Synthesis and characterization of an infinite sheet of metal-alkyl bonds : unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate

Baillie, Sharon E. and Clegg, William and Garcia-Alvarez, Pablo and Hevia, Eva and Kennedy, Alan R. and Klett, Jan and Russo, Luca (2011) Synthesis and characterization of an infinite sheet of metal-alkyl bonds : unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate. Chemical Communications (London), 47 (1). pp. 388-390. ISSN 0009-241X

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Abstract

The study of co-complexation reactions between NaCH2SiMe3 and Mg(CH2SiMe3)(2) has allowed the isolation and structural elucidation of the first solvent-free alkali-metal alkylmagnesiate [{NaMg(CH2SiMe3)(3)}(infinity)] (1) as well as the related solvent-free sodium alkyl [{(NaCH2SiMe3)(4)}(infinity)] (3).

Author(s):Baillie, Sharon E., Clegg, William, Garcia-Alvarez, Pablo, Hevia, Eva ORCID logoORCID: https://orcid.org/0000-0002-3998-7506, Kennedy, Alan R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Klett, Jan and Russo, Luca
Item type:Article
ID code:33729
Keywords:trisalkylmagnesiate, metal-alkyl bonds , alkali-metal trisalkylmagnesiate, Physical and theoretical chemistry, Chemistry(all)
Subjects:Science > Chemistry > Physical and theoretical chemistry
Department:Faculty of Science > Pure and Applied Chemistry
Depositing user: Pure Administrator
Date deposited:18 Oct 2011 10:56
Last modified:20 Sep 2019 02:38
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URI:https://strathprints.strath.ac.uk/id/eprint/33729
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