New synthetic routes to cationic rhenium tricarbonyl bipyridine complexes with labile ligands
Hevia, E and Perez, J and Riera, V and Miguel, D and Kassel, S and Rheingold, A (2002) New synthetic routes to cationic rhenium tricarbonyl bipyridine complexes with labile ligands. Inorganic Chemistry, 41 (18). pp. 4673-4679. ISSN 0020-1669 (https://doi.org/10.1021/ic020174c)
Full text not available in this repository.Request a copyAbstract
Triflate abstraction from the complex [Re(OTf)(CO)(3)(bipy)] (1) using the salt NaBAr'(4) (Ar' = 3,5-bis(trifluoromethyl)phenyl) in dichloromethane solution in the presence of L = PPh3, NCMe, NCPh, imines, ketones, Et2O, THF, MeOH, and Mel affords cationic complexes [Re(L)(CO)(3)(bipy)](+) as their BAr'(-)(4) salts. The new complexes have been characterized spectroscopically and, for [Re(eta1-O=C(Me)R)(CO)(3)(bipy)]BAr'(4) (R = CH3, 6a; R = Ph, 6b), and [Re(THF)(CO)(3)(bipy)]BAr'(4) (9), also by single-crystal X-ray diffraction. Compared with conventional methodologies, the route reported here allows the coordination of a broader range of weakly coordinating ligands and requires considerably milder conditions. On the other hand, the reactions of lithium acetylides with [Re(THF)(CO)(3)(bipy)]BAr'(4) (9) can be used for the high-yield syntheses of rhenium alkynyls [Re(Cequivalent toCR)(CO)(3)(bipy)] (R = Ph, 12; R SiMe3, 13). Complex 9 was found to catalyze the aziridination of benzylideneaniline with ethyl diazoacetate.
-
-
Item type: Article ID code: 34753 Dates: DateEvent9 September 2002PublishedSubjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 21 Oct 2011 12:05 Last modified: 18 Apr 2024 12:19 URI: https://strathprints.strath.ac.uk/id/eprint/34753