Synthesis of heteroleptic bis(amides) : crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]

Henderson, Kenneth W. and Mulvey, Robert and Clegg, William and O'Neil, Paul A. (1993) Synthesis of heteroleptic bis(amides) : crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]. Polyhedron, 12 (20). pp. 2535-2538. ISSN 0277-5387

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Official URL: https://doi.org/10.1016/S0277-5387(00)83080-6

Abstract

Reaction of Ph(2-Pyr)NH with ''Mg(Bu)2'', followed by addition of amine substrates, gives heteroleptic magnesium bis(amides), one of which, [{Mg[N(Ph)2][N(Ph)(2-Pyr)]}2], has been crystallographically characterized and shown to be a dimer with a central, rectangular azamagnesacyclic ring.

Author(s):	Henderson, Kenneth W., Mulvey, Robert ORCID: https://orcid.org/0000-0002-1015-2564, Clegg, William and O'Neil, Paul A.
Item type:	Article
ID code:	38833
Keywords:	Lithium Diisopropylamide LDA, amides, reagent, Chemistry, Materials Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry
Subjects:	Science > Chemistry
Department:	Faculty of Science > Pure and Applied Chemistry
Depositing user:	Pure Administrator
Date deposited:	30 Mar 2012 11:20
Last modified:	05 Jul 2019 03:29
URI:	https://strathprints.strath.ac.uk/id/eprint/38833
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