Structurally stimulated deprotonation/alumination of the TMP anion
Conway, B. and Kennedy, A.R. and Mulvey, R.E. and Robertson, Stuart D. and Garcia Alvarez, Joaquin (2010) Structurally stimulated deprotonation/alumination of the TMP anion. Angewandte Chemie, 49 (18). pp. 3182-3184. ISSN 0044-8249
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Abstract
Long utilized as a strong Brønsted base, the tetramethylpiperidine (TMP) anion is forced to convert to a Brønsted acid in the presence of a potassium–aluminate species. The new compound [(TMEDA)K(μ-TMP*)(μ-iBu)Al(iBu)] was obtained where TMP* represents a CH3- and NH-deprotonated dianionic variant of TMP.
Creators(s): |
Conway, B., Kennedy, A.R. ![]() ![]() ![]() | Item type: | Article |
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ID code: | 27616 |
Keywords: | alkali metals, aluminium, amides, metalation, steric effects, Science (General), Chemistry, Medicine(all) |
Subjects: | Science > Science (General) Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Mrs Gillian Neeson |
Date deposited: | 13 May 2011 08:41 |
Last modified: | 20 Jan 2021 19:04 |
Related URLs: | |
URI: | https://strathprints.strath.ac.uk/id/eprint/27616 |
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