Sodium-mediated manganation: direct mono- and dimanganation of benzene and synthesis of a transition-metal inverse-crown complex

Carrella, L.M. and Clegg, William and Graham, D.V. and Hogg, L.M. and Kennedy, A.R. and Klett, J. and Mulvey, R.E. and Rentschler, E. (2007) Sodium-mediated manganation: direct mono- and dimanganation of benzene and synthesis of a transition-metal inverse-crown complex. Angewandte Chemie, 46 (25). pp. 4662-4666. ISSN 0044-8249 (http://dx.doi.org/10.1002/anie.200700965)

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Abstract

Inside out approach: Twofold deprotonation of benzene by a sodium monoalkyl bisamido manganate(II) reagent derived from BuNa, 2,2,6,6-tetramethylpiperidine, and Mn(CH2SiMe3)2 has produced the first inverse-crown complex in which the transition-metal atoms are incorporated in the host (see X-ray structure, blue N, green Na, purple Mn). Variable-temperature magnetization measurements show that the complex is antiferromagnetic.

ORCID iDs

Carrella, L.M., Clegg, William, Graham, D.V., Hogg, L.M., Kennedy, A.R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Klett, J., Mulvey, R.E. ORCID logoORCID: https://orcid.org/0000-0002-1015-2564 and Rentschler, E.;
  • Item type:Article
    ID code:17161
    Dates:
    Date
    Event
    2007
    Published
    Notes:Strathprints' policy is to record up to 8 authors per publication, plus any additional authors based at the University of Strathclyde. More authors may be listed on the official publication than appear in the Strathprints' record.
    Keywords:alkali metals, arenes, inverse-crown compounds, manganese, metalation, Chemistry, Medicine(all)
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Strathprints Administrator
    Date deposited:27 Apr 2010 15:45
    Last modified:04 Jun 2021 02:28
    URI:https://strathprints.strath.ac.uk/id/eprint/17161
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