Bis[(μ-cyclopentylamino-N:N)dimethylaluminium(III)]

Craig, F.J. and Kennedy, A.R. and Mulvey, R.E. (2000) Bis[(μ-cyclopentylamino-N:N)dimethylaluminium(III)]. Acta Crystallographica Section C: Crystal Structure Communications, 56 (1). pp. 31-32. ISSN 0108-2701 (http://dx.doi.org/10.1107/S0108270199012639)

Full text not available in this repository.Request a copy

Abstract

Reaction of AlMe3 with NH2(C5H9) caused the evolution of methane and produced the dimeric species bis(μ-cyclo­pentyl­amino-N:N)bis[dimethylaluminium(III)], [Al(CH3)2-(C5H10N)]2, which was found to adopt a cis configuration of cyclopentyl groups about a bent AlNAlN ring (which has twofold crystallographic symmetry) instead of the more common trans arrangement.

ORCID iDs

Craig, F.J., Kennedy, A.R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015 and Mulvey, R.E. ORCID logoORCID: https://orcid.org/0000-0002-1015-2564;
  • Item type:Article
    ID code:1263
    Dates:
    Date
    Event
    January 2000
    Published
    Keywords:evolution of methane, dimeric species, cyclopentyl groups, crystallographic symmetry, Chemistry, Biochemistry, Genetics and Molecular Biology(all)
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user:Users 45 not found.
    Date deposited:28 Jun 2006
    Last modified:19 May 2023 00:58
    Related URLs:
    URI:https://strathprints.strath.ac.uk/id/eprint/1263
CORE (COnnecting REpositories)