Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates
He, X.Y. and Noll, B.C. and Beatty, A. and Mulvey, R.E. and Henderson, K.W. (2004) Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates. Journal of the American Chemical Society, 126 (24). pp. 7444-7445. ISSN 0002-7863
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Abstract
Potassium, calcium, and mixed potassium-calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized.
Creators(s): |
He, X.Y., Noll, B.C., Beatty, A., Mulvey, R.E. ![]() | Item type: | Article |
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ID code: | 638 |
Keywords: | inverse crown chemistry, magnesium, polymerization, complexes, diisopropylamides, alkoxides, sodium, Chemistry, Biochemistry, Colloid and Surface Chemistry, Chemistry(all), Catalysis |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Mr Derek Boyle |
Date deposited: | 28 Mar 2006 |
Last modified: | 20 Jan 2021 16:59 |
Related URLs: | |
URI: | https://strathprints.strath.ac.uk/id/eprint/638 |
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