Molecular structures of THF-solvated alkali-metal 2,2,6,6-tetramethylpiperidides finally revealed: x-ray crystallographic, DFT, and NMR (including DOSY) spectroscopic studies
Armstrong, David R. and Garcia-Alvarez, Pablo and Kennedy, Alan R. and Mulvey, Robert E. and Robertson, Stuart D. (2011) Molecular structures of THF-solvated alkali-metal 2,2,6,6-tetramethylpiperidides finally revealed: x-ray crystallographic, DFT, and NMR (including DOSY) spectroscopic studies. Chemistry - A European Journal, 17 (24). pp. 6725-6730. ISSN 0947-6539
Full text not available in this repository.Request a copy from the Strathclyde authorAbstract
The often studied THF solvates of the utility alkali-metal amides lithium and sodium 2,2,6,6-tetramethylpiperidide are shown to exist in the solid state as asymmetric cyclic dimers containing a central M2N2 ring and one molecule of donor per metal to give a distorted trigonal planar metal coordination. DFT studies support these structures and confirm the asymmetry in the ring. In C6D12 solution, the lithium amide displays a concentration-dependent equilibrium between a solvated and unsolvated species which have been shown by diffusion-ordered NMR spectroscopy (DOSY) to be a dimer and larger oligomer, respectively. A third species, a solvated monomer, is also present in very low concentration, as proven by spiking the NMR sample with THF. In contrast, the sodium amide displays a far simpler C6D12 solution chemistry, consistent with the solid-state dimeric arrangement but with labile THF ligands.
Creators(s): |
Armstrong, David R., Garcia-Alvarez, Pablo, Kennedy, Alan R. ![]() ![]() ![]() | Item type: | Article |
---|---|
ID code: | 33731 |
Keywords: | alkali metals, amides, crystal structures, density functional calculations, NMR spectroscopy, crystal structure, mixture analysis, orbital methods, solid-state, open dimers, basis sets, complexes, Physical and theoretical chemistry, Chemistry(all) |
Subjects: | Science > Chemistry > Physical and theoretical chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Pure Administrator |
Date deposited: | 18 Oct 2011 11:11 |
Last modified: | 01 Jan 2021 09:57 |
Related URLs: | |
URI: | https://strathprints.strath.ac.uk/id/eprint/33731 |
Export data: |