Crystal and Solution Structures of [tBu2CNLi·OP(NMe2)3]n
Barr, D. and Clegg, W. and Mulvey, Robert and Reed, D. and Snaith, R. (1985) Crystal and Solution Structures of [tBu2CNLi·OP(NMe2)3]n. Angewandte Chemie International Edition, 24 (4). pp. 328-329. ISSN 1433-7851
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Abstract
The first dimeric lithium alkylideneamide with a μ2-nitrogen ligand and resulting Li2N2 ring is the solvent-stabilized title compound 1. The ring is exactly planar. Both the dimer 1 and the monomer are present in aromatic solvents, as was confirmed by cryoscopic Mr determinations in combination with high-field 1H- and 7Li-NMR measurements
Creators(s): |
Barr, D., Clegg, W., Mulvey, Robert ![]() | Item type: | Article |
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ID code: | 37561 |
Keywords: | crystal solutions, crystal structure, aromatic solvents, Chemistry |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Pure Administrator |
Date deposited: | 09 Feb 2012 18:24 |
Last modified: | 20 Jan 2021 19:59 |
URI: | https://strathprints.strath.ac.uk/id/eprint/37561 |
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