A unique lithium halide complex, [(LiBr)2·3HMPA·toluene]: synthesis from reaction of solid NH4Br with BunLi in HMPA (hexamethylphosphoramide)/toluene media, crystal structure showing two Li–Br units linked by three µ2-HMPA ligands, and detection of 7Li 31P coupling in solutions of the complex

BARR, D and DOYLE, M J and Mulvey, Robert and RAITHBY, P R and REED, D and SNAITH, R and WRIGHT, D S (1989) A unique lithium halide complex, [(LiBr)2·3HMPA·toluene]: synthesis from reaction of solid NH4Br with BunLi in HMPA (hexamethylphosphoramide)/toluene media, crystal structure showing two Li–Br units linked by three µ2-HMPA ligands, and detection of 7Li 31P coupling in solutions of the complex. Journal of the Chemical Society, Chemical Communications (5). pp. 318-319. ISSN 0022-4936 (https://doi.org/10.1039/C39890000318)

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Abstract

Reaction of solid NH4Br with BunLi and HMPA (hexamethylphosphoramide)(1 : 1 : 2 ratio) in toluene produces (LiBr)2·3HMPA·toluene, (1), shown by X-ray crystallography to contain (LiBr)2·3HMPA molecules whose two terminal Li–Br units are linked by three µ2-HMPA ligands and with toluene molecules lying between these units in the lattice; in arene solutions, the (LiBr)2·3HMPA units remain intact, giving rise in 7Li n.m.r. spectra to 1 : 3 : 3 : 1 quartets caused by through-bond (OP) coupling of each 7Li nucleus to three 31P(HMPA) centres.

ORCID iDs

BARR, D, DOYLE, M J, Mulvey, Robert ORCID logoORCID: https://orcid.org/0000-0002-1015-2564, RAITHBY, P R, REED, D, SNAITH, R and WRIGHT, D S;
  • Item type:Article
    ID code:37647
    Dates:
    Date
    Event
    1 March 1989
    Published
    Keywords:lithium halide complex , X-ray crystallography , lattice, Physical and theoretical chemistry, Molecular Medicine
    Subjects:Science > Chemistry > Physical and theoretical chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:14 Feb 2012 13:16
    Last modified:21 May 2023 03:17
    URI:https://strathprints.strath.ac.uk/id/eprint/37647
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