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The structural isomers of {[ph(2-pyridyl)NLi]·[OP(NMe2)3]}2: dimeric species with alternative central (LiN)2 and (LiO)2 rings, the latter involving unprecedented neutral bridging oxygen ligands

BARR, D and CLEGG, W and Mulvey, Robert and SNAITH, R (1984) The structural isomers of {[ph(2-pyridyl)NLi]·[OP(NMe2)3]}2: dimeric species with alternative central (LiN)2 and (LiO)2 rings, the latter involving unprecedented neutral bridging oxygen ligands. Journal of the Chemical Society, Chemical Communications (11). pp. 700-701. ISSN 0022-4936

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Abstract

An X-ray crystallographic study of the title compound, (1), shows it to consist of two structural isomers, one, (1A), with a planar (LiN)2 ring structure provided by µ-amido ligands, but the other,(1B), with an (LiO)2 ring due to previously unobserved bridging by the oxygen of formally neutral ligand.

Item type: Article
ID code: 37488
Keywords: neutral bridging oxygen ligands , oxygen ligands , structural isomers, Chemistry, Molecular Medicine
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Depositing user: Pure Administrator
Date deposited: 08 Feb 2012 15:35
Last modified: 11 Aug 2017 04:59
URI: https://strathprints.strath.ac.uk/id/eprint/37488
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