The structural isomers of {[ph(2-pyridyl)NLi]·[OP(NMe2)3]}2: dimeric species with alternative central (LiN)2 and (LiO)2 rings, the latter involving unprecedented neutral bridging oxygen ligands
BARR, D and CLEGG, W and Mulvey, Robert and SNAITH, R (1984) The structural isomers of {[ph(2-pyridyl)NLi]·[OP(NMe2)3]}2: dimeric species with alternative central (LiN)2 and (LiO)2 rings, the latter involving unprecedented neutral bridging oxygen ligands. Journal of the Chemical Society, Chemical Communications (11). pp. 700-701. ISSN 0022-4936
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Abstract
An X-ray crystallographic study of the title compound, (1), shows it to consist of two structural isomers, one, (1A), with a planar (LiN)2 ring structure provided by µ-amido ligands, but the other,(1B), with an (LiO)2 ring due to previously unobserved bridging by the oxygen of formally neutral ligand.
Creators(s): |
BARR, D, CLEGG, W, Mulvey, Robert ![]() | Item type: | Article |
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ID code: | 37488 |
Keywords: | neutral bridging oxygen ligands , oxygen ligands , structural isomers, Chemistry, Molecular Medicine |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Pure Administrator |
Date deposited: | 08 Feb 2012 15:35 |
Last modified: | 22 Jan 2021 04:35 |
URI: | https://strathprints.strath.ac.uk/id/eprint/37488 |
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