Picture of boy being examining by doctor at a tuberculosis sanatorium

Understanding our future through Open Access research about our past...

Strathprints makes available scholarly Open Access content by researchers in the Centre for the Social History of Health & Healthcare (CSHHH), based within the School of Humanities, and considered Scotland's leading centre for the history of health and medicine.

Research at CSHHH explores the modern world since 1800 in locations as diverse as the UK, Asia, Africa, North America, and Europe. Areas of specialism include contraception and sexuality; family health and medical services; occupational health and medicine; disability; the history of psychiatry; conflict and warfare; and, drugs, pharmaceuticals and intoxicants.

Explore the Open Access research of the Centre for the Social History of Health and Healthcare. Or explore all of Strathclyde's Open Access research...

Image: Heart of England NHS Foundation Trust. Wellcome Collection - CC-BY.

Lewis base mediated rearrangements of alkali metal imides to η3-aza-allyl complexes: preparation and n.m.r. spectroscopic solution studies of [CH3CH2CH2C(H)C(But)N(H)·M·(HMPA)x]n(M = Li, x= 1; M = Na, x= 2)(HMPA = hexamethylphosphoramide)

ANDREWS, P C and ARMSTRONG, D R and MACGREGOR, M and Mulvey, Robert and REED, D (1989) Lewis base mediated rearrangements of alkali metal imides to η3-aza-allyl complexes: preparation and n.m.r. spectroscopic solution studies of [CH3CH2CH2C(H)C(But)N(H)·M·(HMPA)x]n(M = Li, x= 1; M = Na, x= 2)(HMPA = hexamethylphosphoramide). Journal of the Chemical Society, Chemical Communications (18). pp. 1341-1342. ISSN 0022-4936

Full text not available in this repository. Request a copy from the Strathclyde author

Abstract

The η3-aza-allyl complexes [CH3CH2CH2[graphic omitted]·(HMPA)x]n[M = Li,x= 1, (1); M = Na, X= 2, (2)](HMPA = hexamethylphosphoramide) are formed in high yield when HMPA [OP(NMe2)3] is added to the metal imides, [Bun(But)CNM]n; complexes (1) and (2) have been fully characterised by elemental analyses, and by i.r. and n.m.r. (1H, 7Li, 13C) spectroscopies.