Lithium dimethyl(amido)zinc complexes: contrasting zincate (amido = tmp) and inverse zincate (amido = hmds) structures on addition of TMEDA
Graham, D.V. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. (2006) Lithium dimethyl(amido)zinc complexes: contrasting zincate (amido = tmp) and inverse zincate (amido = hmds) structures on addition of TMEDA. Organometallics, 25 (14). pp. 3297-3300. ISSN 0276-7333
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Abstract
Introducing TMEDA to the lithium dimethyl(amido)zincates 'LiZn(NR2)Me2' leads to a discrete ion-contacted zincate with TMEDA bound to lithium in the case of NR2 = TMP but to a novel 'inverse zincate' with TMEDA bound to zinc in the case of NR2 = HMDS, where unexpectedly Me2Zn(TMEDA) functions as a η1,μ ligand to dimeric (LiHMDS)2 molecules to afford a zigzag chain polymer.
| Creators(s): |
Graham, D.V., Hevia, E.  ORCID: https://orcid.org/0000-0002-3998-7506, Kennedy, A.R. ORCID: https://orcid.org/0000-0003-3652-6015 and Mulvey, R.E. ORCID: https://orcid.org/0000-0002-1015-2564;
| Item type: | Article |
|---|---|
| ID code: | 17233 |
| Keywords: | TMEDA, lithium dimethyl(amido)zincates, LiZn(NR2)Me2, zincate, lithium, zinc, molecules, chain polymer, Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Depositing user: | Strathprints Administrator |
| Date deposited: | 09 Apr 2010 11:18 |
| Last modified: | 07 Sep 2020 01:57 |
| URI: | https://strathprints.strath.ac.uk/id/eprint/17233 |
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