Bis[(μ-cyclopentylamino-N:N)dimethylaluminium(III)]

Craig, F.J. and Kennedy, A.R. and Mulvey, R.E. (2000) Bis[(μ-cyclopentylamino-N:N)dimethylaluminium(III)]. Acta Crystallographica Section C: Crystal Structure Communications, 56 (1). pp. 31-32. ISSN 0108-2701

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Abstract

Reaction of AlMe3 with NH2(C5H9) caused the evolution of methane and produced the dimeric species bis(μ-cyclo­pentyl­amino-N:N)bis[dimethylaluminium(III)], [Al(CH3)2-(C5H10N)]2, which was found to adopt a cis configuration of cyclopentyl groups about a bent AlNAlN ring (which has twofold crystallographic symmetry) instead of the more common trans arrangement.

Author(s):Craig, F.J., Kennedy, A.R. and Mulvey, R.E.
Item type:Article
ID code:1263
Keywords:evolution of methane, dimeric species, cyclopentyl groups, crystallographic symmetry, Chemistry, Biochemistry, Genetics and Molecular Biology(all)
Subjects:Science > Chemistry
Department:Faculty of Science > Pure and Applied Chemistry
Depositing user: Catriona Mccallum
Date deposited:28 Jun 2006
Last modified:03 Jan 2019 11:12
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URI:https://strathprints.strath.ac.uk/id/eprint/1263
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