Novel octameric structure of the lithium primary amide [{Bu(t)N(H)Li}(8)] and its implication for the directed synthesis of heterometallic imide cages
Barnett, Nicholas D. R. and Clegg, William and Horsburgh, Lynne and Lindsay, David M. and Liu, Qi-Yong and Mackenzie, Fiona M. and Mulvey, Robert E. and Williard, Paul G. (1996) Novel octameric structure of the lithium primary amide [{Bu(t)N(H)Li}(8)] and its implication for the directed synthesis of heterometallic imide cages. Chemical Communications (20). pp. 2321-2322. ISSN 1359-7345 (https://doi.org/10.1039/cc9960002321)
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The crystalline lithium primary amide derived from tert-butylamine, [{Bu(t)N(H)Li}(n)], is structurally characterised by an X-ray diffraction study and shown to be a novel octameric (n = 8) ladder conformation, the cyclic, 'double-crown' nature of which implies molecules of this design could direct the synthesis of heterobimetallic (i.e, lithium and another metal) imide cage constructions.
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Item type: Article ID code: 38192 Dates: DateEvent21 October 1996PublishedSubjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 06 Mar 2012 12:43 Last modified: 08 Apr 2024 19:51 URI: https://strathprints.strath.ac.uk/id/eprint/38192