Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions
Andrikopoulos, Prokopis C. and Armstrong, David R. and Hevia, Eva and Kennedy, Alan R. and Mulvey, Robert E. and O'Hara, Charles T. (2005) Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions. Chemical Communications (London), 2005 (9). pp. 1131-1133. ISSN 0009-241X
Full text not available in this repository.Request a copy from the Strathclyde authorOfficial URL: https://doi.org/10.1039/b416636a
Abstract
Toluene is metallated by DABCO-activated disodium tetrabutylmagnesiate, but not by DABCO-activated monosodium tributylmagnesiate; this distinction is rationalised by DFT calculations on model systems, and the crystal structure of the main non-metallated product, which shows interstitial MgBu42- dianions within a polycationic network, is reported.
Creators(s): |
Andrikopoulos, Prokopis C., Armstrong, David R., Hevia, Eva ![]() ![]() ![]() ![]() | Item type: | Article |
---|---|
ID code: | 646 |
Keywords: | magnesium, chemistry, Chemistry, Chemistry(all) |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Mr Derek Boyle |
Date deposited: | 28 Mar 2006 |
Last modified: | 20 Jan 2021 17:00 |
Related URLs: | |
URI: | https://strathprints.strath.ac.uk/id/eprint/646 |
Export data: |
CORE (COnnecting REpositories)