Lithium dimethyl(amido)zinc complexes: contrasting zincate (amido = tmp) and inverse zincate (amido = hmds) structures on addition of TMEDA
Graham, D.V. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. (2006) Lithium dimethyl(amido)zinc complexes: contrasting zincate (amido = tmp) and inverse zincate (amido = hmds) structures on addition of TMEDA. Organometallics, 25 (14). pp. 3297-3300. ISSN 0276-7333
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Abstract
Introducing TMEDA to the lithium dimethyl(amido)zincates 'LiZn(NR2)Me2' leads to a discrete ion-contacted zincate with TMEDA bound to lithium in the case of NR2 = TMP but to a novel 'inverse zincate' with TMEDA bound to zinc in the case of NR2 = HMDS, where unexpectedly Me2Zn(TMEDA) functions as a η1,μ ligand to dimeric (LiHMDS)2 molecules to afford a zigzag chain polymer.
Creators(s): |
Graham, D.V., Hevia, E. ![]() ![]() ![]() | Item type: | Article |
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ID code: | 17233 |
Keywords: | TMEDA, lithium dimethyl(amido)zincates, LiZn(NR2)Me2, zincate, lithium, zinc, molecules, chain polymer, Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Strathprints Administrator |
Date deposited: | 09 Apr 2010 11:18 |
Last modified: | 20 Jan 2021 18:28 |
URI: | https://strathprints.strath.ac.uk/id/eprint/17233 |
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