Exploiting a substituted dihydrotriazinide as a novel bulky ligand: synthesis and crystal structure of a rubidium complex with an unprecedented tetrameric cyclic core
Clegg, W and Drummond, A M and Mulvey, Robert and OShaughnessy, P (1997) Exploiting a substituted dihydrotriazinide as a novel bulky ligand: synthesis and crystal structure of a rubidium complex with an unprecedented tetrameric cyclic core. Chemical Communications (14). pp. 1301-1302. ISSN 1359-7345 (https://doi.org/10.1039/A703009F)
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A metal exchange reaction between the alkoxide (BuORb)-O-t and a dihydrotriazinidolithium complex in tetrahydrofuran (thf) has yielded the first reported triazinidorubidium species, in the bis(thf) solvate of 4-n-butyl-4-tert-butyl-2,6-diphenyl-1,4-dihydro-s-triazinido-1-rubidium, which exists as a unique cyclic tetramer in the solid state having an unprecedented sixteen-membered (NCNRb)(4) ring core.
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Item type: Article ID code: 38195 Dates: DateEvent21 July 1997PublishedSubjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 06 Mar 2012 12:48 Last modified: 08 Apr 2024 19:51 URI: https://strathprints.strath.ac.uk/id/eprint/38195