Bis[(μ-cyclopentylamino-N:N)dimethylaluminium(III)]
Craig, F.J. and Kennedy, A.R. and Mulvey, R.E. (2000) Bis[(μ-cyclopentylamino-N:N)dimethylaluminium(III)]. Acta Crystallographica Section C: Crystal Structure Communications, 56 (1). pp. 31-32. ISSN 0108-2701 (http://dx.doi.org/10.1107/S0108270199012639)
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Reaction of AlMe3 with NH2(C5H9) caused the evolution of methane and produced the dimeric species bis(μ-cyclopentylamino-N:N)bis[dimethylaluminium(III)], [Al(CH3)2-(C5H10N)]2, which was found to adopt a cis configuration of cyclopentyl groups about a bent AlNAlN ring (which has twofold crystallographic symmetry) instead of the more common trans arrangement.
ORCID iDs
Craig, F.J., Kennedy, A.R.

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Item type: Article ID code: 1263 Dates: DateEventJanuary 2000PublishedKeywords: evolution of methane, dimeric species, cyclopentyl groups, crystallographic symmetry, Chemistry, Biochemistry, Genetics and Molecular Biology(all) Subjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Users 45 not found. Date deposited: 28 Jun 2006 Last modified: 19 May 2023 00:58 Related URLs: URI: https://strathprints.strath.ac.uk/id/eprint/1263
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