Synthesis and characterization of an infinite sheet of metal-alkyl bonds : unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate
Baillie, Sharon E. and Clegg, William and Garcia-Alvarez, Pablo and Hevia, Eva and Kennedy, Alan R. and Klett, Jan and Russo, Luca (2011) Synthesis and characterization of an infinite sheet of metal-alkyl bonds : unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate. Chemical Communications (London), 47 (1). pp. 388-390. ISSN 0009-241X
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Abstract
The study of co-complexation reactions between NaCH2SiMe3 and Mg(CH2SiMe3)(2) has allowed the isolation and structural elucidation of the first solvent-free alkali-metal alkylmagnesiate [{NaMg(CH2SiMe3)(3)}(infinity)] (1) as well as the related solvent-free sodium alkyl [{(NaCH2SiMe3)(4)}(infinity)] (3).
ORCID iDs
Baillie, Sharon E., Clegg, William, Garcia-Alvarez, Pablo, Hevia, Eva
ORCID: https://orcid.org/0000-0002-3998-7506, Kennedy, Alan R. ORCID: https://orcid.org/0000-0003-3652-6015, Klett, Jan and Russo, Luca;
Item type: Article ID code: 33729 Dates: DateEvent2011PublishedKeywords: trisalkylmagnesiate, metal-alkyl bonds , alkali-metal trisalkylmagnesiate, Physical and theoretical chemistry, Chemistry(all) Subjects: Science > Chemistry > Physical and theoretical chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 18 Oct 2011 10:56 Last modified: 11 Jun 2021 02:05 Related URLs: URI: https://strathprints.strath.ac.uk/id/eprint/33729
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