Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions

Andrikopoulos, Prokopis C. and Armstrong, David R. and Hevia, Eva and Kennedy, Alan R. and Mulvey, Robert E. and O'Hara, Charles T. (2005) Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions. Chemical Communications (London), 2005 (9). pp. 1131-1133. ISSN 0009-241X (https://doi.org/10.1039/b416636a)

Abstract

Toluene is metallated by DABCO-activated disodium tetrabutylmagnesiate, but not by DABCO-activated monosodium tributylmagnesiate; this distinction is rationalised by DFT calculations on model systems, and the crystal structure of the main non-metallated product, which shows interstitial MgBu42- dianions within a polycationic network, is reported.

ORCID iDs

Hevia, Eva ORCID: https://orcid.org/0000-0002-3998-7506

Kennedy, Alan R. ORCID: https://orcid.org/0000-0003-3652-6015

Mulvey, Robert E. ORCID: https://orcid.org/0000-0002-1015-2564

• Share and Export
  

  RDF+XMLBibTeXRIOXX2 XMLRDF+N-TriplesJSONDublin CoreAtomSimple MetadataReferMETSHTML CitationASCII CitationOpenURL ContextObjectEndNoteOpenURL ContextObject in SpanMODSMPEG-21 DIDLEP3 XMLData Cite XMLRIS (EndNote Online, Zotero, Ref manager, etc)RDF+N3Multiline CSV
• Citations and altmetrics
• Item metadata

  Item type:	Article
  ID code:	646
  Dates:	Date Event January 2005 Published 18 January 2005 Published Online 8 May 2004 Accepted
  Keywords:	magnesium, chemistry, Chemistry, Chemistry(all)
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Mr Derek Boyle
  Date deposited:	28 Mar 2006
  Last modified:	19 May 2023 01:03
  Related URLs:	http://www.rsc.org/ej/CC/2005/b416636a.p...
  URI:	https://strathprints.strath.ac.uk/id/eprint/646