Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates

He, X.Y. and Noll, B.C. and Beatty, A. and Mulvey, R.E. and Henderson, K.W. (2004) Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates. Journal of the American Chemical Society, 126 (24). pp. 7444-7445. ISSN 0002-7863

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Abstract

Potassium, calcium, and mixed potassium-calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized.

Author(s):He, X.Y., Noll, B.C., Beatty, A., Mulvey, R.E. ORCID logoORCID: https://orcid.org/0000-0002-1015-2564 and Henderson, K.W.
Item type:Article
ID code:638
Keywords:inverse crown chemistry, magnesium, polymerization, complexes, diisopropylamides, alkoxides, sodium, Chemistry, Biochemistry, Colloid and Surface Chemistry, Chemistry(all), Catalysis
Subjects:Science > Chemistry
Department:Faculty of Science > Pure and Applied Chemistry
Depositing user: Mr Derek Boyle
Date deposited:28 Mar 2006
Last modified:15 Jan 2020 06:55
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URI:https://strathprints.strath.ac.uk/id/eprint/638
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