Evidence for extreme activation of carbon-hydrogen bonds in [(PhCH2)2NNa]n : resultant carbon-hydrogen bond cleavage to give {[PhC(H)NC(H)Ph]Na.cntdot.PMDETA}n

Andrews, Philip C. and Armstrong, David R. and Mulvey, Robert and Reed, David (1988) Evidence for extreme activation of carbon-hydrogen bonds in [(PhCH2)2NNa]n : resultant carbon-hydrogen bond cleavage to give {[PhC(H)NC(H)Ph]Na.cntdot.PMDETA}n. Journal of the American Chemical Society, 110 (15). pp. 5235-5236. ISSN 0002-7863 (https://doi.org/10.1021/ja00223a076)

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Abstract

In organolithium chemistry evidence is accumulating that lithium atoms situated in abnormally low coordination environments then proceed to interact with nearby CH units of the ligands. For example, the crystal structure of [(PhCH,),NLi], revealed a planar (NLi)3 ring whose formally just two-coordinate metal atoms form close contacts with CHpCoCH portions of the benzyl groups.

ORCID iDs

Andrews, Philip C., Armstrong, David R., Mulvey, Robert ORCID logoORCID: https://orcid.org/0000-0002-1015-2564 and Reed, David;
  • Item type:Article
    ID code:37564
    Dates:
    Date
    Event
    20 July 1988
    Published
    Keywords:carbon-hydrogen bonds, organolithium chemistry, Chemistry, Biochemistry, Colloid and Surface Chemistry, Chemistry(all), Catalysis
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:09 Feb 2012 19:23
    Last modified:21 May 2023 03:17
    URI:https://strathprints.strath.ac.uk/id/eprint/37564
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