Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns
Hevia, E. and Gallagher, D.J. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Talmard, C. (2004) Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns. Chemical Communications (London), 2004 (21). pp. 2422-2423. ISSN 0009-241X
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Abstract
Only two-fold amination occurs when 3 molar equivalents of TMPH are offered to a 1:1 BuNa-Bu2Mg mixture; adding TMEDA gives the mixed alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP) Mg(TMP)], which itself affords the phenyl-bridged analogue when reacted with benzene.
Creators(s): |
Hevia, E. ![]() ![]() ![]() ![]() | Item type: | Article |
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ID code: | 643 |
Keywords: | magnesium, chemistry, mixed-metal alkyl amide, Chemistry, Chemistry(all) |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry Unknown Department |
Depositing user: | Mr Derek Boyle |
Date deposited: | 28 Mar 2006 |
Last modified: | 20 Jan 2021 16:59 |
Related URLs: | |
URI: | https://strathprints.strath.ac.uk/id/eprint/643 |
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