Dis-assembling lithium amide ladder structures : new insight through the structure of [{[PhCH2N(H)Li](2)center dot thf}(infinity)], a polymer of (NLi)(2) planar rings connected by thf-bridged (NLi)(2) butterfly junctions

Clegg, W. and Liddle, S.T. and Mulvey, Robert and Robertson, Alan (1999) Dis-assembling lithium amide ladder structures : new insight through the structure of [{[PhCH2N(H)Li](2)center dot thf}(infinity)], a polymer of (NLi)(2) planar rings connected by thf-bridged (NLi)(2) butterfly junctions. Chemical Communications, 1999 (6). pp. 511-512. ISSN 1359-7345 (https://doi.org/10.1039/A900392D)

Abstract

One can visualise how the novel hemi-solvated polymeric ladder structure of the title compound would dis-assemble at its long, weak cisoid-(NLi)(2) butterfly junctions on further solvation, to release transoid-(NLi)(2) planar dimeric rings, the expected product of full solvation.

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• Item metadata

  Item type:	Article
  ID code:	38350
  Dates:	Date Event 21 March 1999 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	09 Mar 2012 09:28
  Last modified:	08 Apr 2024 19:52
  URI:	https://strathprints.strath.ac.uk/id/eprint/38350