The synthesis and X-ray structural characterisation of the first mixed alkali metal organonitrogen molecular cluster LiNa3[OP(NMe2)3]3[NC(NMe2)2]4
CLEGG, W and Mulvey, Robert and SNAITH, R and TOOGOOD, G E and WADE, K (1986) The synthesis and X-ray structural characterisation of the first mixed alkali metal organonitrogen molecular cluster LiNa3[OP(NMe2)3]3[NC(NMe2)2]4. Journal of the Chemical Society, Chemical Communications (23). pp. 1740-1742. ISSN 0022-4936
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Abstract
A mixed alkali metal guanidino complex LiNa3[OP(NMe2)3]3[NC(NMe2)2]4(1), the first compound of its type, has been synthesised from BunLi, BunNa, OP(NMe2)3, and HNC(NMe2)2; an X-ray crystallographic study shows it to be a cubane-type cluster built up of novel µ3-N–LiNa2 and µ3-N–Na3 pyramids though additional Li H–C interactions are indicated.
Creators(s): |
CLEGG, W, Mulvey, Robert ![]() | Item type: | Article |
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ID code: | 37502 |
Keywords: | crystal structures, X-ray structures, organonitrogen molecular cluster, Physical and theoretical chemistry, Molecular Medicine |
Subjects: | Science > Chemistry > Physical and theoretical chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Pure Administrator |
Date deposited: | 08 Feb 2012 16:19 |
Last modified: | 20 Jan 2021 19:59 |
URI: | https://strathprints.strath.ac.uk/id/eprint/37502 |
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