Synthesis of heteroleptic bis(amides) : crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]
Henderson, Kenneth W. and Mulvey, Robert and Clegg, William and O'Neil, Paul A. (1993) Synthesis of heteroleptic bis(amides) : crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]. Polyhedron, 12 (20). pp. 2535-2538. ISSN 0277-5387
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Abstract
Reaction of Ph(2-Pyr)NH with ''Mg(Bu)2'', followed by addition of amine substrates, gives heteroleptic magnesium bis(amides), one of which, [{Mg[N(Ph)2][N(Ph)(2-Pyr)]}2], has been crystallographically characterized and shown to be a dimer with a central, rectangular azamagnesacyclic ring.
| Creators(s): |
Henderson, Kenneth W., Mulvey, Robert  ORCID: https://orcid.org/0000-0002-1015-2564, Clegg, William and O'Neil, Paul A.;
| Item type: | Article |
|---|---|
| ID code: | 38833 |
| Keywords: | Lithium Diisopropylamide LDA, amides, reagent, Chemistry, Materials Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Depositing user: | Pure Administrator |
| Date deposited: | 30 Mar 2012 11:20 |
| Last modified: | 20 Jan 2021 20:02 |
| URI: | https://strathprints.strath.ac.uk/id/eprint/38833 |
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