Bis[(μ-cyclopentylamino-N:N)dimethylaluminium(III)]
Craig, F.J. and Kennedy, A.R. and Mulvey, R.E. (2000) Bis[(μ-cyclopentylamino-N:N)dimethylaluminium(III)]. Acta Crystallographica Section C: Crystal Structure Communications, 56 (1). pp. 31-32. ISSN 0108-2701
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Abstract
Reaction of AlMe3 with NH2(C5H9) caused the evolution of methane and produced the dimeric species bis(μ-cyclopentylamino-N:N)bis[dimethylaluminium(III)], [Al(CH3)2-(C5H10N)]2, which was found to adopt a cis configuration of cyclopentyl groups about a bent AlNAlN ring (which has twofold crystallographic symmetry) instead of the more common trans arrangement.
| Creators(s): |
Craig, F.J., Kennedy, A.R.  ORCID: https://orcid.org/0000-0003-3652-6015 and Mulvey, R.E. ORCID: https://orcid.org/0000-0002-1015-2564;
| Item type: | Article |
|---|---|
| ID code: | 1263 |
| Keywords: | evolution of methane, dimeric species, cyclopentyl groups, crystallographic symmetry, Chemistry, Biochemistry, Genetics and Molecular Biology(all) |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Depositing user: | Catriona Mccallum |
| Date deposited: | 28 Jun 2006 |
| Last modified: | 07 Sep 2020 00:38 |
| Related URLs: | |
| URI: | https://strathprints.strath.ac.uk/id/eprint/1263 |
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