Post-metalation structural insights into the use of alkali-metal-mediated zincation for directed ortho-metalation of a tertiary aromatic amide
Clegg, W and Dale, S H and Harrington, R W and Hevia, E and Honeyman, G W and Mulvey, R E (2006) Post-metalation structural insights into the use of alkali-metal-mediated zincation for directed ortho-metalation of a tertiary aromatic amide. Angewandte Chemie, 45 (15). pp. 2374-2377. ISSN 0044-8249
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Abstract
Invisible using standard electrophilic substitution detection methods, two distinct ortho-metalated “intermediates” generated by alkali-metal-mediated zincation of N,N-diisopropylbenzamide are structurally elucidated.
Author(s): | Clegg, W, Dale, S H, Harrington, R W, Hevia, E, Honeyman, G W and Mulvey, R E | Item type: | Article |
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ID code: | 34750 |
Keywords: | alkali metals, amides, directing groups, metalation, zinc, zinc exchange-reaction, lithiation, reagents, reactivities, alkyl, Chemistry, Medicine(all) |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Pure Administrator |
Date deposited: | 21 Oct 2011 11:33 |
Last modified: | 29 Mar 2019 03:15 |
URI: | https://strathprints.strath.ac.uk/id/eprint/34750 |
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