Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns

Hevia, E. and Gallagher, D.J. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Talmard, C. (2004) Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns. Chemical Communications (London), 2004 (21). pp. 2422-2423. ISSN 0009-241X

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Official URL: http://dx.doi.org/10.1039/b410293b

Abstract

Only two-fold amination occurs when 3 molar equivalents of TMPH are offered to a 1:1 BuNa-Bu2Mg mixture; adding TMEDA gives the mixed alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP) Mg(TMP)], which itself affords the phenyl-bridged analogue when reacted with benzene.

Author(s):	Hevia, E. ORCID: https://orcid.org/0000-0002-3998-7506, Gallagher, D.J., Kennedy, A.R. ORCID: https://orcid.org/0000-0003-3652-6015, Mulvey, R.E. ORCID: https://orcid.org/0000-0002-1015-2564, O'Hara, C.T. ORCID: https://orcid.org/0000-0002-1691-1568 and Talmard, C.
Item type:	Article
ID code:	643
Keywords:	magnesium, chemistry, mixed-metal alkyl amide, Chemistry, Chemistry(all)
Subjects:	Science > Chemistry
Department:	Faculty of Science > Pure and Applied Chemistry Unknown Department
Depositing user:	Mr Derek Boyle
Date deposited:	28 Mar 2006
Last modified:	23 Aug 2019 02:03
Related URLs:	http://www.rsc.org/ej/CC/2004/b410293b.p...
URI:	https://strathprints.strath.ac.uk/id/eprint/643
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