Synthesis of the mixed lithium-magnesium, mixed amide (R,R/S,S)-[{LiMg(TMP)[CH2Si(Me)(2)N(SiMe3)]}(2)]: a conformationally-locked structure of five fused rings inducing two stereogenic nitrogen centres

Kennedy, A.R. and MacLellan, J.G. and Moir, J.H. and Mulvey, R.E. and Rodger, P.J.A. (2000) Synthesis of the mixed lithium-magnesium, mixed amide (R,R/S,S)-[{LiMg(TMP)[CH2Si(Me)(2)N(SiMe3)]}(2)]: a conformationally-locked structure of five fused rings inducing two stereogenic nitrogen centres. Chemical Communications (London), 2000 (18). pp. 1757-1758. ISSN 0009-241X (http://dx.doi.org/10.1039/b004317f)

Abstract

Reaction of the magnesium amide Mg(TMP)2 with the lithium amide LiHMDS is accompanied by an unexpected, sterically-promoted hydrogen transfer/amine elimination process, to yield the novel title compound which is the first such heterometallic composition to contain a heteroleptic amide ligand set.

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• Item metadata

  Item type:	Article
  ID code:	1270
  Dates:	Date Event 2 August 2000 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry Unknown Department
  Depositing user:	Users 45 not found.
  Date deposited:	23 Jun 2006
  Last modified:	08 Apr 2024 15:17
  URI:	https://strathprints.strath.ac.uk/id/eprint/1270