Synergic transformation of an ethylenediamine to a lithium 1,3-diaza-2-zincacyclopentene via an alkyllithium/bis(alkyl)zinc mixture

Campbell, Ross and Garcia-Alvarez, Pablo and Kennedy, Alan R. and Mulvey, Robert E. (2010) Synergic transformation of an ethylenediamine to a lithium 1,3-diaza-2-zincacyclopentene via an alkyllithium/bis(alkyl)zinc mixture. Chemistry - A European Journal, 16 (33). pp. 9964-9968. ISSN 0947-6539 (https://doi.org/10.1002/chem.201001314)

Abstract

Four bonds in total, two NH and two CH bonds, have been cleaved from a neutral secondary diamine through the cooperative effects of a lithium alkyl–zinc bisalkyl coalition aided by N,N,N′,N′-tetramethylethylenediamine (TMEDA) to generate a dianionic diazaethene.

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• Item metadata

  Item type:	Article
  ID code:	34026
  Dates:	Date Event 3 September 2010 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	20 Oct 2011 11:52
  Last modified:	08 Apr 2024 19:27
  Related URLs:	Scopus publication
  URI:	https://strathprints.strath.ac.uk/id/eprint/34026