Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions

Andrikopoulos, Prokopis C. and Armstrong, David R. and Hevia, Eva and Kennedy, Alan R. and Mulvey, Robert E. and O'Hara, Charles T. (2005) Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions. Chemical Communications (London), 2005 (9). pp. 1131-1133. ISSN 0009-241X

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Abstract

Toluene is metallated by DABCO-activated disodium tetrabutylmagnesiate, but not by DABCO-activated monosodium tributylmagnesiate; this distinction is rationalised by DFT calculations on model systems, and the crystal structure of the main non-metallated product, which shows interstitial MgBu42- dianions within a polycationic network, is reported.

Creators(s): Andrikopoulos, Prokopis C., Armstrong, David R., Hevia, Eva ORCID logoORCID: https://orcid.org/0000-0002-3998-7506, Kennedy, Alan R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Mulvey, Robert E. ORCID logoORCID: https://orcid.org/0000-0002-1015-2564 and O'Hara, Charles T. ORCID logoORCID: https://orcid.org/0000-0002-1691-1568;
Item type:Article
ID code:646
Keywords:magnesium, chemistry, Chemistry, Chemistry(all)
Subjects:Science > Chemistry
Department:Faculty of Science > Pure and Applied Chemistry
Depositing user: Mr Derek Boyle
Date deposited:28 Mar 2006
Last modified:20 Jan 2021 17:00
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URI:https://strathprints.strath.ac.uk/id/eprint/646
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