Sodium-mediated manganation: direct mono- and dimanganation of benzene and synthesis of a transition-metal inverse-crown complex
Carrella, L.M. and Clegg, William and Graham, D.V. and Hogg, L.M. and Kennedy, A.R. and Klett, J. and Mulvey, R.E. and Rentschler, E. (2007) Sodium-mediated manganation: direct mono- and dimanganation of benzene and synthesis of a transition-metal inverse-crown complex. Angewandte Chemie, 46 (25). pp. 4662-4666. ISSN 0044-8249
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Inside out approach: Twofold deprotonation of benzene by a sodium monoalkyl bisamido manganate(II) reagent derived from BuNa, 2,2,6,6-tetramethylpiperidine, and Mn(CH2SiMe3)2 has produced the first inverse-crown complex in which the transition-metal atoms are incorporated in the host (see X-ray structure, blue N, green Na, purple Mn). Variable-temperature magnetization measurements show that the complex is antiferromagnetic.
| Author(s): | Carrella, L.M., Clegg, William, Graham, D.V., Hogg, L.M., Kennedy, A.R., Klett, J., Mulvey, R.E. and Rentschler, E. | Item type: | Article |
|---|---|
| ID code: | 17161 |
| Notes: | Strathprints' policy is to record up to 8 authors per publication, plus any additional authors based at the University of Strathclyde. More authors may be listed on the official publication than appear in the Strathprints' record. |
| Keywords: | alkali metals, arenes, inverse-crown compounds, manganese, metalation, Chemistry, Medicine(all) |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Depositing user: | Strathprints Administrator |
| Date deposited: | 27 Apr 2010 15:45 |
| Last modified: | 03 Jan 2019 12:22 |
| URI: | https://strathprints.strath.ac.uk/id/eprint/17161 |
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