Selective meta-deprotonation of toluene by using alkali-metal-mediated magnesiation
Andrikopoulos, Prokopis C. and Armstrong, David R. and Graham, David V. and Hevia, Eva and Kennedy, Alan R. and Mulvey, Robert E. and O'Hara, Charles T. and Talmard, Christine (2005) Selective meta-deprotonation of toluene by using alkali-metal-mediated magnesiation. Angewandte Chemie, 44 (22). pp. 3459-3462. ISSN 0044-8249
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Abstract
Conventional meta-deprotonation of toluene leads to resonance of Benzylanionen. But with a new type of bimetallic metalation, the sodium-mediated Magnesierung, can shift the thermodynamic meta-deprotonation in the ring.
Creators(s): |
Andrikopoulos, Prokopis C., Armstrong, David R., Graham, David V., Hevia, Eva ![]() ![]() ![]() ![]() | Item type: | Article |
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ID code: | 651 |
Keywords: | deprotonation, inverse crown compounds, magnesium, metalation, sodium, Chemistry, Medicine(all) |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Mr Derek Boyle |
Date deposited: | 28 Mar 2006 |
Last modified: | 20 Jan 2021 17:00 |
Related URLs: | |
URI: | https://strathprints.strath.ac.uk/id/eprint/651 |
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