Structurally defined reactions of sodium tmp-zincate with nitrile compounds: synthesis of a salt-like sodium sodiumdizincate and other unexpected ion-pair products

Clegg, W. and Dale, S.H. and Hevia, E. and Hogg, L.M. and Honeyman, G.W. and Mulvey, R.E. and O'Hara, C.T. and Russo, L. (2008) Structurally defined reactions of sodium tmp-zincate with nitrile compounds: synthesis of a salt-like sodium sodiumdizincate and other unexpected ion-pair products. Angewandte Chemie, 47 (4). pp. 731-734. ISSN 0044-8249

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Abstract

Zany zincation: Seemingly simple zincation reactions of aromatic or aliphatic nitriles are in reality highly complicated affairs involving separated ion pairs (see X-ray structure; yellow Na, blue N, green Zn; left cation, right anion) or joined ion pairs. The results also show that the free zincate anions can engage in complicated dismutation processes.

Creators(s): Clegg, W., Dale, S.H., Hevia, E. ORCID logoORCID: https://orcid.org/0000-0002-3998-7506, Hogg, L.M., Honeyman, G.W., Mulvey, R.E. ORCID logoORCID: https://orcid.org/0000-0002-1015-2564, O'Hara, C.T. ORCID logoORCID: https://orcid.org/0000-0002-1691-1568 and Russo, L.;
Item type:Article
ID code:19827
Keywords:ion pairs, metalation, nitriles, sodium, zinc, Chemistry, Medicine(all)
Subjects:Science > Chemistry
Department:Faculty of Science > Pure and Applied Chemistry
Depositing user: Strathprints Administrator
Date deposited:01 Jun 2010 10:00
Last modified:05 Sep 2020 01:03
URI:https://strathprints.strath.ac.uk/id/eprint/19827
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