Evidence for extreme activation of carbon-hydrogen bonds in [(PhCH2)2NNa]n : resultant carbon-hydrogen bond cleavage to give {[PhC(H)NC(H)Ph]Na.cntdot.PMDETA}n

Andrews, Philip C. and Armstrong, David R. and Mulvey, Robert and Reed, David Evidence for extreme activation of carbon-hydrogen bonds in [(PhCH2)2NNa]n : resultant carbon-hydrogen bond cleavage to give {[PhC(H)NC(H)Ph]Na.cntdot.PMDETA}n. Journal of the American Chemical Society, 110 (15). pp. 5235-5236. ISSN 0002-7863

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Abstract

In organolithium chemistry evidence is accumulating that lithium atoms situated in abnormally low coordination environments then proceed to interact with nearby CH units of the ligands. For example, the crystal structure of [(PhCH,),NLi], revealed a planar (NLi)3 ring whose formally just two-coordinate metal atoms form close contacts with CHpCoCH portions of the benzyl groups.

Author(s):Andrews, Philip C., Armstrong, David R., Mulvey, Robert ORCID logoORCID: https://orcid.org/0000-0002-1015-2564 and Reed, David
Item type:Article
ID code:37564
Keywords:carbon-hydrogen bonds, organolithium chemistry, Chemistry, Biochemistry, Colloid and Surface Chemistry, Chemistry(all), Catalysis
Subjects:Science > Chemistry
Department:Faculty of Science > Pure and Applied Chemistry
Depositing user: Pure Administrator
Date deposited:09 Feb 2012 19:23
Last modified:09 Jan 2020 22:39
URI:https://strathprints.strath.ac.uk/id/eprint/37564
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