Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions
Burke, Lisa T. and Hevia-Freire, Eva and Holland, Rebecca and Jeffery, John C. and Leedham, Angela P. and Russell, Christopher A. and Steiner, Alexander and Zagorski, Anette (2000) Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions. Chemical Communications (London) (18). pp. 1769-1770. ISSN 0009-241X (https://doi.org/10.1039/B004192K)
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The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with BunLi (2 equivalents) yields a complex [Li2P(H)(NR)3]2 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3]2−.
ORCID iDs
Burke, Lisa T., Hevia-Freire, Eva
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Item type: Article ID code: 34775 Dates: DateEvent2000PublishedKeywords: phosphonate anion , phosphorous oxoanions , 2-methoxyaniline , Chemistry, Chemistry(all) Subjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 21 Oct 2011 12:27 Last modified: 20 May 2023 03:55 URI: https://strathprints.strath.ac.uk/id/eprint/34775
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