An infinite ladder structure of alternating, fused K2N2 rhomboids and KN2 triangles : synthesis and crystallographic characterisation of benzotriazolatopotassium·HMPA (HMPA = hexamethylphosphoric triamide)

Andrews, Philip C. and Clegg, W. and Mulvey, Robert and O'Neil, P.A. and Wilson, Heather M.M. (1993) An infinite ladder structure of alternating, fused K2N2 rhomboids and KN2 triangles : synthesis and crystallographic characterisation of benzotriazolatopotassium·HMPA (HMPA = hexamethylphosphoric triamide). Journal of the Chemical Society, Chemical Communications, 1993 (14). pp. 1142-1144. ISSN 0022-4936 (https://doi.org/10.1039/C39930001142)

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Abstract

Benzotriazolatopotassium-HMPA, a rare example of an alkali metal benzotriazole derivative, has been synthesised and shown by an X-ray diffraction study to have an intricate, polymeric ladder arrangement made up of alternating, fused K2N2 rhomboids and KN2 triangles.

ORCID iDs

Andrews, Philip C., Clegg, W., Mulvey, Robert ORCID logoORCID: https://orcid.org/0000-0002-1015-2564, O'Neil, P.A. and Wilson, Heather M.M.;
  • Item type:Article
    ID code:38147
    Dates:
    Date
    Event
    21 July 1993
    Published
    Keywords:crystal structure, complexes, benzotriazole, derivatives, ligands, Chemistry, Molecular Medicine
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:05 Mar 2012 13:54
    Last modified:20 Jan 2021 20:02
    URI:https://strathprints.strath.ac.uk/id/eprint/38147
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