Structurally defined reactions of sodium tmp-zincate with nitrile compounds: synthesis of a salt-like sodium sodiumdizincate and other unexpected ion-pair products
Clegg, W. and Dale, S.H. and Hevia, E. and Hogg, L.M. and Honeyman, G.W. and Mulvey, R.E. and O'Hara, C.T. and Russo, L. (2008) Structurally defined reactions of sodium tmp-zincate with nitrile compounds: synthesis of a salt-like sodium sodiumdizincate and other unexpected ion-pair products. Angewandte Chemie, 47 (4). pp. 731-734. ISSN 0044-8249
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Abstract
Zany zincation: Seemingly simple zincation reactions of aromatic or aliphatic nitriles are in reality highly complicated affairs involving separated ion pairs (see X-ray structure; yellow Na, blue N, green Zn; left cation, right anion) or joined ion pairs. The results also show that the free zincate anions can engage in complicated dismutation processes.
Creators(s): |
Clegg, W., Dale, S.H., Hevia, E. ![]() ![]() ![]() | Item type: | Article |
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ID code: | 19827 |
Keywords: | ion pairs, metalation, nitriles, sodium, zinc, Chemistry, Medicine(all) |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Strathprints Administrator |
Date deposited: | 01 Jun 2010 10:00 |
Last modified: | 20 Jan 2021 18:30 |
URI: | https://strathprints.strath.ac.uk/id/eprint/19827 |
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