Structurally stimulated deprotonation/alumination of the TMP anion

Conway, B. and Kennedy, A.R. and Mulvey, R.E. and Robertson, Stuart D. and Garcia Alvarez, Joaquin (2010) Structurally stimulated deprotonation/alumination of the TMP anion. Angewandte Chemie, 49 (18). pp. 3182-3184. ISSN 0044-8249 (https://doi.org/10.1002/anie.201000181)

Abstract

Long utilized as a strong Brønsted base, the tetramethylpiperidine (TMP) anion is forced to convert to a Brønsted acid in the presence of a potassium–aluminate species. The new compound [(TMEDA)K(μ-TMP*)(μ-iBu)Al(iBu)] was obtained where TMP* represents a CH3- and NH-deprotonated dianionic variant of TMP.

ORCID iDs

Kennedy, A.R. ORCID: https://orcid.org/0000-0003-3652-6015

Mulvey, R.E. ORCID: https://orcid.org/0000-0002-1015-2564

Robertson, Stuart D. ORCID: https://orcid.org/0000-0002-9330-8770

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  Item type:	Article
  ID code:	27616
  Dates:	Date Event 19 April 2010 Published
  Keywords:	alkali metals, aluminium, amides, metalation, steric effects, Science (General), Chemistry, Medicine(all)
  Subjects:	Science > Science (General) Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Mrs Gillian Neeson
  Date deposited:	13 May 2011 08:41
  Last modified:	03 Feb 2023 02:22
  Related URLs:	Scopus publication
  URI:	https://strathprints.strath.ac.uk/id/eprint/27616