Structurally-defined direct C-magnesiation and C-zincation of N-heterocyclic aromatic compounds using alkali-metal-mediated metallation
Mulvey, R.E. and Kennedy, A.R. and Hevia, E. (2007) Structurally-defined direct C-magnesiation and C-zincation of N-heterocyclic aromatic compounds using alkali-metal-mediated metallation. Chemical Communications (London) (27). pp. 2864-2866. ISSN 0009-241X (http:/dx.doi.org/10.1039/b704362g)
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Demonstrating direct synergic ''low polarity metallation'', 1-methylindole is C-magnesiated by (TMEDA)2?Na2MgBu4 and C-zincated by (TMEDA)?Na(tBu)(TMP)Zn(tBu), and 1-methylpyrrole is C-zincated by the same reagent, with all three metal products successfully crystallographically characterised.
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Item type: Article ID code: 27773 Dates: DateEvent2007PublishedSubjects: Science > Chemistry > Physical and theoretical chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Miss Stephanie Cassidy Date deposited: 11 Oct 2010 19:02 Last modified: 14 Jun 2024 08:16 URI: https://strathprints.strath.ac.uk/id/eprint/27773
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