Structurally stimulated deprotonation/alumination of the TMP anion

Conway, B. and Kennedy, A.R. and Mulvey, R.E. and Robertson, Stuart D. and Garcia Alvarez, Joaquin (2010) Structurally stimulated deprotonation/alumination of the TMP anion. Angewandte Chemie, 49 (18). pp. 3182-3184. ISSN 0044-8249

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Official URL: https://doi.org/10.1002/anie.201000181

Abstract

Long utilized as a strong Brønsted base, the tetramethylpiperidine (TMP) anion is forced to convert to a Brønsted acid in the presence of a potassium–aluminate species. The new compound [(TMEDA)K(μ-TMP*)(μ-iBu)Al(iBu)] was obtained where TMP* represents a CH3- and NH-deprotonated dianionic variant of TMP.

Creators(s):	Conway, B., Kennedy, A.R. ORCID: https://orcid.org/0000-0003-3652-6015, Mulvey, R.E. ORCID: https://orcid.org/0000-0002-1015-2564, Robertson, Stuart D. ORCID: https://orcid.org/0000-0002-9330-8770 and Garcia Alvarez, Joaquin;
Item type:	Article
ID code:	27616
Keywords:	alkali metals, aluminium, amides, metalation, steric effects, Science (General), Chemistry, Medicine(all)
Subjects:	Science > Science (General) Science > Chemistry
Department:	Faculty of Science > Pure and Applied Chemistry
Depositing user:	Mrs Gillian Neeson
Date deposited:	13 May 2011 08:41
Last modified:	27 Feb 2020 02:09
Related URLs:	Scopus publication
URI:	https://strathprints.strath.ac.uk/id/eprint/27616
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