading institute in Europe for comparative research on public policy, with a particular focus on regional development policies. Spanning 30 European countries, EPRC research programmes have a strong emphasis on applied research and knowledge exchange, including the provision of policy advice to EU institutions and national and sub-national government authorities throughout Europe.

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Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions

Burke, Lisa T. and Hevia-Freire, Eva and Holland, Rebecca and Jeffery, John C. and Leedham, Angela P. and Russell, Christopher A. and Steiner, Alexander and Zagorski, Anette (2000) Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions. Chemical Communications (London) (18). pp. 1769-1770. ISSN 0009-241X

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Abstract

The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with BunLi (2 equivalents) yields a complex [Li2P(H)(NR)3]2 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3]2−.