An infinite ladder structure of alternating, fused K2N2 rhomboids and KN2 triangles : synthesis and crystallographic characterisation of benzotriazolatopotassium·HMPA (HMPA = hexamethylphosphoric triamide)

Andrews, Philip C. and Clegg, W. and Mulvey, Robert and O'Neil, P.A. and Wilson, Heather M.M. (1993) An infinite ladder structure of alternating, fused K2N2 rhomboids and KN2 triangles : synthesis and crystallographic characterisation of benzotriazolatopotassium·HMPA (HMPA = hexamethylphosphoric triamide). Journal of the Chemical Society, Chemical Communications, 1993 (14). pp. 1142-1144. ISSN 0022-4936

Abstract

Benzotriazolatopotassium-HMPA, a rare example of an alkali metal benzotriazole derivative, has been synthesised and shown by an X-ray diffraction study to have an intricate, polymeric ladder arrangement made up of alternating, fused K2N2 rhomboids and KN2 triangles.

ORCID iDs

Mulvey, Robert ORCID: https://orcid.org/0000-0002-1015-2564

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  Item type:	Article
  ID code:	38147
  Dates:	Date Event 21 July 1993 Published
  Keywords:	crystal structure, complexes, benzotriazole, derivatives, ligands, Chemistry, Molecular Medicine
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	05 Mar 2012 13:54
  Last modified:	20 Jan 2021 20:02
  URI:	https://strathprints.strath.ac.uk/id/eprint/38147