Synthesis and characterization of an infinite sheet of metal-alkyl bonds : unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate

Baillie, Sharon E. and Clegg, William and Garcia-Alvarez, Pablo and Hevia, Eva and Kennedy, Alan R. and Klett, Jan and Russo, Luca (2011) Synthesis and characterization of an infinite sheet of metal-alkyl bonds : unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate. Chemical Communications (London), 47 (1). pp. 388-390. ISSN 0009-241X

Abstract

The study of co-complexation reactions between NaCH2SiMe3 and Mg(CH2SiMe3)(2) has allowed the isolation and structural elucidation of the first solvent-free alkali-metal alkylmagnesiate [{NaMg(CH2SiMe3)(3)}(infinity)] (1) as well as the related solvent-free sodium alkyl [{(NaCH2SiMe3)(4)}(infinity)] (3).

ORCID iDs

Hevia, Eva ORCID: https://orcid.org/0000-0002-3998-7506

Kennedy, Alan R. ORCID: https://orcid.org/0000-0003-3652-6015

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  Item type:	Article
  ID code:	33729
  Dates:	Date Event 2011 Published
  Keywords:	trisalkylmagnesiate, metal-alkyl bonds , alkali-metal trisalkylmagnesiate, Physical and theoretical chemistry, Chemistry(all)
  Subjects:	Science > Chemistry > Physical and theoretical chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	18 Oct 2011 10:56
  Last modified:	11 Jun 2021 02:05
  Related URLs:	Scopus publication
  URI:	https://strathprints.strath.ac.uk/id/eprint/33729