Synthesis and characterization of an infinite sheet of metal-alkyl bonds : unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate
Baillie, Sharon E. and Clegg, William and Garcia-Alvarez, Pablo and Hevia, Eva and Kennedy, Alan R. and Klett, Jan and Russo, Luca (2011) Synthesis and characterization of an infinite sheet of metal-alkyl bonds : unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate. Chemical Communications (London), 47 (1). pp. 388-390. ISSN 0009-241X
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Abstract
The study of co-complexation reactions between NaCH2SiMe3 and Mg(CH2SiMe3)(2) has allowed the isolation and structural elucidation of the first solvent-free alkali-metal alkylmagnesiate [{NaMg(CH2SiMe3)(3)}(infinity)] (1) as well as the related solvent-free sodium alkyl [{(NaCH2SiMe3)(4)}(infinity)] (3).
Creators(s): |
Baillie, Sharon E., Clegg, William, Garcia-Alvarez, Pablo, Hevia, Eva ![]() ![]() | Item type: | Article |
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ID code: | 33729 |
Keywords: | trisalkylmagnesiate, metal-alkyl bonds , alkali-metal trisalkylmagnesiate, Physical and theoretical chemistry, Chemistry(all) |
Subjects: | Science > Chemistry > Physical and theoretical chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Pure Administrator |
Date deposited: | 18 Oct 2011 10:56 |
Last modified: | 29 Jan 2021 03:53 |
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URI: | https://strathprints.strath.ac.uk/id/eprint/33729 |
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